Self-Assembly of Partially Charged Diblock Copolymer-Homopolymer Ternary Blends

Zheng, Caini; Zhang, Bo; Bates, Frank S.; Lodge, Timothy P.

doi:10.1021/acs.macromol.2c00518

Self-Assembly of Partially Charged Diblock Copolymer-Homopolymer Ternary Blends

Journal Article · Fri May 27 00:00:00 EDT 2022 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.2c00518· OSTI ID:1874678

Zheng, Caini ^[1]; ^[2]; ^[2]; ^[2]

Univ. of Minnesota, Minneapolis, MN (United States); University of MInnesota Twin Cities
Univ. of Minnesota, Minneapolis, MN (United States)

Ternary blends comprising of a diblock copolymer and the corresponding homopolymers provide ready access to a variety of morphologies, but the impact of charge on their phase behavior has not been studied extensively. Here, three partially charged ternary blends consisting of symmetric poly[(oligo(ethylene glycol) methyl ether methacrylate-co-oligo(ethylene glycol) propyl sodium sulfonate methacrylate)] (POEGMA#), polystyrene (PS), and POEGMA#-PS with different charge fractions were prepared, where # denotes the mole fraction of charged monomers in the POEGMA chain. Here, the phase behavior was systematically studied using small-angle X-ray scattering (SAXS), and isothermal phase diagrams at 120 °C were constructed. The resulting isothermal planes contain a wide lamellar (LAM) phase window with a slight deviation from symmetry for ion-containing ternary blends, due to the homopolymer size difference. Given the absence of any significant change in the phase diagrams as the charge fraction increases, the role of charge is primarily to increase the segregation strength in the ternary system, as in the case of partially charged diblock polymers. In addition, examination of the increase in domain size along the volumetrically symmetric isopleth reveals a “dry-brush” like swelling behavior of homopolymers in all three blends, presumably due to the space-filling nature of the oligomeric ethylene glycol side chains on POEGMA.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Minnesota, Twin Cities, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC); NSF; NNCI

