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January 2020 |
Brønsted Acid-Promoted C–H Bond Cleavage via Electron Transfer from Toluene Derivatives to a Protonated Nonheme Iron(IV)-Oxo Complex with No Kinetic Isotope Effect
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March 2013 |
Dioxygen Activation by Metalloenzymes and Models
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July 2007 |
Unified View of Oxidative C–H Bond Cleavage and Sulfoxidation by a Nonheme Iron(IV)–Oxo Complex via Lewis Acid-Promoted Electron Transfer
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March 2014 |
Kinetic Isotope Effect Determination Probes the Spin of the Transition State, Its Stereochemistry, and Its Ligand Sphere in Hydrogen Abstraction Reactions of Oxoiron(IV) Complexes
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January 2018 |
Redox inactive metal ion triggered N-dealkylation by an iron catalyst with dioxygen activation: a lesson from lipoxygenases
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January 2015 |
A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions
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January 2013 |
Spectroscopic Identification of an Fe III Center, not Fe IV , in the Crystalline Sc–O–Fe Adduct Derived from [Fe IV (O)(TMC)] 2+
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March 2015 |
Evidence for an oxygen evolving iron–oxo–cerium intermediate in iron-catalysed water oxidation
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January 2015 |
High-Valent Manganese–Oxo Valence Tautomers and the Influence of Lewis/Brönsted Acids on C–H Bond Cleavage
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September 2016 |
The development of molecular water oxidation catalysts
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April 2019 |
Tuning the reactivity of mononuclear nonheme manganese( iv )-oxo complexes by triflic acid
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January 2015 |
Lewis-Acid-Promoted Stoichiometric and Catalytic Oxidations by Manganese Complexes Having Cross-Bridged Cyclam Ligand: A Comprehensive Study
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April 2013 |
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
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April 2011 |
Transient Intermediates from Mn(salen) with Sterically Hindered Mesityl Groups: Interconversion between Mn IV -Phenolate and Mn III -Phenoxyl Radicals as an Origin for Unique Reactivity
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March 2008 |
Metal ion-coupled and decoupled electron transfer
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February 2010 |
OLEX2 : a complete structure solution, refinement and analysis program
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January 2009 |
A new look at the role of thiolate ligation in cytochrome P450
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January 2017 |
Effect of Lewis Acids on the Structure and Reactivity of a Mononuclear Hydroxomanganese(III) Complex
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February 2020 |
Theoretical x-ray absorption fine structure standards
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July 1991 |
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates
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September 2015 |
Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes
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June 2016 |
High-valent metal-oxo intermediates in energy demanding processes: from dioxygen reduction to water splitting
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April 2015 |
SHELXT – Integrated space-group and crystal-structure determination
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January 2015 |
Catalytic control of electron-transfer processes
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January 2003 |
Lewis versus Brønsted Acid Activation of a Mn(IV) Catalyst for Alkene Oxidation
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October 2019 |
Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III)
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June 2017 |
Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese( iv )–oxo adducts
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January 2021 |
Redox Reactivity of a Mononuclear Manganese-Oxo Complex Binding Calcium Ion and Other Redox-Inactive Metal Ions
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December 2018 |
A change in the oxidation state of iron: scandium is not innocent
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January 2013 |
Evidence for a Precursor Complex in CH Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex
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April 2011 |
Long-Lived Photoexcited State of a Mn(IV)-Oxo Complex Binding Scandium Ions That is Capable of Hydroxylating Benzene
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June 2018 |
Determination of the Cu(III)–OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger’s Rule
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March 2017 |
Valence Tautomerism in a High-Valent Manganese–Oxo Porphyrinoid Complex Induced by a Lewis Acid
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June 2012 |
BF 3 -Activated Oxidation of Alkanes by MnO 4 -
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February 2006 |
Fine Control of the Redox Reactivity of a Nonheme Iron(III)-Peroxo Complex by Binding Redox-Inactive Metal Ions
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December 2016 |
The Effects of Redox-Inactive Metal Ions on the Activation of Dioxygen: Isolation and Characterization of a Heterobimetallic Complex Containing a Mn III –(μ-OH)–Ca II Core
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June 2011 |
Progress Toward a Molecular Mechanism of Water Oxidation in Photosystem II
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May 2017 |
A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II
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August 2011 |
Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
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March 2013 |
Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes
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February 2014 |
PySpline: A Modern, Cross-Platform Program for the Processing of Raw Averaged XAS Edge and EXAFS Data
- Tenderholt, Adam; Hedman, Britt; Hodgson, Keith O.
