Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides

Clites, Mallory; Blickley, Adam; Cullen, David A.; Pomerantseva, Ekaterina

doi:10.1007/s10853-022-07190-z

Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides

Journal Article · Tue Apr 19 04:00:00 EDT 2022 · Journal of Materials Science

DOI:https://doi.org/10.1007/s10853-022-07190-z· OSTI ID:1876288

Clites, Mallory ^[1]; Blickley, Adam ^[1]; ^[2]; ^[1]

Drexel Univ., Philadelphia, PA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Tungsten oxide, WO₃·nH₂O, is a unique layered oxide material that offers enhanced performance in electrochromic and energy storage applications. Herein, we report the formation of a new, never previously synthesized, Na-containing layered tungsten oxide phase, Na_0.20WO₃·0.81H₂O, using a chemical preintercalation approach. The structure and composition of this novel phase were investigated via microscopy, spectroscopy, and diffraction methods. Electrochemical cycling of Na_0.20WO₃·0.81H₂O electrodes revealed initial discharge capacities of 37.43 mAh g^-1, 480.8 mAh g^-1, and 253.2 mAh g^-1 in aqueous H₂SO₄ cells (potential window of - 0.2–0.8 V vs. Ag/AgCl), non-aqueous Li-ion cells (potential window of 0.1–4.0 V vs. Li/Li⁺), and non-aqueous Na-ion cells (potential window of 0.1–4.0 V vs. Na/Na⁺), respectively. Additionally, a reversible, pressure-induced color change from pale yellow to dark brown/black was observed for the Na_0.20WO₃·0.81H₂O sample when it was placed under pressures of 1000 psi or higher. Our results demonstrate the viability of chemical preintercalation synthesis approach to produce new oxide phases with interesting functional properties.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1876288

Journal Information:: Journal of Materials Science, Journal Name: Journal of Materials Science Journal Issue: 16 Vol. 57; ISSN 0022-2461

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemical preintercalation
confined water
energy storage
layered materials
tungsten oxide

Chemical preintercalation synthesis approach for the formation of new layered tungsten oxides

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