Grant/Contract Number:: SC0017809; AC02-06CH11357

OSTI ID:: 1874678

Alternate ID(s):: OSTI ID: 1873537
OSTI ID: 1877226
OSTI ID: 1906371

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 11 Vol. 55; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Design of bicontinuous polymeric microemulsions Fredrickson, Glenn H.; Bates, Frank S. Journal of Polymer Science Part B: Polymer Physics, Vol. 35, Issue 17 https://doi.org/10.1002/(SICI)1099-0488(199712)35:17<2775::AID-POLB2>3.0.CO;2-Q	journal	December 1997
Prediction of polymer densities Van Krevelen, D. W.; Hoftyzer, P. J. Journal of Applied Polymer Science, Vol. 13, Issue 5 https://doi.org/10.1002/app.1969.070130506	journal	May 1969
Physical Properties of Polymers Handbook Mark, James E. https://doi.org/10.1007/978-0-387-69002-5	book	January 2007
Measurement of molecular dimensions of polystyrene chains in the bulk polymer by low angle neutron diffraction Ballard, D. G. H.; Wignall, G. D.; Schelten, J. European Polymer Journal, Vol. 9, Issue 9 https://doi.org/10.1016/0014-3057(73)90059-1	journal	September 1973
Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts Berthier, C.; Gorecki, W.; Minier, M. Solid State Ionics, Vol. 11, Issue 1 https://doi.org/10.1016/0167-2738(83)90068-1	journal	September 1983
Effect of the molecular weight of the homopolymers on the morphology in ternary blends of polystyrene, polyisoprene, polystyrene-block-polyisoprene copolymer Messé, Loı̈c; Corvazier, Laurence; Ryan, Anthony J. Polymer, Vol. 44, Issue 24 https://doi.org/10.1016/j.polymer.2003.09.021	journal	November 2003
Salt-induced microphase separation in poly(ε-caprolactone)-b-poly(ethylene oxide) block copolymer Huang, Jie; Tong, Zai-Zai; Zhou, Bing Polymer, Vol. 54, Issue 12 https://doi.org/10.1016/j.polymer.2013.03.070	journal	May 2013
Solvation Energy of Ions in Polymers: Effects of Chain Length and Connectivity on Saturated Dipoles near Ions Liu, Lijun; Nakamura, Issei The Journal of Physical Chemistry B, Vol. 121, Issue 14 https://doi.org/10.1021/acs.jpcb.7b00671	journal	March 2017
Influence of Added Salt on Chain Conformations in Poly(ethylene oxide) Melts: SANS Analysis with Complications Xie, Shuyi; Zhang, Bo; Mao, Yimin Macromolecules, Vol. 53, Issue 16 https://doi.org/10.1021/acs.macromol.0c01194	journal	August 2020
Phase Behavior of Diblock Copolymer–Homopolymer Ternary Blends with a Compositionally Asymmetric Diblock Copolymer Zhang, Bo; Xie, Shuyi; Lodge, Timothy P. Macromolecules, Vol. 54, Issue 1 https://doi.org/10.1021/acs.macromol.0c01745	journal	December 2020
Coexistence of Polymeric Microemulsion with Homopolymer-Rich Phases Spencer, Russell K. W.; Matsen, Mark W. Macromolecules, Vol. 54, Issue 3 https://doi.org/10.1021/acs.macromol.0c02668	journal	January 2021
Phase Behavior of Salt-Doped A/B/AB Ternary Polymer Blends: The Role of Homopolymer Distribution Xie, Shuyi; Zhang, Bo; Bates, Frank S. Macromolecules, Vol. 54, Issue 14 https://doi.org/10.1021/acs.macromol.1c00928	journal	July 2021
Effects of Ion-Induced Cross-Linking on the Phase Behavior in Salt-Doped Polymer Blends Ren, Chun-Lai; Nakamura, Issei; Wang, Zhen-Gang Macromolecules, Vol. 49, Issue 1 https://doi.org/10.1021/acs.macromol.5b02229	journal	December 2015
Lithium Salt-Induced Microstructure and Ordering in Diblock Copolymer/Homopolymer Blends Irwin, Matthew T.; Hickey, Robert J.; Xie, Shuyi Macromolecules, Vol. 49, Issue 13 https://doi.org/10.1021/acs.macromol.6b00995	journal	June 2016
Structure–Conductivity Relationships in Ordered and Disordered Salt-Doped Diblock Copolymer/Homopolymer Blends Irwin, Matthew T.; Hickey, Robert J.; Xie, Shuyi Macromolecules, Vol. 49, Issue 18 https://doi.org/10.1021/acs.macromol.6b01553	journal	September 2016
Phase Behavior of Diblock Copolymer–Homopolymer Ternary Blends: Congruent First-Order Lamellar–Disorder Transition Hickey, Robert J.; Gillard, Timothy M.; Irwin, Matthew T. Macromolecules, Vol. 49, Issue 20 https://doi.org/10.1021/acs.macromol.6b01872	journal	October 2016
Quantifying Lithium Salt and Polymer Density Distributions in Nanostructured Ion-Conducting Block Polymers Gartner, Thomas E.; Morris, Melody A.; Shelton, Cameron K. Macromolecules, Vol. 51, Issue 5 https://doi.org/10.1021/acs.macromol.7b02600	journal	February 2018
