Quantum Effect on the Ground State of the Triple-Perovskite Ba3MNb2O9 (M = Co, Ni, and Mn) with Triangular-Lattice

Jiao, Jinlong; Zhang, Shangshun; Huang, Qing; Zhang, M.; Shu, M. F.; Lin, G. T.; dela Cruz, Clarina R.; Garlea, Vasile O.; Butch, N.; Matsuda, Masaaki; Zhou, Haidong; Ma, Jie

doi:10.1021/acs.chemmater.2c01576

Title: Quantum Effect on the Ground State of the Triple-Perovskite Ba₃MNb₂O₉ (M = Co, Ni, and Mn) with Triangular-Lattice

Journal Article · Tue Jul 05 00:00:00 EDT 2022 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.2c01576· OSTI ID:1878676

^[1];

^[2]; Huang, Qing ^[3]; Zhang, M. ^[1]; Shu, M. F. ^[1]; Lin, G. T. ^[1];

^[4];

^[4]; Butch, N. ^[5];

^[4];

^[3]; Ma, Jie ^[6]

Shanghai Jiao Tong Univ. (China)
Univ. of Minnesota, Minneapolis, MN (United States)
Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
Shanghai Jiao Tong Univ. (China); Huazhong Univ. of Science and Technology, Wuhan (China)

As the simplest example of geometrical frustration, the two-dimensional triangular lattice antiferromagnet exhibits the mismatch between the lattice geometry and spin-exchange interaction, which has been the subject of intensive studies due to its exotic quantum phenomena. In this work, we performed detailed studies of the magnetic structures and spin wave excitations by neutron powder diffraction and inelastic neutron scattering measurements on the triple-perovskite oxides Ba₃MNb₂O₉ (M = Co, Ni, and Mn) with triangular-lattice geometry. The interplay between the frustrated interaction and easy-plane/axis anisotropy gives rise to two magnetic phase transition temperatures for Ba₃CoNb₂O₉ (Ba₃MnNb₂O₉) and only one for Ba₃NiNb₂O₉. The linear spin-wave theory +1/S calculations indicate that both spatial dimensionality and the spin size have a significant impact on the strength of quantum fluctuations, which lead to their different magnetic ground states and exotic physical properties. Moreover, the effects of the thermal fluctuations are presented for Ba₃NiNb₂O₉.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); National Natural Science Foundation of China (NSFC); Wuhan National High Magnetic Field Center; National Key Research and Development Program of China; China Postdoctoral Science Foundation

Grant/Contract Number:: AC05-00OR22725; DMR- 2003117; U2032213; 11774223; 12004243; WHMFC 202122; 2018YFA0704300; 2019M661474

OSTI ID:: 1878676

Journal Information:: Chemistry of Materials, Vol. 34, Issue 14; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Quantum Effect on the Ground State of the Triple-Perovskite Ba3MNb2O9 (M = Co, Ni, and Mn) with Triangular-Lattice

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Title: Quantum Effect on the Ground State of the Triple-Perovskite Ba₃MNb₂O₉ (M = Co, Ni, and Mn) with Triangular-Lattice