Transport of polymer-coated metal–organic framework nanoparticles in porous media

Nune, Satish K.; Miller, Quin R. S.; Schaef, H. Todd; Jian, Tengyue; Song, Miao; Li, Dongsheng; Shuttanandan, Vaithiyalingam; McGrail, B. Peter

doi:10.1038/s41598-022-18264-y

Transport of polymer-coated metal–organic framework nanoparticles in porous media

Journal Article · Wed Aug 17 00:00:00 EDT 2022 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-022-18264-y· OSTI ID:1882255

; ; ; Jian, Tengyue; Song, Miao; ; Shuttanandan, Vaithiyalingam;

Abstract

Injecting fluids into deep underground geologic structures is a critical component to development of long-term strategies for managing greenhouse gas emissions and facilitating energy extraction operations. Recently, we reported that metal–organic frameworks are low-frequency, absorptive-acoustic metamaterial that may be injected into the subsurface to enhance geophysical monitoring tools used to track fluids and map complex structures. A key requirement for this nanotechnology deployment is transportability through porous geologic media without being retained by mineral-fluid interfaces. We used flow-through column studies to estimate transport and retention properties of five different polymer-coated MIL-101(Cr) nanoparticles (NP) in siliceous porous media. When negatively charged polystyrene sulfonate coated nanoparticles (NP-PSS-70K) were transported in 1 M NaCl, only about 8.4% of nanoparticles were retained in the column. Nanoparticles coated with polyethylenimine (NP-PD1) exhibited significant retention (> 50%), emphasizing the importance of complex nanoparticle-fluid-rock interactions for successful use of nanofluid technologies in the subsurface. Nanoparticle transport experiments revealed that nanoparticle surface characteristics play a critical role in nanoparticle colloidal stability and as well the transport.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy and Carbon Management (FECM)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1882255

Alternate ID(s):: OSTI ID: 1888559

Report Number(s):: PNNL-SA-158528; 13962; PII: 18264

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 12; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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