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Phase Transfer‐Mediated Degradation of Ether‐Based Localized High‐Concentration Electrolytes in Alkali Metal Batteries

Journal Article · · Angewandte Chemie (International Edition)
Abstract

Localized high‐concentration electrolytes (LHCEs) have attracted interest in alkali metal batteries due to the advantages of forming stable solid‐electrolyte interphases (SEIs) on anodes and good chemical/electrochemical stability. Herein, a new degradation mechanism is revealed for ether‐based LHCEs that questions their compatibility with alkali metal anodes (Li, Na, and K). Specifically, the ether solvent reacts with alkali metals to generate solvated electrons (e s ) that attack hydrofluoroether co‐solvents to form a series of byproducts. The ether solvent essentially acts as a phase‐transfer reagent that continuously transfers electrons from solid‐phase metals into the solution phase, thus inhibiting the formation of stable SEI and leading to continuous alkali metal corrosion. Switching to an ester‐based solvating solvent or intercalation anodes such as graphite or molybdenum disulfide has been shown to avoid such a degradation mechanism due to the absence of e s .

Research Organization:
The Ohio State University, Columbus, OH (United States)
Sponsoring Organization:
China Scholarship Council (CSC); Sichuan University; USDOE; USDOE Office of Science (SC)
Grant/Contract Number:
FG02-07ER46427
OSTI ID:
1880363
Alternate ID(s):
OSTI ID: 1880364
OSTI ID: 1904632
Journal Information:
Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 33 Vol. 61; ISSN 1433-7851
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

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