Integration of high capacity materials into interdigitated mesostructured electrodes for high energy and high power density primary microbatteries

Pikul, James H.; Liu, Jinyun; Braun, Paul V.; King, William P.

doi:10.1016/j.jpowsour.2016.03.034

Integration of high capacity materials into interdigitated mesostructured electrodes for high energy and high power density primary microbatteries

Journal Article · Tue Mar 22 00:00:00 EDT 2016 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2016.03.034· OSTI ID:1875509

Pikul, James H. ^[1]; Liu, Jinyun ^[2]; Braun, Paul V. ^[2]; King, William P. ^[2]

Univ. of Illinois at Urbana-Champaign, IL (United States); University of Illinois
Univ. of Illinois at Urbana-Champaign, IL (United States)

Microbatteries are increasingly important for powering electronic systems, however, the volumetric energy density of microbatteries lags behind that of conventional format batteries. This paper reports a primary microbattery with energy density 45.5 μWh cm^–2 μm^–1 and peak power 5300 μW cm^–2 μm^–1, enabled by the integration of large volume fractions of high capacity anode and cathode chemistry into porous micro-architectures. The interdigitated battery electrodes consist of a lithium metal anode and a mesoporous manganese oxide cathode. The key enabler of the high energy and power density is the integration of the high capacity manganese oxide conversion chemistry into a mesostructured high power interdigitated bicontinuous cathode architecture and an electrodeposited dense lithium metal anode. Here, the resultant energy density is greater than previously reported three-dimensional microbatteries and is comparable to commercial conventional format lithium-based batteries.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-06OR23100; FG02-07ER46471

OSTI ID:: 1875509

Alternate ID(s):: OSTI ID: 1341183

Journal Information:: Journal of Power Sources, Journal Name: Journal of Power Sources Vol. 315; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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