Photoactivated p-Doping of Organic Interlayer Enables Efficient Perovskite/Silicon Tandem Solar Cells

Zheng, Xiaopeng; Liu, Jiang; Liu, Tuo; Aydin, Erkan; Chen, Min; Yan, Wenbo; De Bastiani, Michele; Allen, Thomas G.; Yuan, Shuai; Kirmani, Ahmad R.; Baustert, Kyle N.; Salvador, Michael F.; Turedi, Bekir; Alsalloum, Abdullah Y.; Almasabi, Khulud; Kotsovos, Konstantinos; Gereige, Issam; Liao, Liang-Sheng; Luther, Joseph M.; Graham, Kenneth R.; Mohammed, Omar F.; De Wolf, Stefaan; Bakr, Osman M.

doi:10.1021/acsenergylett.2c00780

Title: Photoactivated p-Doping of Organic Interlayer Enables Efficient Perovskite/Silicon Tandem Solar Cells

Journal Article · Tue May 17 00:00:00 EDT 2022 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.2c00780· OSTI ID:1878127

Zheng, Xiaopeng; Liu, Jiang; Liu, Tuo; Aydin, Erkan; Chen, Min; Yan, Wenbo; De Bastiani, Michele; Allen, Thomas G.; Yuan, Shuai; Kirmani, Ahmad R.; Baustert, Kyle N.; Salvador, Michael F.; Turedi, Bekir; Alsalloum, Abdullah Y.; Almasabi, Khulud; Kotsovos, Konstantinos; Gereige, Issam; Liao, Liang-Sheng;

; Graham, Kenneth R. more »

Solution-processed organic semiconductor layers on rough surfaces tend to vary widely in thickness, significantly hindering charge extraction in relevant optoelectronic devices. Herein, we report the photoactivated p-doping of hole-transporting material (HTM) to enhance hole extraction for (textured) perovskite/silicon tandem solar cells, making the device performance less sensitive to the variation of hole transport layer thickness. We used the ionic compound 4-isopropyl-4'-methyldiphenyliodonium tetrakis(penta-fluorophenyl-borate) (DPI-TPFB) as a p-type dopant in poly(triaryl amine) (PTAA), which we used as the HTM. We observed that light soaking DPI-TPFB-doped PTAA shows approximately 22 times higher conductivity compared with an undoped PTAA film, which translated into an improved fill factor (FF) for tandem solar cells. Our tandem solar cells achieved an ~80% FF and 27.8% efficiency and operated at their maximum power point for 200 h without loss of performance, in addition to retaining ~83% of initial performance over a month of operation in an outdoor environment.

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Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1878127

Report Number(s):: NREL/JA-5900-82546; MainId:83319; UUID:709de06e-7283-44f4-92cf-a9a7a40ad590; MainAdminID:64921

Journal Information:: ACS Energy Letters, Vol. 7, Issue 6

Country of Publication:: United States

Language:: English

References (37)

