Kinetic arrest, dynamical transitions, and activated relaxation in dense fluids of attractive nonspherical colloids

Zhang, Rui; Schweizer, Kenneth S.

doi:10.1103/physreve.83.060502

Kinetic arrest, dynamical transitions, and activated relaxation in dense fluids of attractive nonspherical colloids

Journal Article · Tue Jun 28 00:00:00 EDT 2011 · Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics

DOI:https://doi.org/10.1103/physreve.83.060502· OSTI ID:1875528

Zhang, Rui ^[1]; Schweizer, Kenneth S. ^[2]

Univ. of Illinois, Urbana, IL (United States); University of Illinois
Univ. of Illinois, Urbana, IL (United States)

The coupled translation-rotation activated dynamics in dense suspensions of attractive homogeneous and Janus uniaxial dicolloids are studied using microscopic statistical mechanical theory. Multiple kinetic arrest transitions and reentrant phenomena are predicted that are associated with fluid, gel, repulsive glass, attractive glass, plastic glass, and novel glass-gel states. Furthermore, the activated relaxation rate is a nonuniversal nonmonotonic function of attraction strength at high volume fractions due to the consequences of a change of the transient localization mechanism from caging to physical bonding.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER46471

OSTI ID:: 1875528

Alternate ID(s):: OSTI ID: 1099683

Journal Information:: Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics, Journal Name: Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics Journal Issue: 6 Vol. 83; ISSN 1539-3755

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (26)

