Bio‐Based Piezo‐ and Thermoresistive Photocurable Sensing Materials from Acrylated Epoxidized Soybean Oil

Mendes‐Felipe, Cristian; Costa, Pedro; Roppolo, Ignazio; Sangermano, Marco; Lanceros‐Mendez, Senentxu

doi:10.1002/mame.202100934

Title: Bio‐Based Piezo‐ and Thermoresistive Photocurable Sensing Materials from Acrylated Epoxidized Soybean Oil

Journal Article · Fri Apr 15 00:00:00 EDT 2022 · Macromolecular Materials and Engineering

DOI:https://doi.org/10.1002/mame.202100934· OSTI ID:1876501

^[1]; Costa, Pedro ^[2]; Roppolo, Ignazio ^[3]; Sangermano, Marco ^[4]; Lanceros‐Mendez, Senentxu ^[5]

BCMaterials Basque Center for Materials Applications and Nanostructures UPV/EHU Science Park Leioa 48940 Spain, Dipartimento di Scienza Applicata e Tecnologia (DISAT) Politecnico di Torino C.so Duca Degli Abruzzi 24 Torino 10129 Italy
Center of Physics University of Minho Campus de Gualtar Braga 4710‐057 Portugal, Institute for Polymers and Composites IPC University of Minho Guimarães 4804‐533 Portugal
Dipartimento di Scienza Applicata e Tecnologia (DISAT) Politecnico di Torino C.so Duca Degli Abruzzi 24 Torino 10129 Italy, Center for Sustainable Future Technologies Istituto Italiano di Tecnologia Via Livorno 60 Torino 10144 Italy
Dipartimento di Scienza Applicata e Tecnologia (DISAT) Politecnico di Torino C.so Duca Degli Abruzzi 24 Torino 10129 Italy
BCMaterials Basque Center for Materials Applications and Nanostructures UPV/EHU Science Park Leioa 48940 Spain, Ikerbasque Basque Foundation for Science Bilbao 48009 Spain

Abstract Bio‐based photocurable polymers are increasingly in demand as environmentally friendly materials for advanced applications. Together with functional fillers, these represent a next step for the generation of functional and active smart materials, compatible with additive manufacturing technologies. Herein, acrylated epoxidized soybean oil (AESO) mixed with different amounts of reduced graphene oxide (rGO) up to 6 wt% in order to obtain UV‐curable piezoresistive and thermoresistive materials, is reported. It is shown that the addition of rGO to AESO hinders the curing process, but always maintains double bond conversions higher than 50%. Composites are characterized by a good dispersion of micrometric filler clusters. Further, the thermal stabilities are close to 300 °C and crosslinking degrees are above 1.75 mmol cm ^–3 . The Young modulus of the composites decreases with the addition of the rGO fillers, in particular for the higher filler contents, and electrical conductivities up to 0.13 S m ^–1 are obtained for the composites with the highest rGO content. UV‐curable composites with piezoresistive and thermoresistive responses suitable for applications are thus obtained, characterized by gauge factors around 26 for deformations up to 2% and maximum thermoresistive sensitivity of S = 0.43, values similar to the values obtained for petroleum‐based materials.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1876501

Journal Information:: Macromolecular Materials and Engineering, Journal Name: Macromolecular Materials and Engineering Vol. 307 Journal Issue: 7; ISSN 1438-7492

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (59)