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051 https://doi.org/10.1021/ja809598r	journal	May 2009
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes Min, Hanul; Lee, Do Yoon; Kim, Junu Nature, Vol. 598, Issue 7881 https://doi.org/10.1038/s41586-021-03964-8	journal	October 2021
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals Shi, D.; Adinolfi, V.; Comin, R. Science, Vol. 347, Issue 6221 https://doi.org/10.1126/science.aaa2725	journal	January 2015
Perovskite Single-Crystal Solar Cells: Going Forward Turedi, Bekir; Yeddu, Vishal; Zheng, Xiaopeng ACS Energy Letters, Vol. 6, Issue 2 https://doi.org/10.1021/acsenergylett.0c02573	journal	January 2021
Quantum Dots Supply Bulk- and Surface-Passivation Agents for Efficient and Stable Perovskite Solar Cells Zheng, Xiaopeng; Troughton, Joel; Gasparini, Nicola Joule, Vol. 3, Issue 8 https://doi.org/10.1016/j.joule.2019.05.005	journal	August 2019
Managing grains and interfaces via ligand anchoring enables 22.3%-efficiency inverted perovskite solar cells Zheng, Xiaopeng; Hou, Yi; Bao, Chunxiong Nature Energy, Vol. 5, Issue 2 https://doi.org/10.1038/s41560-019-0538-4	journal	January 2020
22.8%-Efficient single-crystal mixed-cation inverted perovskite solar cells with a near-optimal bandgap Alsalloum, Abdullah Y.; Turedi, Bekir; Almasabi, Khulud Energy & Environmental Science, Vol. 14, Issue 4 https://doi.org/10.1039/D0EE03839C	journal	January 2021
Low-Temperature Crystallization Enables 21.9% Efficient Single-Crystal MAPbI ₃ Inverted Perovskite Solar Cells Alsalloum, Abdullah Y.; Turedi, Bekir; Zheng, Xiaopeng ACS Energy Letters, Vol. 5, Issue 2 https://doi.org/10.1021/acsenergylett.9b02787	journal	January 2020
Selecting tandem partners for silicon solar cells Yu, Zhengshan; Leilaeioun, Mehdi; Holman, Zachary Nature Energy, Vol. 1, Issue 11 https://doi.org/10.1038/nenergy.2016.137	journal	September 2016
Efficient tandem solar cells with solution-processed perovskite on textured crystalline silicon Hou, Yi; Aydin, Erkan; De Bastiani, Michele Science, Vol. 367, Issue 6482 https://doi.org/10.1126/science.aaz3691	journal	March 2020
28.2%-efficient, outdoor-stable perovskite/silicon tandem solar cell Liu, Jiang; Aydin, Erkan; Yin, Jun Joule, Vol. 5, Issue 12 https://doi.org/10.1016/j.joule.2021.11.003	journal	December 2021
High-performance perovskite/Cu(In,Ga)Se ₂ monolithic tandem solar cells Han, Qifeng; Hsieh, Yao-Tsung; Meng, Lei Science, Vol. 361, Issue 6405 https://doi.org/10.1126/science.aat5055	journal	August 2018
Monolithic perovskite/silicon tandem solar cell with >29% efficiency by enhanced hole extraction Al-Ashouri, Amran; Köhnen, Eike; Li, Bor Science, Vol. 370, Issue 6522 https://doi.org/10.1126/science.abd4016	journal	December 2020
Grain Engineering for Perovskite/Silicon Monolithic Tandem Solar Cells with Efficiency of 25.4% Chen, Bo; Yu, Zhengshan; Liu, Kong Joule, Vol. 3, Issue 1 https://doi.org/10.1016/j.joule.2018.10.003	journal	January 2019
Efficient, stable silicon tandem cells enabled by anion-engineered wide-bandgap perovskites Kim, Daehan; Jung, Hee Joon; Park, Ik Jae Science, Vol. 368, Issue 6487 https://doi.org/10.1126/science.aba3433	journal	March 2020
Triple-halide wide–band gap perovskites with suppressed phase segregation for efficient tandems Xu, Jixian; Boyd, Caleb C.; Yu, Zhengshan J. Science, Vol. 367, Issue 6482 https://doi.org/10.1126/science.aaz5074	journal	March 2020
All-Perovskite Tandem Solar Cells: A Roadmap to Uniting High Efficiency with High Stability Zheng, Xiaopeng; Alsalloum, Abdullah Y.; Hou, Yi Accounts of Materials Research, Vol. 1, Issue 1 https://doi.org/10.1021/accountsmr.0c00017	journal	September 2020
Perovskite/CIGS Tandem Solar Cells: From Certified 24.2% toward 30% and Beyond Jošt, Marko; Köhnen, Eike; Al-Ashouri, Amran ACS Energy Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsenergylett.2c00274	journal	March 2022
High-performance solar flow battery powered by a perovskite/silicon tandem solar cell Li, Wenjie; Zheng, Jianghui; Hu, Bo Nature Materials, Vol. 19, Issue 12 https://doi.org/10.1038/s41563-020-0720-x	journal	July 2020