Solvation and Entropic Regimes in Ion-Containing Block Copolymers Hou, Kevin J.; Qin, Jian Macromolecules, Vol. 51, Issue 19 https://doi.org/10.1021/acs.macromol.8b01616	journal	September 2018
Investigating the Effect of Added Salt on the Chain Dimensions of Poly(ethylene oxide) through Small-Angle Neutron Scattering Loo, Whitney S.; Mongcopa, Katrina I.; Gribble, Daniel A. Macromolecules, Vol. 52, Issue 22 https://doi.org/10.1021/acs.macromol.9b01509	journal	November 2019
Structure and Properties of Bicontinuous Microemulsions from Salt-Doped Ternary Polymer Blends Xie, Shuyi; Meyer, Daniel J.; Wang, En Macromolecules, Vol. 52, Issue 24 https://doi.org/10.1021/acs.macromol.9b01963	journal	December 2019
Effect of Ion Concentration on the Formation of Bicontinuous Microemulsions in Partially Charged Ternary Polymer Blends Shim, Jimin; Xie, Shuyi; Bates, Frank S. Macromolecules, Vol. 52, Issue 23 https://doi.org/10.1021/acs.macromol.9b02104	journal	December 2019
Harnessing the Power of Plastics: Nanostructured Polymer Systems in Lithium-Ion Batteries Morris, Melody A.; An, Hyosung; Lutkenhaus, Jodie L. ACS Energy Letters, Vol. 2, Issue 8 https://doi.org/10.1021/acsenergylett.7b00368	journal	August 2017
Influence of Charge Fraction on the Phase Behavior of Symmetric Single-Ion Conducting Diblock Copolymers Zhang, Bo; Zheng, Caini; Sims, Michael B. ACS Macro Letters, Vol. 10, Issue 8 https://doi.org/10.1021/acsmacrolett.1c00393	journal	July 2021
Bicontinuous Microemulsions in Partially Charged Ternary Polymer Blends Shim, Jimin; Bates, Frank S.; Lodge, Timothy P. ACS Macro Letters, Vol. 8, Issue 9 https://doi.org/10.1021/acsmacrolett.9b00554	journal	August 2019
Formation of a C15 Laves Phase with a Giant Unit Cell in Salt-Doped A/B/AB Ternary Polymer Blends Xie, Shuyi; Lindsay, Aaron P.; Bates, Frank S. ACS Nano, Vol. 14, Issue 10 https://doi.org/10.1021/acsnano.0c06071	journal	August 2020
Nanoporous Polyethylene Thin Films Templated by Polymeric Bicontinuous Microemulsions: Evolution of Morphology on Non-neutral Substrates Jones, Brad H.; Cheng, Kai-Yuan; Holmes, Russell J. ACS Applied Materials & Interfaces, Vol. 3, Issue 10 https://doi.org/10.1021/am2009794	journal	September 2011
Nanoporous Materials Derived from Polymeric Bicontinuous Microemulsions Jones, Brad H.; Lodge, Timothy P. Chemistry of Materials, Vol. 22, Issue 4 https://doi.org/10.1021/cm903408x	journal	February 2010
High-Temperature Nanoporous Ceramic Monolith Prepared from a Polymeric Bicontinuous Microemulsion Template Jones, Brad H.; Lodge, Timothy P. Journal of the American Chemical Society, Vol. 131, Issue 5 https://doi.org/10.1021/ja8092554	journal	January 2009
Gyroid and Other Ordered Morphologies in Single-Ion Conducting Polymers and Their Impact on Ion Conductivity Yan, Lu; Rank, Christina; Mecking, Stefan Journal of the American Chemical Society, Vol. 142, Issue 2 https://doi.org/10.1021/jacs.9b09701	journal	December 2019
Thermodynamics of Block Copolymers with and without Salt Teran, Alexander A.; Balsara, Nitash P. The Journal of Physical Chemistry B, Vol. 118, Issue 1 https://doi.org/10.1021/jp408079z	journal	December 2013
Effects of Ion Solvation on the Miscibility of Binary Polymer Blends ^† Wang, Zhen-Gang The Journal of Physical Chemistry B, Vol. 112, Issue 50 https://doi.org/10.1021/jp806897t	journal	December 2008
Bicontinuous Polymeric Microemulsions from Polydisperse Diblock Copolymers Ellison, Christopher J.; Meuler, Adam J.; Qin, Jian The Journal of Physical Chemistry B, Vol. 113, Issue 12 https://doi.org/10.1021/jp807343b	journal	December 2008
Model Bicontinuous Microemulsions in Ternary Homopolymer/Block Copolymer Blends Hillmyer, Marc A.; Maurer, Wayne W.; Lodge, Timothy P. The Journal of Physical Chemistry B, Vol. 103, Issue 23 https://doi.org/10.1021/jp990089z	journal	June 1999
Ternary Polymer Blends as Model Surfactant Systems Washburn, Newell R.; Lodge, Timothy P.; Bates, Frank S. The Journal of Physical Chemistry B, Vol. 104, Issue 30 https://doi.org/10.1021/jp994230f	journal	August 2000