Electromechanical performance of poly(vinylidene fluoride)/carbon nanotube composites for strain sensor applications Ferrreira, A.; Rocha, J. G.; Ansón-Casaos, A. Sensors and Actuators A: Physical, Vol. 178 https://doi.org/10.1016/j.sna.2012.01.041	journal	May 2012
Polymer-based sensors: A review Cichosz, Stefan; Masek, Anna; Zaborski, Marian Polymer Testing, Vol. 67 https://doi.org/10.1016/j.polymertesting.2018.03.024	journal	May 2018
Multifunctional wax based conductive and piezoresistive nanocomposites for sensing applications Brito-Pereira, R.; Tubio, C. R.; Costa, P. Composites Science and Technology, Vol. 213 https://doi.org/10.1016/j.compscitech.2021.108892	journal	September 2021
Polymer-based smart materials by printing technologies: Improving application and integration Oliveira, J.; Correia, V.; Castro, H. Additive Manufacturing, Vol. 21 https://doi.org/10.1016/j.addma.2018.03.012	journal	May 2018
New UV‐Curable Anticorrosion Coatings from Vegetable Oils Noè, Camilla; Iannucci, Leonardo; Malburet, Samuel Macromolecular Materials and Engineering, Vol. 306, Issue 6 https://doi.org/10.1002/mame.202100029	journal	March 2021
High biorenewable content acrylate photocurable resins for DLP 3D printing Lebedevaite, Migle; Talacka, Vaidas; Ostrauskaite, Jolita Journal of Applied Polymer Science, Vol. 138, Issue 16 https://doi.org/10.1002/app.50233	journal	November 2020
Industry 4.0: state of the art and future trends Xu, Li Da; Xu, Eric L.; Li, Ling International Journal of Production Research, Vol. 56, Issue 8 https://doi.org/10.1080/00207543.2018.1444806	journal	March 2018
DLP 4D‐Printing of Remotely, Modularly, and Selectively Controllable Shape Memory Polymer Nanocomposites Embedding Carbon Nanotubes Cortés, Alejandro; Cosola, Andrea; Sangermano, Marco Advanced Functional Materials, Vol. 31, Issue 50 https://doi.org/10.1002/adfm.202106774	journal	September 2021
Water-Based Graphene Inks for All-Printed Temperature and Deformation Sensors Franco, Miguel; Alves, Raquel; Perinka, Nikola ACS Applied Electronic Materials, Vol. 2, Issue 9 https://doi.org/10.1021/acsaelm.0c00508	journal	August 2020
One-pot synthesis of conducting graphene–polymer composites and their strain sensing application Eswaraiah, Varrla; Balasubramaniam, Krishnan; Ramaprabhu, Sundara Nanoscale, Vol. 4, Issue 4 https://doi.org/10.1039/c2nr11555g	journal	January 2012
Acrylated vegetable oils as photocrosslinkable materials Pelletier, Hélène; Belgacem, Naceur; Gandini, Alessandro Journal of Applied Polymer Science, Vol. 99, Issue 6 https://doi.org/10.1002/app.22322	journal	January 2006
Experimental investigation of the thermoresistive response of multiwall carbon nanotube/polysulfone composites under heating-cooling cycles Cen-Puc, M.; Pool, G.; Oliva-Avilés, A. I. Composites Science and Technology, Vol. 151 https://doi.org/10.1016/j.compscitech.2017.08.003	journal	October 2017
Photocuring of Epoxidized Cardanol for Biobased Composites with Microfibrillated Cellulose Dalle Vacche, Sara; Vitale, Alessandra; Bongiovanni, Roberta Molecules, Vol. 24, Issue 21 https://doi.org/10.3390/molecules24213858	journal	October 2019
Advanced elastomer nano-composites based on CNT-hybrid filler systems Lorenz, H.; Fritzsche, J.; Das, A. Composites Science and Technology, Vol. 69, Issue 13 https://doi.org/10.1016/j.compscitech.2009.05.014	journal	October 2009
Cationic photocured epoxy nanocomposites filled with different carbon fillers Martin-Gallego, M.; Hernández, M.; Lorenzo, V. Polymer, Vol. 53, Issue 9 https://doi.org/10.1016/j.polymer.2012.02.054	journal	April 2012
The use of renewable feedstock in UV-curable materials – A new age for polymers and green chemistry Fertier, Laurent; Koleilat, Houria; Stemmelen, Mylène Progress in Polymer Science, Vol. 38, Issue 6 https://doi.org/10.1016/j.progpolymsci.2012.12.002	journal	June 2013
UV-cured transparent magnetic polymer nanocomposites Nardi, Tommaso; Sangermano, Marco; Leterrier, Yves Polymer, Vol. 54, Issue 17 https://doi.org/10.1016/j.polymer.2013.06.052	journal	August 2013
High dielectric constant UV curable polyurethane acrylate/indium tin oxide composites for capacitive sensing Mendes-Felipe, Cristian; Barbosa, J. C.; Gonçalves, Sérgio Composites Science and Technology, Vol. 199 https://doi.org/10.1016/j.compscitech.2020.108363	journal	October 2020
Synthesis and Characterization of Fiber-Reinforced Resorcinol Epoxy Acrylate Applied to Stereolithography 3D Printing Desai, Prashil. Dharmesh.; Jagtap, Ramanand. Namdev. ACS Omega, Vol. 6, Issue 46 https://doi.org/10.1021/acsomega.1c04566	journal	November 2021
Photo-curing 3D printing of micro-scale bamboo fibers reinforced palm oil-based thermosets composites Wu, Yuchao; Li, Chao; Chen, Tingting Composites Part A: Applied Science and Manufacturing, Vol. 152 https://doi.org/10.1016/j.compositesa.2021.106676	journal	January 2022
