High‐Pressure and High‐Temperature Single‐Crystal Elasticity of Cr‐Pyrope: Implications for the Density and Seismic Velocity of Subcontinental Lithospheric Mantle

Xu, Jingui; Fan, Dawei; Li, Bo; Tkachev, Sergey N.; Prakapenka, Vitali B.; Zhang, Dongzhou; Yang, Guangzhong; Zhou, Yi; Zhou, Wenge

doi:10.1029/2022GC010393

High‐Pressure and High‐Temperature Single‐Crystal Elasticity of Cr‐Pyrope: Implications for the Density and Seismic Velocity of Subcontinental Lithospheric Mantle

Journal Article · Fri Aug 12 00:00:00 EDT 2022 · Geochemistry, Geophysics, Geosystems

DOI:https://doi.org/10.1029/2022GC010393· OSTI ID:1881038

^[1]; ^[2]; Li, Bo ^[3]; ^[4]; ^[4]; ^[5]; Yang, Guangzhong ^[6]; Zhou, Yi ^[7]; Zhou, Wenge ^[2]

Key Laboratory for High‐Temperature and High‐Pressure Study of the Earth's Interior Institute of Geochemistry Chinese Academy of Sciences Guiyang China, Hawai'i Institute of Geophysics and Planetology School of Ocean and Earth Science and Technology University of Hawai'i at Manoa Honolulu HI USA
Key Laboratory for High‐Temperature and High‐Pressure Study of the Earth's Interior Institute of Geochemistry Chinese Academy of Sciences Guiyang China
Research Institute of Petroleum Exploration &, Development‐Northwest (NWGI) PetroChina Lanzhou China
Center for Advanced Radiation Sources University of Chicago Chicago IL USA
Hawai'i Institute of Geophysics and Planetology School of Ocean and Earth Science and Technology University of Hawai'i at Manoa Honolulu HI USA
The No. 101 Geological Brigade Geological and Mineral Exploration and Development Bureau of Guizhou Province Kaili China
School of Geoscience and Technology Southwest Petroleum University Chengdu China

Abstract

Single‐crystal X‐ray diffraction and Brillouin spectroscopy experiments were performed on a natural Cr‐pyrope (Prp _71.0 Alm _12.6 Sps _0.7 Grs _3.5 Uvr _12.2 ) at high pressure and high temperature up to 11.0 GPa and 800 K. Fitting the collected data to the third‐order finite strain equation yields bulk modulus ( K _{S 0} ), shear modulus ( G ₀ ), their pressure ((∂ K _S /∂ P ) _T and (∂ G /∂ P ) _T ) and temperature (( ∂K _S /∂T ) _P and ( ∂G/∂T ) _P ) derivatives, K _{S 0} = 167.7(8) GPa, G ₀ = 91.5(5) GPa, (∂ K _S /∂ P ) _T = 4.3(1), (∂ G /∂ P ) _T = 1.4(1), ( ∂K _S /∂T ) _P = − 0.0175(1) GPa/K and ( ∂G/∂T ) _P = − 0.0073(1) GPa/K. Using the obtained results, we examined whether the elastic properties of the Cr‐pyrope can be accurately calculated from those of endmembers including pyrope, almandine, grossular, and uvarovite assuming a linear relationship between elastic properties and composition (end‐member model). The results indicate that the end‐member model provides a sufficient approximation for the elastic properties of Cr‐pyrope in calculating the density and velocity of the subcontinental lithospheric mantle (SCLM). We modeled the densities and velocities of three typical types of SCLM (Archon, Proton, and Tecton) in order to investigate how the variation of chemical composition influences the SCLM. We obtained that the compositional change from the Archon to the Tecton increases the density of the SCLM significantly, which can be an important prerequisite for SCLM delamination. However, the compositional variation only slightly changes the velocity of the SCLM and the change is within the uncertainty of the calculation. Moreover, in comparison to the velocity, ρ / V _P and ρ / V _S are much more sensitive to the compositional change of the SCLM.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-94ER14466

OSTI ID:: 1881038

Alternate ID(s):: OSTI ID: 1884333
OSTI ID: 1900773

Journal Information:: Geochemistry, Geophysics, Geosystems, Journal Name: Geochemistry, Geophysics, Geosystems Journal Issue: 8 Vol. 23; ISSN 1525-2027

Publisher:: American Geophysical Union (AGU)Copyright Statement

Country of Publication:: United States

Language:: English

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Thermodynamic properties of uvarovite garnet (Ca3Cr2Si3O12) Klemme, S. American Mineralogist, Vol. 90, Issue 4 https://doi.org/10.2138/am.2005.1812	journal	April 2005
Calcium Tschermak's pyroxene, CaAlAlSiO6, from the Allende and Murray meteorites: EBSD and micro-Raman characterizations Ma, C.; Simon, S. B.; Rossman, G. R. American Mineralogist, Vol. 94, Issue 10 https://doi.org/10.2138/am.2009.3231	journal	October 2009
Thermoelastic Equation of State of Monoclinic Pyroxene: CaMgSi2O6 Diopside. Zhao, Yusheng; Dreele, R. B. Von; Zhang, J. Z. THE REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY, Vol. 7 https://doi.org/10.4131/jshpreview.7.25	journal	January 1998
Elasticity and thermal expansion of a natural garnet up to 1,000K. Suzuki, Isao; Anderson, Orson L. Journal of Physics of the Earth, Vol. 31, Issue 2 https://doi.org/10.4294/jpe1952.31.125	journal	January 1983

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