Glass Formation and Shear Elasticity in Dense Suspensions of Repulsive Anisotropic Particles

Kramb, R. C.; Zhang, R.; Schweizer, K. S.; Zukoski, C. F.

doi:10.1103/physrevlett.105.055702

Glass Formation and Shear Elasticity in Dense Suspensions of Repulsive Anisotropic Particles

Journal Article · Wed Jul 28 00:00:00 EDT 2010 · Physical Review Letters

DOI:https://doi.org/10.1103/physrevlett.105.055702· OSTI ID:1875461

Kramb, R. C. ^[1]; Zhang, R. ^[2]; Schweizer, K. S. ^[2]; Zukoski, C. F. ^[2]

Univ. of Illinois, Urbana, IL (United States); University of Illinois
Univ. of Illinois, Urbana, IL (United States)

Kinetic vitrification, shear elasticity, and the approach to jamming are investigated for repulsive nonspherical colloids and contrasted with their spherical analog. Particle anisotropy dramatically increases the volume fraction for kinetic arrest. The shear modulus of all systems increases roughly exponentially with volume fraction, and a universal collapse is achieved based on either the dynamic crossover or random close packing volume fraction as the key nondimensionalizing quantity. As a result, quantitative comparisons with recent microscopic theories are performed and good agreement demonstrated.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: FG02-07ER46453; FG02-07ER46471

OSTI ID:: 1875461

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 5 Vol. 105; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

References (29)