Ordered structure in mixtures of a block copolymer and homopolymers. 1. Solubilization of low molecular weight homopolymers Tanaka, Hideaki; Hasegawa, Hirokazu; Hashimoto, Takeji Macromolecules, Vol. 24, Issue 1 https://doi.org/10.1021/ma00001a037	journal	January 1991
A Study of the Influence of LiI on the Chain Conformations of Poly(ethylene oxide) in the Melt by Small-Angle Neutron Scattering and Molecular Dynamics Simulations Annis, B. K.; Kim, Man-Ho; Wignall, George D. Macromolecules, Vol. 33, Issue 20 https://doi.org/10.1021/ma000452w	journal	October 2000
The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M. Macromolecules, Vol. 27, Issue 15 https://doi.org/10.1021/ma00093a006	journal	July 1994
Linear Viscoelasticity of a Polymeric Bicontinuous Microemulsion Burghardt, Wesley R.; Krishnan, Kasiraman; Bates, Frank S. Macromolecules, Vol. 35, Issue 10 https://doi.org/10.1021/ma012087u	journal	May 2002
Fluctuation Effects in Ternary AB + A + B Polymeric Emulsions Düchs, Dominik; Ganesan, Venkat; Fredrickson, Glenn H. Macromolecules, Vol. 36, Issue 24 https://doi.org/10.1021/ma030201y	journal	December 2003
Stability of the Gyroid Phase in Diblock Copolymers at Strong Segregation Cochran, Eric W.; Garcia-Cervera, Carlos J.; Fredrickson, Glenn H. Macromolecules, Vol. 39, Issue 7 https://doi.org/10.1021/ma0527707	journal	April 2006
Thermodynamic Properties of Block Copolymer Electrolytes Containing Imidazolium and Lithium Salts Wanakule, Nisita S.; Virgili, Justin M.; Teran, Alexander A. Macromolecules, Vol. 43, Issue 19 https://doi.org/10.1021/ma1013786	journal	October 2010
Thermodynamic and Structural Changes in Ion-Containing Symmetric Diblock Copolymers: A Small-Angle X-ray Scattering Study Gunkel, Ilja; Thurn-Albrecht, Thomas Macromolecules, Vol. 45, Issue 1 https://doi.org/10.1021/ma201334h	journal	December 2011
Nanoporous Poly(3,4-ethylenedioxythiophene) Derived from Polymeric Bicontinuous Microemulsion Templates Jones, Brad H.; Cheng, Kai-Yuan; Holmes, Russell J. Macromolecules, Vol. 45, Issue 1 https://doi.org/10.1021/ma202239b	journal	December 2011
Salt Doping in PEO-Containing Block Copolymers: Counterion and Concentration Effects Young, Wen-Shiue; Epps, Thomas H. Macromolecules, Vol. 42, Issue 7 https://doi.org/10.1021/ma802799p	journal	April 2009
Ordered Network Mesostructures in Block Polymer Materials Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S. Macromolecules, Vol. 42, Issue 19 https://doi.org/10.1021/ma9009593	journal	October 2009
Phase Behavior of Polystyrene−Poly(2-vinylpyridine) Diblock Copolymers Schulz, Mark F.; Khandpur, Ashish K.; Bates, Frank S. Macromolecules, Vol. 29, Issue 8 https://doi.org/10.1021/ma951714a	journal	January 1996
Phase Behavior of Ternary Homopolymer/Diblock Blends: Influence of Relative Chain Lengths Janert, Philipp K.; Schick, M. Macromolecules, Vol. 30, Issue 1 https://doi.org/10.1021/ma961068v	journal	January 1997
Molecular Dynamics Simulations of Poly(ethylene oxide)/LiI Melts. 1. Structural and Conformational Properties Borodin, Oleg; Smith, Grant D. Macromolecules, Vol. 31, Issue 23 https://doi.org/10.1021/ma980838v	journal	November 1998
Mesoporous Membrane Templated by a Polymeric Bicontinuous Microemulsion Zhou, Ning; Bates, Frank S.; Lodge, Timothy P. Nano Letters, Vol. 6, Issue 10 https://doi.org/10.1021/nl061765t	journal	October 2006
Hierarchically Structured Materials from Block Polymer Confinement within Bicontinuous Microemulsion-Derived Nanoporous Polyethylene Jones, Brad H.; Lodge, Timothy P. ACS Nano, Vol. 5, Issue 11 https://doi.org/10.1021/nn203096x	journal	October 2011
Electrostatic control of block copolymer morphology Sing, Charles E.; Zwanikken, Jos W.; Olvera de la Cruz, Monica Nature Materials, Vol. 13, Issue 7 https://doi.org/10.1038/nmat4001	journal	June 2014
Nanocasting nanoporous inorganic and organic materials from polymeric bicontinuous microemulsion templates Jones, Brad H.; Lodge, Timothy P. Polymer Journal, Vol. 44, Issue 2 https://doi.org/10.1038/pj.2011.136	journal	February 2012
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries Xue, Zhigang; He, Dan; Xie, Xiaolin Journal of Materials Chemistry A, Vol. 3, Issue 38 https://doi.org/10.1039/C5TA03471J	journal	January 2015
