Direct Laser Writing of Photoresponsive Colloids for Microscale Patterning of 3D Porous Structures

George, Matthew C.; Mohraz, Ali; Piech, Martin; Bell, Nelson S.; Lewis, Jennifer A.; Braun, Paul V.

doi:10.1002/adma.200801118

Direct Laser Writing of Photoresponsive Colloids for Microscale Patterning of 3D Porous Structures

Journal Article · Thu Jan 01 23:00:00 EST 2009 · Advanced Materials

DOI:https://doi.org/10.1002/adma.200801118· OSTI ID:1875133

George, Matthew C. ^[1]; Mohraz, Ali ^[2]; Piech, Martin ^[3]; Bell, Nelson S. ^[4]; Lewis, Jennifer A. ^[5]; Braun, Paul V. ^[5]

Univ. of Illinois at Urbana-Champaign, IL (United States); University of Illinois
Univ. of Illinois at Urbana-Champaign, IL (United States); Univ. of California, Irvine, CA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); United Technologies Research Center, East Hartford, CT (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of Illinois at Urbana-Champaign, IL (United States)

3D patterning of colloidal structures is enabled by the phototriggered aggregation of photoresponsive colloids. Here, we use direct laser writing to locally control aggregation behavior of photoresponsive colloids via a 2-photon absorption process. 3D structures composed of porous walls are harvested after rinsing away unexposed colloidal species. Aggregation is fully reversible with sufficient agitation.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: FG02-07ER46471; AC04-94AL85000

OSTI ID:: 1875133

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 1 Vol. 21; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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