Janus Particle Synthesis and Assembly Jiang, Shan; Chen, Qian; Tripathy, Mukta Advanced Materials, Vol. 22, Issue 10 https://doi.org/10.1002/adma.200904094	journal	January 2010
The glass paradigm for colloidal glasses, gels, and other arrested states driven by attractive interactions Dawson, Kenneth A. Current Opinion in Colloid & Interface Science, Vol. 7, Issue 3-4 https://doi.org/10.1016/S1359-0294(02)00052-3	journal	August 2002
Comparison of Dynamical Heterogeneity in Hard-Sphere and Attractive Glass Formers ^† Reichman, David R.; Rabani, Eran; Geissler, Phillip L. The Journal of Physical Chemistry B, Vol. 109, Issue 30 https://doi.org/10.1021/jp044559n	journal	August 2005
Colloids get complex van Blaaderen, Alfons Nature, Vol. 439, Issue 7076 https://doi.org/10.1038/439545a	journal	February 2006
Anisotropy of building blocks and their assembly into complex structures Glotzer, Sharon C.; Solomon, Michael J. Nature Materials, Vol. 6, Issue 8, p. 557-562 https://doi.org/10.1038/nmat1949	journal	August 2007
One liquid, two glasses Sciortino, Francesco Nature Materials, Vol. 1, Issue 3 https://doi.org/10.1038/nmat752	journal	November 2002
Entropic barriers, activated hopping, and the glass transition in colloidal suspensions Schweizer, Kenneth S.; Saltzman, Erica J. The Journal of Chemical Physics, Vol. 119, Issue 2 https://doi.org/10.1063/1.1578632	journal	July 2003
Optimized Cluster Expansions for Classical Fluids. II. Theory of Molecular Liquids Chandler, David; Andersen, Hans C. The Journal of Chemical Physics, Vol. 57, Issue 5 https://doi.org/10.1063/1.1678513	journal	September 1972
Dynamic arrest in a liquid of symmetric dumbbells: Reorientational hopping for small molecular elongations Moreno, Angel J.; Chong, Song-Ho; Kob, Walter The Journal of Chemical Physics, Vol. 123, Issue 20 https://doi.org/10.1063/1.2085030	journal	November 2005
Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 123, Issue 24 https://doi.org/10.1063/1.2137701	journal	December 2005
Direct imaging of repulsive and attractive colloidal glasses Kaufman, Laura J.; Weitz, David A. The Journal of Chemical Physics, Vol. 125, Issue 7 https://doi.org/10.1063/1.2227386	journal	August 2006
Dynamic free energies, cage escape trajectories, and glassy relaxation in dense fluids of uniaxial hard particles Zhang, Rui; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 133, Issue 10 https://doi.org/10.1063/1.3483601	journal	September 2010
Excess entropy scaling of transport properties in network-forming ionic melts (SiO2 and BeF2) Agarwal, Manish; Singh, Murari; Shadrack Jabes, B. The Journal of Chemical Physics, Vol. 134, Issue 1 https://doi.org/10.1063/1.3521488	journal	January 2011
Colloidal glasses and gels: The interplay of bonding and caging Zaccarelli, E.; Poon, W. C. K. Proceedings of the National Academy of Sciences, Vol. 106, Issue 36 https://doi.org/10.1073/pnas.0902294106	journal	August 2009
Yielding in dense suspensions: cage, bond, and rotational confinements Kramb, Ryan C.; Zukoski, Charles F. Journal of Physics: Condensed Matter, Vol. 23, Issue 3 https://doi.org/10.1088/0953-8984/23/3/035102	journal	December 2010
Ideal glass transitions for hard ellipsoids Letz, M.; Schilling, R.; Latz, A. Physical Review E, Vol. 62, Issue 4 https://doi.org/10.1103/PhysRevE.62.5173	journal	October 2000
Idealized glass transitions for a system of dumbbell molecules Chong, S. -H.; Götze, W. Physical Review E, Vol. 65, Issue 4 https://doi.org/10.1103/PhysRevE.65.041503	journal	April 2002
Random packings of spheres and spherocylinders simulated by mechanical contraction Williams, S. R.; Philipse, A. P. Physical Review E, Vol. 67, Issue 5 https://doi.org/10.1103/PhysRevE.67.051301	journal	May 2003
Ideal vitrification, barrier hopping, and jamming in fluids of modestly anisotropic hard objects Yatsenko, Galina; Schweizer, Kenneth S. Physical Review E, Vol. 76, Issue 4 https://doi.org/10.1103/PhysRevE.76.041506	journal	October 2007
Theory of coupled translational-rotational glassy dynamics in dense fluids of uniaxial particles Zhang, Rui; Schweizer, Kenneth S. Physical Review E, Vol. 80, Issue 1 https://doi.org/10.1103/PhysRevE.80.011502	journal	July 2009
Glass Formation and Shear Elasticity in Dense Suspensions of Repulsive Anisotropic Particles Kramb, R. C.; Zhang, R.; Schweizer, K. S. Physical Review Letters, Vol. 105, Issue 5 https://doi.org/10.1103/PhysRevLett.105.055702	journal	July 2010
Dynamics of Uniaxial Hard Ellipsoids De Michele, Cristiano; Schilling, Rolf; Sciortino, Francesco Physical Review Letters, Vol. 98, Issue 26 https://doi.org/10.1103/PhysRevLett.98.265702	journal	June 2007
Yielding behavior of repulsion- and attraction-dominated colloidal glasses Pham, K. N.; Petekidis, G.; Vlassopoulos, D. Journal of Rheology, Vol. 52, Issue 2 https://doi.org/10.1122/1.2838255	journal	March 2008
Multiple Glassy States in a Simple Model System Pham, K. N. Science, Vol. 296, Issue 5565 https://doi.org/10.1126/science.1068238	journal	April 2002
Improving the Density of Jammed Disordered Packings Using Ellipsoids Donev, A. Science, Vol. 303, Issue 5660 https://doi.org/10.1126/science.1093010	journal	February 2004
Particle dynamics in colloidal suspensions above and below the glass-liquid re-entrance transition Latka, A.; Han, Y.; Alsayed, A. M. EPL (Europhysics Letters), Vol. 86, Issue 5 https://doi.org/10.1209/0295-5075/86/58001	journal	June 2009

Cited By (1)

Monte Carlo simulation of cylinders with short-range attractions Hatch, Harold W.; Mahynski, Nathan A.; Murphy, Ryan P. AIP Advances, Vol. 8, Issue 9 https://doi.org/10.1063/1.5040252	journal	September 2018

Similar Records

Theory of nonlinear elasticity, stress-induced relaxation, and dynamic yielding in dense fluids of hard nonspherical colloids

Journal Article · Tue Apr 17 20:00:00 EDT 2012 · Journal of Chemical Physics · OSTI ID:1876439

Activated dynamics in dense fluids of attractive nonspherical particles. I. Kinetic crossover, dynamic free energies, and the physical nature of glasses and gels

Journal Article · Sun Apr 17 20:00:00 EDT 2011 · Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics · OSTI ID:1875065

Re-entrant kinetic arrest and elasticity of concentrated suspensions of spherical and nonspherical repulsive and attractive colloids

Journal Article · Mon Jan 03 19:00:00 EST 2011 · Journal of Chemical Physics · OSTI ID:1876160

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS

Kinetic arrest, dynamical transitions, and activated relaxation in dense fluids of attractive nonspherical colloids

Citation Formats

References (26)

Cited By (1)

Similar Records

Related Subjects