Single lithium-ion conducting solid polymer electrolytes: advances and perspectives Zhang, Heng; Li, Chunmei; Piszcz, Michal Chemical Society Reviews, Vol. 46, Issue 3 https://doi.org/10.1039/C6CS00491A	journal	January 2017
Lithium-ion coordination-induced conformational change of PEG chains in ionic-liquid-based electrolytes Kamiyama, Yuji; Shibata, Masayuki; Kanzaki, Ryo Physical Chemistry Chemical Physics, Vol. 22, Issue 10 https://doi.org/10.1039/C9CP06717E	journal	January 2020
Fluctuations, conformational asymmetry and block copolymer phase behaviour Bates, Frank S.; Schulz, Mark F.; Khandpur, Ashish K. Faraday Discuss., Vol. 98 https://doi.org/10.1039/FD9949800007	journal	January 1994
Dynamics of ternary polymer blends: Disordered, ordered and bicontinuous microemulsion phases Morkved, Terry L.; Chapman, Bryan R.; Bates, Frank S. Faraday Discussions, Vol. 112 https://doi.org/10.1039/a809169b	journal	January 1999
Static and dynamic scattering from ternary polymer blends: Bicontinuous microemulsions, Lifshitz lines, and amphiphilicity Morkved, Terry L.; Stepanek, Petr; Krishnan, Kasiraman The Journal of Chemical Physics, Vol. 114, Issue 16 https://doi.org/10.1063/1.1357800	journal	April 2001
Origin of the scattering peak in microemulsions Teubner, M.; Strey, R. The Journal of Chemical Physics, Vol. 87, Issue 5 https://doi.org/10.1063/1.453006	journal	September 1987
Phase equilibria in copolymer/homopolymer ternary blends: Molecular weight effects Broseta, Daniel; Fredrickson, Glenn H. The Journal of Chemical Physics, Vol. 93, Issue 4 https://doi.org/10.1063/1.458877	journal	August 1990
The standard Gaussian model for block copolymer melts Matsen, M. W. Journal of Physics: Condensed Matter, Vol. 14, Issue 2 https://doi.org/10.1088/0953-8984/14/2/201	journal	December 2001
Instability of the Microemulsion Channel in Block Copolymer-Homopolymer Blends Vorselaars, Bart; Spencer, Russell K. W.; Matsen, Mark W. Physical Review Letters, Vol. 125, Issue 11 https://doi.org/10.1103/PhysRevLett.125.117801	journal	September 2020
Stable and unstable phases of a diblock copolymer melt Matsen, M. W.; Schick, M. Physical Review Letters, Vol. 72, Issue 16 https://doi.org/10.1103/PhysRevLett.72.2660	journal	April 1994
Polymeric Bicontinuous Microemulsions Bates, Frank S.; Maurer, Wayne W.; Lipic, Paul M. Physical Review Letters, Vol. 79, Issue 5 https://doi.org/10.1103/PhysRevLett.79.849	journal	August 1997
Improving Polymeric Microemulsions with Block Copolymer Polydispersity Thompson, R. B.; Matsen, M. W. Physical Review Letters, Vol. 85, Issue 3 https://doi.org/10.1103/PhysRevLett.85.670	journal	July 2000
Effects of shear flow on a polymeric bicontinuous microemulsion: Equilibrium and steady state behavior Krishnan, Kasiraman; Chapman, Bryan; Bates, Frank S. Journal of Rheology, Vol. 46, Issue 2 https://doi.org/10.1122/1.1446883	journal	March 2002
Shear flow behavior of a dynamically symmetric polymeric bicontinuous microemulsion Zhou, Ning; Bates, Frank S.; Lodge, Timothy P. Journal of Rheology, Vol. 51, Issue 5 https://doi.org/10.1122/1.2750668	journal	September 2007
Polymer Electrolytes Hallinan, Daniel T.; Balsara, Nitash P. Annual Review of Materials Research, Vol. 43, Issue 1 https://doi.org/10.1146/annurev-matsci-071312-121705	journal	July 2013
Dendrite Growth in Lithium/Polymer Systems Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 150, Issue 10 https://doi.org/10.1149/1.1606686	journal	January 2003

Similar Records

Effect of poly[oligo(ethylene glycol) methyl ether methacrylate] side chain length on the brush swelling behavior in A/B/A–B ternary blends with polystyrene

Journal Article · Wed Jun 07 00:00:00 EDT 2023 · Soft Matter · OSTI ID:2420649

Bicontinuous Microemulsions in Partially Charged Ternary Polymer Blends

Journal Article · Fri Aug 23 00:00:00 EDT 2019 · ACS Macro Letters · OSTI ID:1831779

Related Subjects

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
36 MATERIALS SCIENCE
77 NANOSCIENCE AND NANOTECHNOLOGY
Absorption
Copolymers
Homopolymers
Polymers
X-ray scattering

Self-Assembly of Partially Charged Diblock Copolymer-Homopolymer Ternary Blends

Citation Formats

References (69)

Similar Records

Related Subjects