21.6%-Efficient Monolithic Perovskite/Cu(In,Ga)Se ₂ Tandem Solar Cells with Thin Conformal Hole Transport Layers for Integration on Rough Bottom Cell Surfaces Jošt, Marko; Bertram, Tobias; Koushik, Dibyashree ACS Energy Letters, Vol. 4, Issue 2 https://doi.org/10.1021/acsenergylett.9b00135	journal	January 2019
Large-Area 23%-Efficient Monolithic Perovskite/Homojunction-Silicon Tandem Solar Cell with Enhanced UV Stability Using Down-Shifting Material Zheng, Jianghui; Mehrvarz, Hamid; Liao, Chwenhaw ACS Energy Letters, Vol. 4, Issue 11 https://doi.org/10.1021/acsenergylett.9b01783	journal	October 2019
23.6%-efficient monolithic perovskite/silicon tandem solar cells with improved stability Bush, Kevin A.; Palmstrom, Axel F.; Yu, Zhengshan J. Nature Energy, Vol. 2, Issue 4 https://doi.org/10.1038/nenergy.2017.9	journal	February 2017
Minimizing Current and Voltage Losses to Reach 25% Efficient Monolithic Two-Terminal Perovskite–Silicon Tandem Solar Cells Bush, Kevin A.; Manzoor, Salman; Frohna, Kyle ACS Energy Letters, Vol. 3, Issue 9 https://doi.org/10.1021/acsenergylett.8b01201	journal	August 2018
Fully textured monolithic perovskite/silicon tandem solar cells with 25.2% power conversion efficiency Sahli, Florent; Werner, Jérémie; Kamino, Brett A. Nature Materials, Vol. 17, Issue 9 https://doi.org/10.1038/s41563-018-0115-4	journal	June 2018
Interplay between temperature and bandgap energies on the outdoor performance of perovskite/silicon tandem solar cells Aydin, Erkan; Allen, Thomas G.; De Bastiani, Michele Nature Energy, Vol. 5, Issue 11 https://doi.org/10.1038/s41560-020-00687-4	journal	September 2020
Blade-Coated Perovskites on Textured Silicon for 26%-Efficient Monolithic Perovskite/Silicon Tandem Solar Cells Chen, Bo; Yu, Zhengshan J.; Manzoor, Salman Joule, Vol. 4, Issue 4 https://doi.org/10.1016/j.joule.2020.01.008	journal	April 2020
Multimodal Microscale Imaging of Textured Perovskite–Silicon Tandem Solar Cells Tennyson, Elizabeth M.; Frohna, Kyle; Drake, William K. ACS Energy Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acsenergylett.1c00568	journal	May 2021
25.1%-Efficient Monolithic Perovskite/Silicon Tandem Solar Cell Based on a p -type Monocrystalline Textured Silicon Wafer and High-Temperature Passivating Contacts Nogay, G.; Sahli, F.; Werner, J. ACS Energy Letters, Vol. 4, Issue 4 https://doi.org/10.1021/acsenergylett.9b00377	journal	March 2019
Reflection of normally incident light from silicon solar cells with pyramidal texture Baker-Finch, Simeon C.; McIntosh, Keith R. Progress in Photovoltaics: Research and Applications, Vol. 19, Issue 4 https://doi.org/10.1002/pip.1050	journal	October 2010
Efficient Lead-Free Solar Cells Based on Hollow {en}MASnI ₃ Perovskites Ke, Weijun; Stoumpos, Constantinos C.; Spanopoulos, Ioannis Journal of the American Chemical Society, Vol. 139, Issue 41 https://doi.org/10.1021/jacs.7b09018	journal	October 2017
Enhanced Efficiency of Planar Heterojunction Perovskite Solar Cells by a Light Soaking Treatment on Tris(pentafluorophenyl)borane-Doped Poly(triarylamine) Solution Ye, Tengling; Chen, Wenbo; Jin, Shan ACS Applied Materials & Interfaces, Vol. 11, Issue 15 https://doi.org/10.1021/acsami.8b18663	journal	March 2019
n-type charge transport in heavily p-doped polymers Liang, Zhiming; Choi, Hyun Ho; Luo, Xuyi Nature Materials, Vol. 20, Issue 4 https://doi.org/10.1038/s41563-020-00859-3	journal	January 2021
Photochemistry of diaryliodonium salts Dektar, John L.; Hacker, Nigel P. The Journal of Organic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/jo00289a045	journal	January 1990
Photoactivation of an ionic p-type dopant used in a triarylamine based hole transporting material for enhancing conductivity of solution processed films Seim, Henning; Haase, Nils; Scheible, Katja Synthetic Metals, Vol. 230 https://doi.org/10.1016/j.synthmet.2017.05.012	journal	August 2017
Toward Stable Monolithic Perovskite/Silicon Tandem Photovoltaics: A Six-Month Outdoor Performance Study in a Hot and Humid Climate De Bastiani, Michele; Van Kerschaver, Emmanuel; Jeangros, Quentin ACS Energy Letters, Vol. 6, Issue 8 https://doi.org/10.1021/acsenergylett.1c01018	journal	July 2021

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Title: Photoactivated p-Doping of Organic Interlayer Enables Efficient Perovskite/Silicon Tandem Solar Cells

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