Photopolymerization of Pollen Based Biosourced Composites and Applications in 3D and 4D Printing Zhang, Yijun; Chen, Hong; Liu, Shaohui Macromolecular Materials and Engineering, Vol. 306, Issue 6 https://doi.org/10.1002/mame.202000774	journal	April 2021
Flexible and Stretchable Temperature Sensors Fabricated Using Solution‐Processable Conductive Polymer Composites Dan, Li; Elias, Anastasia L. Advanced Healthcare Materials, Vol. 9, Issue 16 https://doi.org/10.1002/adhm.202000380	journal	June 2020
Gas sensors using carbon nanomaterials: A review Llobet, Eduard Sensors and Actuators B: Chemical, Vol. 179 https://doi.org/10.1016/j.snb.2012.11.014	journal	March 2013
Recent Advances in Carbon Material‐Based Multifunctional Sensors and Their Applications in Electronic Skin Systems Guo, Yunjian; Wei, Xiao; Gao, Song Advanced Functional Materials, Vol. 31, Issue 40 https://doi.org/10.1002/adfm.202104288	journal	July 2021
Acryloyl-group functionalized graphene for enhancing thermal and mechanical properties of acrylated epoxidized soybean oil UV-curable based coatings Dong, Bowen; Yuan, Yan; Luo, Jing Progress in Organic Coatings, Vol. 118 https://doi.org/10.1016/j.porgcoat.2018.01.020	journal	May 2018
Sensors for daily life: A review Javaid, Mohd; Haleem, Abid; Rab, Shanay Sensors International, Vol. 2 https://doi.org/10.1016/j.sintl.2021.100121	journal	January 2021
Recent advances in vegetable oil-based polymers and their composites Zhang, Chaoqun; Garrison, Thomas F.; Madbouly, Samy A. Progress in Polymer Science, Vol. 71 https://doi.org/10.1016/j.progpolymsci.2016.12.009	journal	August 2017
Polycarbonate based multifunctional self-sensing 2D and 3D printed structures for aeronautic applications Costa, P.; Dios, J. R.; Cardoso, J. Smart Materials and Structures, Vol. 30, Issue 8 https://doi.org/10.1088/1361-665X/ac0cbe	journal	July 2021
Thermoresistive mechanisms of carbon nanotube/polymer composites Cen-Puc, M.; Oliva-Avilés, A. I.; Avilés, F. Physica E: Low-dimensional Systems and Nanostructures, Vol. 95 https://doi.org/10.1016/j.physe.2017.09.001	journal	January 2018
Photopolymerization of Acrylated Epoxidized Soybean Oil: A Photocalorimetry-Based Kinetic Study Kousaalya, Adhimoolam Bakthavachalam; Ayalew, Beshah; Pilla, Srikanth ACS Omega, Vol. 4, Issue 26 https://doi.org/10.1021/acsomega.9b02680	journal	December 2019
Influence of photoinitiator and temperature on photocross-linking kinetics of acrylated epoxidized soybean oil and properties of the resulting polymers Lebedevaite, Migle; Ostrauskaite, Jolita Industrial Crops and Products, Vol. 161 https://doi.org/10.1016/j.indcrop.2020.113210	journal	March 2021
Enhancing water resistance of interface between starch films and acrylated epoxidized soybean oil coating Meng, Linghan; Li, Sheng; Yang, Weidong Progress in Organic Coatings, Vol. 163 https://doi.org/10.1016/j.porgcoat.2021.106646	journal	February 2022
Sensors and actuators based on carbon nanotubes and their composites: A review Li, Chunyu; Thostenson, Erik T.; Chou, Tsu-Wei Composites Science and Technology, Vol. 68, Issue 6 https://doi.org/10.1016/j.compscitech.2008.01.006	journal	May 2008
The world of smart healable materials Murphy, Erin B.; Wudl, Fred Progress in Polymer Science, Vol. 35, Issue 1-2 https://doi.org/10.1016/j.progpolymsci.2009.10.006	journal	January 2010
State-of-the-Art and Future Challenges of UV Curable Polymer-Based Smart Materials for Printing Technologies Mendes-Felipe, Cristian; Oliveira, Juliana; Etxebarria, Ikerne Advanced Materials Technologies, Vol. 4, Issue 3 https://doi.org/10.1002/admt.201800618	journal	January 2019
Sheet molding compound resins from soybean oil: Thickening behavior and mechanical properties Lu, Jue; Wool, Richard P. Polymer Engineering & Science, Vol. 47, Issue 9 https://doi.org/10.1002/pen.20846	journal	January 2007
Sustainable polymers from renewable resources Zhu, Yunqing; Romain, Charles; Williams, Charlotte K. Nature, Vol. 540, Issue 7633 https://doi.org/10.1038/nature21001	journal	December 2016
Development and application of triglyceride-based polymers and composites Khot, Shrikant N.; Lascala, John J.; Can, Erde Journal of Applied Polymer Science, Vol. 82, Issue 3 https://doi.org/10.1002/app.1897	journal	January 2001
Importance of Sustainable Mineral Resource Management in Implementing the Circular Economy (CE) Model and the European Green Deal Strategy Smol, Marzena; Marcinek, Paulina; Duda, Joanna Resources, Vol. 9, Issue 5 https://doi.org/10.3390/resources9050055	journal	May 2020
Sensors for Agriculture and the Food Industry Li, Suiqiong; Simonian, Aleksandr; Chin, Bryan A. The Electrochemical Society Interface, Vol. 19, Issue 4 https://doi.org/10.1149/2.F05104if	journal	January 2010
