Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy

Savee, John D.; Sztáray, Bálint; Hemberger, Patrick; Zádor, Judit; Bodi, Andras; Osborn, David L.

doi:10.1039/D2FD00028H

Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy

Journal Article · Fri Oct 21 00:00:00 EDT 2022 · Faraday Discussions

DOI:https://doi.org/10.1039/D2FD00028H· OSTI ID:1875935

Savee, John D. ^[1]; ^[2]; ^[3]; ^[1]; ^[3]; ^[1]

Combustion Research Facility, Sandia National Laboratories, Mailstop 9055, Livermore, California, 94551, USA
Department of Chemistry, University of the Pacific, Stockton, California, USA
Laboratory for Synchrotron Radiation and Femtochemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland

The unimolecular isomerisation of the propargyl + propargyl “head-to-head” adduct, 1,5-hexadiyne to fulvene and benzene via 3,4-dimethylenecyclobut-1-ene (all C ₆ H ₆ ) was studied in the high-pressure limit by threshold photoelectron spectroscopy.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1875935

Journal Information:: Faraday Discussions, Journal Name: Faraday Discussions Vol. 238; ISSN 1359-6640; ISSN FDISE6

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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