High and temperature-insensitive piezoelectric performance in the lead-free Sm-doped BiFeO3–BaTiO3 ceramics with high Curie temperature

Habib, Muhammad; Ahmad, Pervaiz; Akram, Fazli; Kebaili, Imen; Rahman, Attaur; Din, Israf Ud; Iqbal, Muhammad Javid; Kim, Myong-Ho; Lee, Soonil; Khandaker, Mayeen Uddin; Yeo, Hong Goo; Karoui, Abdennaceur; Song, Tae Kwon

doi:10.1016/j.ceramint.2022.05.355

High and temperature-insensitive piezoelectric performance in the lead-free Sm-doped BiFeO₃–BaTiO₃ ceramics with high Curie temperature

Journal Article · Mon May 30 00:00:00 EDT 2022 · Ceramics International

DOI:https://doi.org/10.1016/j.ceramint.2022.05.355· OSTI ID:1873388

Habib, Muhammad ^[1]; ^[2]; ^[3]; ^[4]; ^[5]; Din, Israf Ud ^[6]; Iqbal, Muhammad Javid ^[7]; Kim, Myong-Ho ^[5]; ^[5]; ^[8]; Yeo, Hong Goo ^[9]; ^[3]; Song, Tae Kwon ^[5]

Univ. of Azad Jammu and Kashmir (Pakistan); North Carolina Central Univ., Durham, NC (United States); Department of Mathematics and Physics / CREST center, North Carolina Central University, Durham, North Carolina, 27707, USA
Univ. of Azad Jammu and Kashmir (Pakistan)
North Carolina Central Univ., Durham, NC (United States)
King Khalid Univ., Abha (Saudi Arabia); Univ. de Sfax (Tunisia)
Changwon National Univ., Gyeongnam (Korea, Republic of)
Prince Sattam Bin Abdulaziz Univ., Al-Kharaj (Saudi Arabia)
Univ. of Peshawar (Pakistan)
Sunway Univ., Selangor (Malaysia)
Sun Moon Univ., Chungnam (Korea, Republic of)

Large sensor piezoelectric constant (d₃₃ = 334 pC/N) and superior actuator piezoelectric constant (d₃₃* = 552 pm/V) as well as a high Curie temperature (T_C = 454 °C) were obtained simultaneously in the lead-free 0.67Bi_1.03FeO₃-0.33Ba_1-xSm_xTiO₃ ceramics. Such an excellent and temperature-insensitive piezoelectric performance with only 10% temperature variation of piezoelectric strain at the range of 25–125 °C is highly desirable for real applications. The structural origin of the enhanced piezoelectric performance is mainly attributed to the morphotropic phase boundary and the highest known tetragonality (c_T/a_T = 1.02) in such materials. Transmission electron microscopy and electro-mechanical phenomenological theory demonstrate that the superior d₃₃ and d₃₃* are associated with the hybrids nanodomains (60–90 nm) and flattened thermodynamic energy profile owing to the local structure heterogeneity. Furthermore, these results are superior as the piezoelectric properties are temperature-independent and the material has large d₃₃*, and high TC compared to other lead-free piezoelectric ceramics.

View Accepted Manuscript (DOE)

Research Organization:: North Carolina Central Univ., Durham, NC (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003979

OSTI ID:: 1873388

Journal Information:: Ceramics International, Journal Name: Ceramics International Journal Issue: 18 Vol. 48; ISSN 0272-8842

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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