Skip to main content
OSTI.GOVU.S. Department of Energy Office of Scientific and Technical Information
U.S. Department of Energy
Office of Scientific and Technical Information
 

Manipulating Interfacial Dissolution–Redeposition Dynamics to Resynthesize Electrode Surface Chemistry

Journal Article · · ACS Energy Letters
 [1];  [1];  [2];  [3];  [4];  [5];  [6];  [7];  [2];  [6];  [1]
  1. Virginia Polytechnic Institute and State University (Virginia Tech), Blacksburg, VA (United States)
  2. San Diego State University, CA (United States)
  3. Brookhaven National Laboratory (BNL), Upton, NY (United States)
  4. SLAC National Accelerator Laboratory, Menlo Park, CA (United States); University of Oulu (Finland)
  5. SLAC National Accelerator Laboratory, Menlo Park, CA (United States)
  6. Argonne National Laboratory (ANL), Argonne, IL (United States)
  7. Jackson State University, Jackson, MS (United States)
+ Show Author Affiliations
The solid-liquid electrochemical interface offers a two-dimensional environment for geometrically confined interfacial reactions to tailor electrode surface chemistry under operating conditions. In this study, we demonstrate that the dissolution and redeposition kinetics of transition metal cations, a ubiquitous phenomenon at the electrochemical interface, can be manipulated to regulate the chemical composition and crystal structure of the electrode surface as well as the overall electrochemical performance. Foreign cations (e.g., Ti4+), either added as electrolyte additives or dissolved from surface coatings, can rapidly participate in the electrode dissolution-redeposition process, and facilitate the establishment of the dissolution-redeposition equilibrium. Our work expands the control over the electrochemical reactions at the solid-liquid interface and provides new insights into interfacial studies in electrochemistry and surface science.
Research Organization:
Argonne National Laboratory (ANL); Argonne National Laboratory (ANL), Argonne, IL (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
Horizon 2020; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357; AC02-76SF00515; SC0012704
OSTI ID:
1877089
Alternate ID(s):
OSTI ID: 1970710
Report Number(s):
BNL-223170-2022-JAAM
Journal Information:
ACS Energy Letters, Journal Name: ACS Energy Letters Vol. 7; ISSN 2380-8195
Publisher:
American Chemical Society (ACS)Copyright Statement
Country of Publication:
United States
Language:
English

References (26)

Suppressing Surface Lattice Oxygen Release of Li-Rich Cathode Materials via Heterostructured Spinel Li 4 Mn 5 O 12 Coating journal May 2018
Atomic Layer Deposition for Lithium-Based Batteries journal September 2016
Thermodynamics of Ti-H2O-F(-Fe) systems at 298 K journal April 1990
Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights journal October 2015
Structural and Electrochemical Impacts of Mg/Mn Dual Dopants on the LiNiO 2 Cathode in Li-Metal Batteries journal March 2020
Examination of Near-Electrode Concentration Gradients and Kinetic Impacts on the Electrochemical Reduction of CO 2 using Surface-Enhanced Infrared Spectroscopy journal April 2018
Rutile-TiO 2 Nanocoating for a High-Rate Li 4 Ti 5 O 12 Anode of a Lithium-Ion Battery journal April 2012
Polarization-Induced Local pH Swing Promotes Pd-Catalyzed CO 2 Hydrogenation journal July 2020
Revealing the Dynamics and Roles of Iron Incorporation in Nickel Hydroxide Water Oxidation Catalysts journal October 2021
Tuning Sn-Catalysis for Electrochemical Reduction of CO 2 to CO via the Core/Shell Cu/SnO 2 Structure journal March 2017
Zn/MnO 2 Battery Chemistry With H + and Zn 2+ Coinsertion journal July 2017
Energy and fuels from electrochemical interfaces journal December 2016
Electrochemical ion insertion from the atomic to the device scale journal May 2021
Phase segregation reversibility in mixed-metal hydroxide water oxidation catalysts journal August 2020
Enhancing the performances of Li-ion batteries by carbon-coating: present and future journal January 2012
Atomic layer deposition of solid-state electrolyte coated cathode materials with superior high-voltage cycling behavior for lithium ion battery application journal January 2014
Self-generated concentration and modulus gradient coating design to protect Si nano-wire electrodes during lithiation journal January 2016
Strategies for stable water splitting via protected photoelectrodes journal January 2017
Harnessing the surface structure to enable high-performance cathode materials for lithium-ion batteries journal January 2020
Quantitative temporally and spatially resolved X-ray fluorescence microprobe characterization of the manganese dissolution-deposition mechanism in aqueous Zn/α-MnO 2 batteries journal January 2020
Uncovering phase transformation, morphological evolution, and nanoscale color heterogeneity in tungsten oxide electrochromic materials journal January 2020
Role of surface coating on cathode materials for lithium-ion batteries journal January 2010
Comparison of the rate capability of nanostructured amorphous and anatase TiO 2 for lithium insertion using anodic TiO 2 nanotube arrays journal May 2009
Electronic structure of titania aerogels from soft x-ray absorption spectroscopy journal June 2004
Reining in dissolved transition-metal ions journal July 2020
Suppression of Cobalt Dissolution from the LiCoO[sub 2] Cathodes with Various Metal-Oxide Coatings journal January 2003

Similar Records

Operando characterization and regulation of metal dissolution and redeposition dynamics near battery electrode surface
Journal Article · Wed Apr 19 20:00:00 EDT 2023 · Nature Nanotechnology · OSTI ID:1974182

Related Subjects

25 ENERGY STORAGE
dissolution
electrodes
electrolytes
layers
oxides