Janus Particle Synthesis and Assembly Jiang, Shan; Chen, Qian; Tripathy, Mukta Advanced Materials, Vol. 22, Issue 10 https://doi.org/10.1002/adma.200904094	journal	January 2010
Subdiffusion and the cage effect studied near the colloidal glass transition Weeks, Eric R.; Weitz, D. A. Chemical Physics, Vol. 284, Issue 1-2 https://doi.org/10.1016/S0301-0104(02)00667-5	journal	November 2002
Dynamical fluctuation effects in glassy colloidal suspensions Schweizer, K. Current Opinion in Colloid & Interface Science, Vol. 12, Issue 6 https://doi.org/10.1016/j.cocis.2007.07.013	journal	December 2007
Synthesis of Anisotropic Nanoparticles by Seeded Emulsion Polymerization Mock, Eric B.; De Bruyn, Hank; Hawkett, Brian S. Langmuir, Vol. 22, Issue 9 https://doi.org/10.1021/la060003a	journal	April 2006
A Metastable van der Waals Gel: Transitioning from Weak to Strong Attractions Kramb, Ryan C.; Zukoski, Charles F. Langmuir, Vol. 24, Issue 14 https://doi.org/10.1021/la800021h	journal	June 2008
Colloids get complex van Blaaderen, Alfons Nature, Vol. 439, Issue 7076 https://doi.org/10.1038/439545a	journal	February 2006
Anisotropy of building blocks and their assembly into complex structures Glotzer, Sharon C.; Solomon, Michael J. Nature Materials, Vol. 6, Issue 8, p. 557-562 https://doi.org/10.1038/nmat1949	journal	August 2007
Effects of shear induced crystallization on the rheology and ageing of hard sphere glasses Koumakis, N.; Schofield, A. B.; Petekidis, G. Soft Matter, Vol. 4, Issue 10 https://doi.org/10.1039/b805171b	journal	January 2008
Entropic barriers, activated hopping, and the glass transition in colloidal suspensions Schweizer, Kenneth S.; Saltzman, Erica J. The Journal of Chemical Physics, Vol. 119, Issue 2 https://doi.org/10.1063/1.1578632	journal	July 2003
Optimized Cluster Expansions for Classical Fluids. II. Theory of Molecular Liquids Chandler, David; Andersen, Hans C. The Journal of Chemical Physics, Vol. 57, Issue 5 https://doi.org/10.1063/1.1678513	journal	September 1972
Dynamic arrest in a liquid of symmetric dumbbells: Reorientational hopping for small molecular elongations Moreno, Angel J.; Chong, Song-Ho; Kob, Walter The Journal of Chemical Physics, Vol. 123, Issue 20 https://doi.org/10.1063/1.2085030	journal	November 2005
Nature of the breakdown in the Stokes-Einstein relationship in a hard sphere fluid Kumar, Sanat K.; Szamel, Grzegorz; Douglas, Jack F. The Journal of Chemical Physics, Vol. 124, Issue 21 https://doi.org/10.1063/1.2192769	journal	June 2006
Ideal glass transitions, shear modulus, activated dynamics, and yielding in fluids of nonspherical objects Yatsenko, Galina; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 126, Issue 1 https://doi.org/10.1063/1.2405354	journal	January 2007
Collisions, caging, thermodynamics, and jamming in the barrier hopping theory of glassy hard sphere fluids Schweizer, Kenneth S.; Yatsenko, Galina The Journal of Chemical Physics, Vol. 127, Issue 16 https://doi.org/10.1063/1.2780861	journal	October 2007
The influence of shape on the glassy dynamics of hard nonspherical particle fluids. I. Dynamic crossover and elasticity Tripathy, Mukta; Schweizer, Kenneth S. The Journal of Chemical Physics, Vol. 130, Issue 24 https://doi.org/10.1063/1.3157279	journal	June 2009
Relaxation processes in supercooled liquids Gotze, W.; Sjogren, L. Reports on Progress in Physics, Vol. 55, Issue 3 https://doi.org/10.1088/0034-4885/55/3/001	journal	March 1992
Observation of a shape-dependent density maximum in random packings and glasses of colloidal silica ellipsoids Sacanna, S.; Rossi, L.; Wouterse, A. Journal of Physics: Condensed Matter, Vol. 19, Issue 37 https://doi.org/10.1088/0953-8984/19/37/376108	journal	August 2007
Glass transition in colloidal hard spheres: Measurement and mode-coupling-theory analysis of the coherent intermediate scattering function van Megen, W.; Underwood, S. M. Physical Review E, Vol. 49, Issue 5 https://doi.org/10.1103/PhysRevE.49.4206	journal	May 1994
Ideal glass transitions for hard ellipsoids Letz, M.; Schilling, R.; Latz, A. Physical Review E, Vol. 62, Issue 4 https://doi.org/10.1103/PhysRevE.62.5173	journal	October 2000
Idealized glass transitions for a system of dumbbell molecules Chong, S. -H.; Götze, W. Physical Review E, Vol. 65, Issue 4 https://doi.org/10.1103/PhysRevE.65.041503	journal	April 2002
Effect of composition changes on the structural relaxation of a binary mixture Götze, W.; Voigtmann, Th. Physical Review E, Vol. 67, Issue 2 https://doi.org/10.1103/PhysRevE.67.021502	journal	February 2003
Mean-field theory, mode-coupling theory, and the onset temperature in supercooled liquids Brumer, Yisroel; Reichman, David R. Physical Review E, Vol. 69, Issue 4 https://doi.org/10.1103/PhysRevE.69.041202	journal	April 2004
Ideal vitrification, barrier hopping, and jamming in fluids of modestly anisotropic hard objects Yatsenko, Galina; Schweizer, Kenneth S. Physical Review E, Vol. 76, Issue 4 https://doi.org/10.1103/PhysRevE.76.041506	journal	October 2007
Theory of coupled translational-rotational glassy dynamics in dense fluids of uniaxial particles Zhang, Rui; Schweizer, Kenneth S. Physical Review E, Vol. 80, Issue 1 https://doi.org/10.1103/PhysRevE.80.011502	journal	July 2009
Effect of mixing and spatial dimension on the glass transition Hajnal, David; Brader, Joseph M.; Schilling, Rolf Physical Review E, Vol. 80, Issue 2 https://doi.org/10.1103/PhysRevE.80.021503	journal	August 2009
Probing the Equilibrium Dynamics of Colloidal Hard Spheres above the Mode-Coupling Glass Transition Brambilla, G.; El Masri, D.; Pierno, M. Physical Review Letters, Vol. 102, Issue 8 https://doi.org/10.1103/PhysRevLett.102.085703	journal	February 2009
Dynamics of Uniaxial Hard Ellipsoids De Michele, Cristiano; Schilling, Rolf; Sciortino, Francesco Physical Review Letters, Vol. 98, Issue 26 https://doi.org/10.1103/PhysRevLett.98.265702	journal	June 2007
Improving the Density of Jammed Disordered Packings Using Ellipsoids Donev, A. Science, Vol. 303, Issue 5660 https://doi.org/10.1126/science.1093010	journal	February 2004
Glassy dynamics in monodisperse hard ellipsoids Pfleiderer, P.; Milinkovic, K.; Schilling, T. EPL (Europhysics Letters), Vol. 84, Issue 1 https://doi.org/10.1209/0295-5075/84/16003	journal	September 2008

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Fluctuations in flow produced by competition between apparent wall slip and dilatancy Larsen, Ryan J.; Kim, Jin-Woong; Zukoski, Charles F. Rheologica Acta, Vol. 53, Issue 4 https://doi.org/10.1007/s00397-014-0764-4	journal	March 2014
Linear and nonlinear rheology and structural relaxation in dense glassy and jammed soft repulsive pNIPAM microgel suspensions Ghosh, Ashesh; Chaudhary, Gaurav; Kang, Jin Gu Soft Matter, Vol. 15, Issue 5 https://doi.org/10.1039/c8sm02014k	journal	January 2019
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