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Densified HKUST-1 Monoliths as a Route to High Volumetric and Gravimetric Hydrogen Storage Capacity

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.2c04608· OSTI ID:1877952
 [1];  [2];  [3];  [3];  [3];  [3];  [3];  [4];  [5];  [6];  [7];  [8];  [8];  [9];  [9];  [9];  [9];  [10];  [10];  [7] more »;  [11];  [12];  [2];  [3] « less
  1. The Adsorption & Advanced Materials Laboratory (A2ML), Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K., Department of Chemical Sciences and Bernal Institute, University of Limerick, Limerick V94 T9PX, Ireland
  2. Department of Chemistry, Stony Brook University, Stony Brook, New York 11790-3400, United States
  3. The Adsorption & Advanced Materials Laboratory (A2ML), Department of Chemical Engineering & Biotechnology, University of Cambridge, Philippa Fawcett Drive, Cambridge CB3 0AS, U.K.
  4. Nanoscale and Microscale Research Center (nmRC), University of Nottingham, University Park, Nottingham NG7 2RD, U.K., School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, U.K.
  5. Synchrotron SOLEIL, Gif sur Yvette Cedex, Saint-Aubin 91190, France
  6. 10 Laboratory for Synchrotron Radiation─Condensed Matter, Paul Scherrer Institute, PSI, 11, Villigen 5232, Switzerland
  7. Laboratorio de Materiales Avanzados (LMA), Departamento de Química Inorgánica-IUMA, Universidad de Alicante, San Vicente del Raspeig 03690, Spain
  8. Immaterial Ltd., 25 Cambridge Science Park, Milton Road, Cambridge CB4 0FW, U.K.
  9. Materials and Chemical Science and Technology Directorate, National Renewable Energy Laboratory, Golden, Colorado 80401, United States
  10. Chemistry, Combustion, and Materials Science Center, Sandia National Laboratories, Livermore, California 94551, United States
  11. Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, U.K.
  12. School of Chemistry, University of Birmingham, Edgbaston, Birmingham B15 2TT, U.K.

Not Available

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI ID:
1877952
Alternate ID(s):
OSTI ID: 1879632
OSTI ID: 1882629
OSTI ID: 1882678
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 30 Vol. 144; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (50)

Sol-Gel Synthesis of Robust Metal-Organic Frameworks for Nanoparticle Encapsulation journal January 2018
How Reproducible are Surface Areas Calculated from the BET Equation? journal May 2022
An International Laboratory Comparison Study of Volumetric and Gravimetric Hydrogen Adsorption Measurements journal June 2019
An international multi-laboratory investigation of carbon-based hydrogen sorbent materials journal January 2016
Recommended volumetric capacity definitions and protocols for accurate, standardized and unambiguous metrics for hydrogen storage materials journal February 2016
Nanoporous polymer-based composites for enhanced hydrogen storage journal May 2019
Towards the hydrogen economy? journal August 2007
Carbon materials for H2 storage journal May 2009
Increased volumetric hydrogen uptake of MOF-5 by powder densification journal February 2012
Volumetric hydrogen adsorption capacity of densified MIL-101 monoliths journal June 2013
Hydrogen cryo-adsorption by hexagonal prism monoliths of MIL-101 journal October 2014
Estimation of system-level hydrogen storage for metal-organic frameworks with high volumetric storage density journal June 2019
Is the H2 economy realizable in the foreseeable future? Part II: H2 storage, transportation, and distribution journal August 2020
Structure-Mechanical Stability Relations of Metal-Organic Frameworks via Machine Learning journal July 2019
The progression of Al-based metal-organic frameworks – From academic research to industrial production and applications journal July 2012
Investigating the Effects of Linker Extension on H 2 Sorption in the rht-Metal–Organic Framework NU-111 by Molecular Simulations journal October 2018
Materials Informatics with PoreBlazer v4.0 and the CSD MOF Database journal November 2020
Development of a Cambridge Structural Database Subset: A Collection of Metal–Organic Frameworks for Past, Present, and Future journal March 2017
Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni 2 ( m -dobdc) at Near-Ambient Temperatures journal October 2018
Nanoporous Materials for the Onboard Storage of Natural Gas journal January 2017
Techno-economic Analysis of Metal–Organic Frameworks for Hydrogen and Natural Gas Storage journal January 2017
Multitechnique Analysis of the Hydration in Three Different Copper Paddle-Wheel Metal–Organic Frameworks journal October 2019
Understanding Volumetric and Gravimetric Hydrogen Adsorption Trade-off in Metal–Organic Frameworks journal April 2017
Benchmark Study of Hydrogen Storage in Metal–Organic Frameworks under Temperature and Pressure Swing Conditions journal February 2018
Local Structure of Framework Cu(II) in HKUST-1 Metallorganic Framework:  Spectroscopic Characterization upon Activation and Interaction with Adsorbates journal March 2006
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
  • Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894 https://doi.org/10.1021/ja4045289
journal July 2013
Shaping the Future of Fuel: Monolithic Metal–Organic Frameworks for High-Density Gas Storage journal April 2020
Ambient-Temperature Hydrogen Storage via Vanadium(II)-Dihydrogen Complexation in a Metal–Organic Framework journal April 2021
Optimizing Hydrogen Storage in MOFs through Engineering of Crystal Morphology and Control of Crystal Size journal July 2021
Observation of an Intermediate to H 2 Binding in a Metal–Organic Framework journal August 2021
Improved Hydrogen Storage and Thermal Conductivity in High-Density MOF-5 Composites journal September 2012
On the Use of the Dual-Process Langmuir Model for Correlating Unary Equilibria and Predicting Mixed-Gas Adsorption Equilibria journal April 2011
A sol–gel monolithic metal–organic framework with enhanced methane uptake journal December 2017
A spray-drying strategy for synthesis of nanoscale metal–organic frameworks and their assembly into hollow superstructures journal February 2013
De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities journal September 2010
Exceptional hydrogen storage achieved by screening nearly half a million metal-organic frameworks journal April 2019
Tuning porosity in macroscopic monolithic metal-organic frameworks for exceptional natural gas storage journal May 2019
Hydrolytic stability in hemilabile metal–organic frameworks journal August 2018
Volumetric hydrogen sorption capacity of monoliths prepared by mechanical densification of MOF-177 journal January 2010
Mechanochemistry: opportunities for new and cleaner synthesis journal January 2012
Evaluation of an industrial pilot scale densified MOF-177 adsorbent as an on-board hydrogen storage medium journal January 2011
Understanding excess uptake maxima for hydrogen adsorption isotherms in frameworks with rht topology journal January 2012
High-resolution solid-state 13C NMR spectroscopy of the paramagnetic metal–organic frameworks, STAM-1 and HKUST-1 journal January 2013
Mechanically and chemically robust ZIF-8 monoliths with high volumetric adsorption capacity journal January 2015
An assessment of strategies for the development of solid-state adsorbents for vehicular hydrogen storage journal January 2018
Technoeconomic analysis of metal–organic frameworks for bulk hydrogen transportation journal January 2021
Targeted classification of metal–organic frameworks in the Cambridge structural database (CSD) journal January 2020
A thermal-gradient approach to variable-temperature measurements resolved in space journal April 2020
A Hydrogen Economy journal June 1972
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy journal April 2020

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