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X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings
https://doi.org/10.1063/1.2644442
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January 2007 |
Unified Mechanism of Oxygen Atom Transfer and Hydrogen Atom Transfer Reactions with a Triflic Acid-Bound Nonheme Manganese(IV)–Oxo Complex via Outer-Sphere Electron Transfer
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January 2019 |
60 years of dioxygen activation
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February 2017 |
Characterization of a selenocysteine-ligated P450 compound I reveals direct link between electron donation and reactivity
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May 2017 |
Formation of superoxide–metal ion complexes and the electron transfer catalysis
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March 2002 |
Strong Inhibition of O-Atom Transfer Reactivity for Mn IV (O)(π-Radical-Cation)(Lewis Acid) versus Mn V (O) Porphyrinoid Complexes
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May 2015 |
Activation of Metal Oxo and Nitrido Complexes by Lewis Acids
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February 2019 |
ESR Spectra of Superoxide Anion−Scandium Complexes Detectable in Fluid Solution
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February 1999 |
Toward the Synthesis of More Reactive S = 2 Non-Heme Oxoiron(IV) Complexes
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July 2015 |
Significantly shorter Fe–S bond in cytochrome P450-I is consistent with greater reactivity relative to chloroperoxidase
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August 2015 |
The O 2 -Evolving Complex of Photosystem II: Recent Insights from Quantum Mechanics/Molecular Mechanics (QM/MM), Extended X-ray Absorption Fine Structure (EXAFS), and Femtosecond X-ray Crystallography Data
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December 2016 |
Effects of Noncovalent Interactions on High-Spin Fe(IV)–Oxido Complexes
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June 2020 |
Multiple-scattering calculations of x-ray-absorption spectra
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July 1995 |
Mechanisms of metal ion-coupled electron transfer
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January 2012 |
Biomimetic Reactivity of Oxygen-Derived Manganese and Iron Porphyrinoid Complexes
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October 2017 |
A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis
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May 2015 |
Lessons from Nature: A Bio-Inspired Approach to Molecular Design
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June 2015 |
Metal Ion-coupled Electron-transfer Reduction of Dioxygen
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August 2008 |
Oxoiron(IV) in Chloroperoxidase Compound II Is Basic: Implications for P450 Chemistry
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June 2004 |
Molecular Catalysts for Water Oxidation
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July 2015 |
Nonredox Metal Ions Promoted Olefin Epoxidation by Iron(II) Complexes with H 2 O 2 : DFT Calculations Reveal Multiple Channels for Oxygen Transfer
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November 2017 |
Iron and manganese oxo complexes, oxo wall and beyond
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July 2020 |
Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals
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June 2013 |
Quantitative Evaluation of Lewis Acidity of Metal Ions with Different Ligands and Counterions in Relation to the Promoting Effects of Lewis Acids on Electron Transfer Reduction of Oxygen
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June 2003 |
C−H Bond Activation by a Ferric Methoxide Complex: Modeling the Rate-Determining Step in the Mechanism of Lipoxygenase
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January 2002 |
Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc 3+
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January 2011 |
Switchover of the Mechanism between Electron Transfer and Hydrogen-Atom Transfer for a Protonated Manganese(IV)-Oxo Complex by Changing Only the Reaction Temperature
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May 2016 |
Oxomanganese(IV) porphyrins identified by resonance Raman and infrared spectroscopy. Weak bonds and the stability of the half-filled t2g subshell
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June 1988 |
Ab initio curved-wave x-ray-absorption fine structure
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A High‐Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity
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November 2019 |
Water-oxidizing complex in Photosystem II: Its structure and relation to manganese-oxide based catalysts
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May 2020 |
Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid
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May 2018 |
Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450
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November 2013 |
Fluorescence Maxima of 10-Methylacridone−Metal Ion Salt Complexes: A Convenient and Quantitative Measure of Lewis Acidity of Metal Ion Salts
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September 2002 |
Acid Catalysis via Acid‐Promoted Electron Transfer
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November 2020 |
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer
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July 2010 |
Synthesis, Characterization, and Solution Properties of a Novel Cross-Bridged Cyclam Manganese(IV) Complex Having Two Terminal Hydroxo Ligands
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October 2006 |
Activation of a Non‐Heme Fe III ‐OOH by a Second Fe III to Hydroxylate Strong C−H Bonds: Possible Implications for Soluble Methane Monooxygenase
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June 2019 |
Understanding the Oxidative Relationships of the Metal Oxo, Hydroxo, and Hydroperoxide Intermediates with Manganese(IV) Complexes Having Bridged Cyclams: Correlation of the Physicochemical Properties with Reactivity
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November 2012 |
Scandium Ion-Enhanced Oxidative Dimerization and N -Demethylation of N , N -Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex
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November 2011 |
Targeting of High-Valent Iron-TAML Activators at Hydrocarbons and Beyond
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March 2017 |
Synthesis, Structure, and Characterization of a Novel Manganese(IV) Monomer, [Mn IV (Me 3 TACN)(OMe) 3 ](PF 6 ) (Me 3 TACN = N , N ‘, N ‘‘-Trimethyl-1,4,7-triazacyclononane), and Its Activity toward Olefin Oxidation with Hydrogen Peroxide
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January 1996 |
Photosynthetic Water Oxidation: Insights from Manganese Model Chemistry
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Metal ion-coupled electron-transfer reactions of metal-oxygen complexes