Stimuli responsive UV cured polyurethane acrylated/carbon nanotube composites for piezoresistive sensing Mendes-Felipe, C.; Oliveira, J.; Costa, P. European Polymer Journal, Vol. 120 https://doi.org/10.1016/j.eurpolymj.2019.109226	journal	November 2019
Internet of Things for In-Home Health Monitoring Systems: Current Advances, Challenges and Future Directions Philip, Nada Y.; Rodrigues, Joel J. P. C.; Wang, Honggang IEEE Journal on Selected Areas in Communications, Vol. 39, Issue 2 https://doi.org/10.1109/JSAC.2020.3042421	journal	February 2021
Development of linseed oil–TiO ₂ green nanocomposites as antimicrobial coatings Díez-Pascual, Ana M.; Díez-Vicente, Angel L. Journal of Materials Chemistry B, Vol. 3, Issue 21 https://doi.org/10.1039/C5TB00209E	journal	January 2015
High-performance graphene-based carbon nanofiller/polymer composites for piezoresistive sensor applications Costa, P.; Nunes-Pereira, J.; Oliveira, J. Composites Science and Technology, Vol. 153 https://doi.org/10.1016/j.compscitech.2017.11.001	journal	December 2017
Photocurable magnetic materials with tailored functional properties Mendes-Felipe, Cristian; Garcia, Ander; Salazar, Daniel Composites Part C: Open Access, Vol. 5 https://doi.org/10.1016/j.jcomc.2021.100143	journal	July 2021
Vat Photopolymerization 3D Printing of Advanced Soft Sensors and Actuators: From Architecture to Function Zhao, Wenyu; Wang, Ziya; Zhang, Jianpeng Advanced Materials Technologies, Vol. 6, Issue 8 https://doi.org/10.1002/admt.202001218	journal	April 2021
Piezoresistive polymer blends for electromechanical sensor applications Costa, P.; Oliveira, J.; Horta-Romarís, Laura Composites Science and Technology, Vol. 168 https://doi.org/10.1016/j.compscitech.2018.10.022	journal	November 2018
Development of an Innovative Biobased UV Coating Synthesized from Acrylated Epoxidized Soybean Oil and Poly(octamethylene maleate (anhydride) citrate) Tang, Qiuyu; Li, Qian; Luo, Yunhan Industrial & Engineering Chemistry Research, Vol. 60, Issue 27 https://doi.org/10.1021/acs.iecr.1c01258	journal	June 2021
Epoxy-Graphene UV-cured nanocomposites Martin-Gallego, M.; Verdejo, R.; Lopez-Manchado, M. A. Polymer, Vol. 52, Issue 21 https://doi.org/10.1016/j.polymer.2011.08.039	journal	September 2011
Study of graphene oxide-based 3D printable composites: Effect of the in situ reduction Chiappone, Annalisa; Roppolo, Ignazio; Naretto, Eric Composites Part B: Engineering, Vol. 124 https://doi.org/10.1016/j.compositesb.2017.05.049	journal	September 2017
The role of disorder on the AC and DC electrical conductivity of vapour grown carbon nanofibre/epoxy composites Cardoso, P.; Silva, J.; Klosterman, D. Composites Science and Technology, Vol. 72, Issue 2 https://doi.org/10.1016/j.compscitech.2011.11.008	journal	January 2012
Photoinitiator Free Resins Composed of Plant-Derived Monomers for the Optical µ-3D Printing of Thermosets Lebedevaite, Migle; Ostrauskaite, Jolita; Skliutas, Edvinas Polymers, Vol. 11, Issue 1 https://doi.org/10.3390/polym11010116	journal	January 2019
Eco-friendly castor oil-based UV-curable urethane acrylate zinc oxide nanocomposites: Synthesis and viscoelastic behavior Madhi, Abbas; S. Hadavand, Behzad Journal of Composite Materials, Vol. 54, Issue 1 https://doi.org/10.1177/0021998319858017	journal	June 2019
Percolation and Conduction Kirkpatrick, Scott Reviews of Modern Physics, Vol. 45, Issue 4, p. 574-588 https://doi.org/10.1103/RevModPhys.45.574	journal	October 1973
Influence of Network Structure on Glass Transition Temperature of Elastomers Bandzierz, Katarzyna; Reuvekamp, Louis; Dryzek, Jerzy Materials, Vol. 9, Issue 7 https://doi.org/10.3390/ma9070607	journal	July 2016
Highly Sensitive Piezoresistive Graphene-Based Stretchable Composites for Sensing Applications Costa, P.; Gonçalves, S.; Mora, H. ACS Applied Materials & Interfaces, Vol. 11, Issue 49 https://doi.org/10.1021/acsami.9b19294	journal	November 2019
A Bio-Based Resin for a Multi-Scale Optical 3D Printing Skliutas, Edvinas; Lebedevaite, Migle; Kasetaite, Sigita Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-66618-1	journal	June 2020
Transparent and Conductive Graphene Oxide/Poly(ethylene glycol) diacrylate Coatings Obtained by Photopolymerization Sangermano, Marco; Marchi, Sophie; Valentini, Luca Macromolecular Materials and Engineering, Vol. 296, Issue 5 https://doi.org/10.1002/mame.201000372	journal	December 2010
Electrical behavior of a graphene/PEKK and carbon black/PEKK nanocomposites in the vicinity of the percolation threshold Bessaguet, C.; Dantras, E.; Michon, G. Journal of Non-Crystalline Solids, Vol. 512 https://doi.org/10.1016/j.jnoncrysol.2019.02.017	journal	May 2019

