Superhydrophobic Phosphonium Modified Robust 3D Covalent Organic Framework for Preferential Trapping of Charge Dispersed Oxoanionic Pollutants

Wang, Yue; Lan, Jianhui; Yang, Xiaofan; Zhong, Shouchao; Yuan, Liyong; Li, Jiuqiang; Peng, Jing; Chai, Zhifang; Gibson, John K.; Zhai, Maolin; Shi, Weiqun

doi:10.1002/adfm.202205222

Title: Superhydrophobic Phosphonium Modified Robust 3D Covalent Organic Framework for Preferential Trapping of Charge Dispersed Oxoanionic Pollutants

Journal Article · Mon Jul 18 00:00:00 EDT 2022 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202205222· OSTI ID:1885472

Wang, Yue ^[1]; Lan, Jianhui ^[2]; Yang, Xiaofan ^[2]; Zhong, Shouchao ^[1]; Yuan, Liyong ^[2]; Li, Jiuqiang ^[1]; Peng, Jing ^[1]; Chai, Zhifang ^[2]; Gibson, John K. ^[3]; Zhai, Maolin ^[1];

^[2]

Beijing National Laboratory for Molecular Sciences Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science the Key Laboratory of Polymer Chemistry and Physics of the Ministry of Education College of Chemistry and Molecular Engineering Peking University Beijing 100871 China
Laboratory of Nuclear Energy Chemistry Institute of High Energy Physics Chinese Academy of Sciences Beijing 100049 China
Chemical Sciences Division Lawrence Berkeley National Laboratory (LBNL) Berkeley CA 94720 USA

Abstract Charge dispersed and less hydrophilic anionic pollutants are often difficult to be preferentially captured by common cationic framework materials. A gamma radiation modification approach is employed to anchor a superhydrophobic phosphonium‐containing coating on a robust crystalline 3D covalent organic framework (COF). By regulating the surface hydrophobicity, the prepared 3DCOF‐ g ‐VBPPh ₃ Cl is endowed with a strong affinity for charge dispersed and less hydrophilic oxoanions, such as MnO ₄ ⁻ , TcO ₄ ⁻ and ReO ₄ ⁻ , to surmount the Hofmeister bias, which much favors remediation of oxoanionic pollutants in complex aqueous systems. Batch and column experiments with 3DCOF‐g‐VBPPh ₃ Cl in both tap water and simulated groundwater are performed, and rapid sequestration is achieved with removal efficacy up to 99.995%, record‐high distribution coefficient of 1.0 × 10 ⁸ mL g ⁻¹ , and desirable priority over competing anions such as Cl ⁻ , SO ₄ ²⁻ , HCO ₃ ⁻ , and NO ₃ ⁻ , confirming promise for remediation of charge dispersed anionic pollutants. Theoretical calculations reveal a mechanism of preferential capture based on electrostatic and dispersion interaction between charge dispersed anions and 3DCOF‐g‐VBPPh ₃ Cl that effectively competes with solvation of the aqueous anions.

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Sponsoring Organization:: USDOE

OSTI ID:: 1885472

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Vol. 32 Journal Issue: 36; ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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