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May 2020 |
Non-redox metal ion promoted oxygen transfer by a non-heme manganese catalyst
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January 2015 |
Redox-inactive metal ions modulate the reactivity and oxygen release of mononuclear non-haem iron(III)–peroxo complexes
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September 2014 |
The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II
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July 2007 |
The Structure of Photosystem II and the Mechanism of Water Oxidation in Photosynthesis
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April 2015 |
Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands
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March 2019 |
Formation of the syn isomer of [Fe IV (O anti )(TMC)(NCMe)] 2+ in the reaction of Lewis acids with the side-on bound peroxo ligand in [Fe III (η 2 -O 2 )(TMC)] +
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January 2016 |
Factors Controlling the Chemoselectivity in the Oxidation of Olefins by Nonheme Manganese(IV)-Oxo Complexes
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August 2016 |
Biological Water Oxidation
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March 2013 |
Manganese Compounds as Water-Oxidizing Catalysts: From the Natural Water-Oxidizing Complex to Nanosized Manganese Oxide Structures
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January 2016 |
Structure validation in chemical crystallography
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January 2009 |
Structure of photosystem II and substrate binding at room temperature
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November 2016 |
Promoting a non-heme manganese complex catalyzed oxygen transfer reaction by both lewis acid and Brønsted acid: Similarities and distinctions
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September 2017 |
Preparation and properties of an Mn IV –hydroxide complex: proton and electron transfer at a mononuclear manganese site and its relationship to the oxygen evolving complex within photosystem II
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January 2014 |
A Manganese(V)–Oxo Complex: Synthesis by Dioxygen Activation and Enhancement of Its Oxidizing Power by Binding Scandium Ion
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June 2016 |
Sc 3+ (or HClO 4 ) Activation of a Nonheme Fe III –OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene
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April 2018 |
Saturation Kinetics in Phenolic O–H Bond Oxidation by a Mononuclear Mn(III)–OH Complex Derived from Dioxygen
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June 2014 |
Electron transfer and catalysis with high-valent metal-oxo complexes
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January 2015 |
Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex
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April 2011 |
The reactivity of the active metal oxo and hydroxo intermediates and their implications in oxidations
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January 2015 |
Mn 4 Ca Cluster in Photosynthesis: Where and How Water is Oxidized to Dioxygen
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March 2014 |
Enhanced Rates of C–H Bond Cleavage by a Hydrogen-Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex
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July 2019 |
Native structure of photosystem II at 1.95 Å resolution viewed by femtosecond X-ray pulses
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November 2014 |
NMR Studies of a Mn III -hydroxo Adduct Reveal an Equilibrium between Mn III -hydroxo and μ-Oxodimanganese(III,III) Species
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June 2018 |
Application of Badger's Rule to Heme and Non-Heme Iron−Oxygen Bonds: An Examination of Ferryl Protonation States
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February 2006 |
Light-induced structural changes and the site of O=O bond formation in PSII caught by XFEL
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February 2017 |
Quantitative Evaluation of Lewis Acidity of Metal Ions Derived from theg Values of ESR Spectra of Superoxide: Metal Ion Complexes in Relation to the Promoting Effects in Electron Transfer Reactions
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December 2000 |
Influence of Calcium(II) and Chloride on the Oxidative Reactivity of a Manganese(II) Complex of a Cross-Bridged Cyclen Ligand
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October 2014 |
Crystal structure refinement with SHELXL
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January 2015 |
Mn K-edge X-ray absorption studies of mononuclear Mn(III)–hydroxo complexes
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October 2017 |
Molecular Designs for Controlling the Local Environments around Metal Ions
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July 2015 |
Redox-inactive metal ions promoted the catalytic reactivity of non-heme manganese complexes towards oxygen atom transfer
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January 2015 |
An amphoteric reactivity of a mixed-valent bis(μ-oxo)dimanganese( iii , iv ) complex acting as an electrophile and a nucleophile
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January 2016 |
Structure of photosynthetic LH1–RC supercomplex at 1.9 Å resolution
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April 2018 |
Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins
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December 2017 |
A Reactive Manganese(IV)–Hydroxide Complex: A Missing Intermediate in Hydrogen Atom Transfer by High-Valent Metal-Oxo Porphyrinoid Compounds
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March 2018 |
A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions
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September 2018 |
Heme and Nonheme High-Valent Iron and Manganese Oxo Cores in Biological and Abiological Oxidation Reactions
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December 2018 |
Factors Affecting Hydrogen Atom Transfer Reactivity of Metal–Oxo Porphyrinoid Complexes
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October 2018 |
Mechanistic Borderline of One-Step Hydrogen Atom Transfer versus Stepwise Sc 3+ -Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex
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September 2012 |
Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C–H Bond Activation Reactions
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July 2019 |
A High Spin Mn(IV)-Oxo Complex Generated via Stepwise Proton and Electron Transfer from Mn(III)–Hydroxo Precursor: Characterization and C–H Bond Cleavage Reactivity
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July 2019 |
Preparation and Properties of a Monomeric Mn IV −Oxo Complex
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July 2006 |
Enhanced Electron-Transfer Reactivity of Nonheme Manganese(IV)–Oxo Complexes by Binding Scandium Ions
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June 2013 |