Similar Records

Biorenewable tough blends of polylactide and acrylated epoxidized soybean oil compatibilized by a polylactide star polymer

Journal Article · Fri Feb 26 00:00:00 EST 2016 · Macromolecules · OSTI ID:1876501

Mauck, Sheli C.; Wang, Shu; Ding, Wenyue; +5 more

Photo‐Curing 3D Printing of Thermosetting Sacrificial Tooling for Fabricating Fiber‐Reinforced Hollow Composites

Journal Article · Sun Feb 26 00:00:00 EST 2023 · Advanced Functional Materials · OSTI ID:1876501

Zhao, Baoming; Hao, Cheng; Chang, Yu‐Chung; +5 more

Mechanically and Thermally Enhanced 3D-Printed Photocurable Polymer Nanocomposites Containing Functionalized Chitin Nanowhiskers by Stereolithography

Journal Article · Tue Mar 29 00:00:00 EDT 2022 · ACS Applied Polymer Materials · OSTI ID:1876501

Maalihan, Reymark D.; Chen, Qiyi; Tamura, Hiroshi; +4 more

Title: Bio‐Based Piezo‐ and Thermoresistive Photocurable Sensing Materials from Acrylated Epoxidized Soybean Oil

Citation Formats

References (59)

Similar Records

Related Subjects