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Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp2 Carbon Cages

Journal Article · · Synlett
DOI:https://doi.org/10.1055/a-1741-9000· OSTI ID:1879640
 [1];  [2];  [3];  [2]
  1. Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States); Rutgers University
  2. Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States)
  3. Univ. Rovira i Virgili, Tarragona (Spain)
+ Show Author Affiliations
We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. Furthermore, this account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80.
Research Organization:
Rutgers Univ., Piscataway, NJ (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0020260
OSTI ID:
1879640
Journal Information:
Synlett, Journal Name: Synlett Journal Issue: 10 Vol. 33; ISSN 0936-5214
Publisher:
ThiemeCopyright Statement
Country of Publication:
United States
Language:
English

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Unexpected Formation of Metallofulleroids from Multicomponent Reactions, with Crystallographic and Computational Studies of the Cluster Motion journal October 2021
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Biomedical Applications of Metal-Encapsulated Fullerene Nanoparticles journal December 2016
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Isocyanide-Induced Annulation Leading to Cyclopento-, Methano-, and Cyclopentano-[60]Fullerene Derivatives journal November 2021
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A multicomponent molecular approach to artificial photosynthesis – the role of fullerenes and endohedral metallofullerenes journal January 2016
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Gadolinium based endohedral metallofullerene Gd 2 @C 79 N as a relaxation boosting agent for dissolution DNP at high fields journal January 2018

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Isocyanide-Induced Annulation Leading to Cyclopento-, Methano-, and Cyclopentano-[60]Fullerene Derivatives
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Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cluster motion
endohedral
fullerenes
isocyanide
multi-component reaction