Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

Hastings, Ashley M.; Ray, Debmalya; Hanna, Sylvia L.; Jeong, WooSeok; Chen, Zhijie; Oliver, Allen G.; Gagliardi, Laura; Farha, Omar K.; Hixon, Amy E.

doi:10.1021/acs.inorgchem.2c00427

Title: Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

Journal Article · Tue Jun 14 00:00:00 EDT 2022 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.2c00427· OSTI ID:1873156

Hastings, Ashley M. ^[1];

^[2]; Hanna, Sylvia L. ^[3]; Jeong, WooSeok ^[2];

^[3];

^[1];

^[4]; Farha, Omar K. ^[3]; Hixon, Amy E. ^[1]

Univ. of Notre Dame, IN (United States)
Univ. of Minnesota, Minneapolis, MN (United States)
Northwestern Univ., Evanston, IL (United States)
Univ. of Chicago, IL (United States); Argonne National Lab. (ANL), Lemont IL (United States)

We report the synthesis, characterization, and iodine capture application of a novel thorium–organic nanotube, TSN-626, [Th6O4(OH)4(C6H4NO2)7(CHO2)5(H2O)3]·3H2O. The classification as a metal–organic nanotube (MONT) distinguishes it as a rare and reduced dimensionality subset of metal–organic frameworks (MOFs); the structure is additionally hallmarked by low node connectivity. TSN-626 is composed of hexameric thorium secondary building units and mixed O/N-donor isonicotinate ligands that demonstrate selective ditopicity, yielding both terminating and bridging moieties. Because hard Lewis acid tetravalent metals have a propensity to bind with electron donors of rival hardness (e.g., carboxylate groups), such Th–N coordination in a MOF is uncommon. However, the formation of key structural Th–N bonds in TSN-626 cap some of the square antiprismatic metal centers, a position usually occupied by terminal water ligands. TSN-626 was characterized by using complementary analytical and computational techniques: X-ray diffraction, vibrational spectroscopy, N2 physisorption isotherms, and density functional theory. TSN-626 satisfies design aspects for the chemisorption of iodine. The synergy between accessibility through pores, vacancies at the metal–oxo nodes, and pendent N-donor sites allowed a saturated iodine loading of 955 mg g–1 by vapor methods. The crystallization of TSN-626 diversifies actinide–MOF linker selection to include soft electron donors, and these Th–N linkages can be leveraged for the investigation of metal-to-ligand bonding and unconventional topological expressions.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: University of Notre Dame, IN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003763; NA0003960; AC02-06CH11357

OSTI ID:: 1873156

Alternate ID(s):: OSTI ID: 1923493

Journal Information:: Inorganic Chemistry, Vol. 61, Issue 25; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (75)

A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability Carter, Korey P.; Ridenour, J. August; Kalaj, Mark Chemistry – A European Journal, Vol. 25, Issue 29 https://doi.org/10.1002/chem.201901610	journal	April 2019
Iodine Adsorption in a Redox-Active Metal–Organic Framework: Electrical Conductivity Induced by Host−Guest Charge-Transfer Zhang, Xinran; da Silva, Ivan; Fazzi, Rodrigo Inorganic Chemistry, Vol. 58, Issue 20 https://doi.org/10.1021/acs.inorgchem.9b02176	journal	September 2019
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
Thorium(IV) Molecular Clusters with a Hexanuclear Th Core Knope, Karah E.; Wilson, Richard E.; Vasiliu, Monica Inorganic Chemistry, Vol. 50, Issue 19 https://doi.org/10.1021/ic2014946	journal	October 2011
The water-based synthesis of chemically stable Zr-based MOFs using pyridine-containing ligands and their exceptionally high adsorption capacity for iodine Wang, Zhe; Huang, Ying; Yang, Jian Dalton Transactions, Vol. 46, Issue 23 https://doi.org/10.1039/C7DT01084B	journal	January 2017
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
UFF, a full periodic table force field for molecular mechanics and molecular dynamics simulations Rappe, A. K.; Casewit, C. J.; Colwell, K. S. Journal of the American Chemical Society, Vol. 114, Issue 25, p. 10024-10035 https://doi.org/10.1021/ja00051a040	journal	December 1992
New software for searching the Cambridge Structural Database and visualizing crystal structures Bruno, Ian J.; Cole, Jason C.; Edgington, Paul R. Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3 https://doi.org/10.1107/S0108768102003324	journal	May 2002
Boosting the Iodine Adsorption and Radioresistance of Th‐UiO‐66 MOFs via Aromatic Substitution Li, Zi‐Jian; Ju, Yu; Lu, Huangjie Chemistry – A European Journal, Vol. 27, Issue 4 https://doi.org/10.1002/chem.202003621	journal	November 2020
Structural Features in Metal–Organic Nanotube Crystals That Influence Stability and Solvent Uptake Jayasinghe, Ashini S.; Unruh, Daniel K.; Kral, Andrew Crystal Growth & Design, Vol. 15, Issue 8 https://doi.org/10.1021/acs.cgd.5b00653	journal	June 2015
Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-66 Hastings, Ashley M.; Ray, Debmalya; Jeong, WooSeok Journal of the American Chemical Society, Vol. 142, Issue 20 https://doi.org/10.1021/jacs.0c01895	journal	April 2020
Computational Thermochemistry: Scale Factor Databases and Scale Factors for Vibrational Frequencies Obtained from Electronic Model Chemistries Alecu, I. M.; Zheng, Jingjing; Zhao, Yan Journal of Chemical Theory and Computation, Vol. 6, Issue 9 https://doi.org/10.1021/ct100326h	journal	August 2010
Rational tuning of thorium-organic frameworks by reticular chemistry for boosting radionuclide sequestration Feng, Han; Xiong, Xiaohong; Gong, Lele Nano Research, Vol. 15, Issue 2 https://doi.org/10.1007/s12274-021-3690-7	journal	July 2021
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials Farha, Omar K.; Hupp, Joseph T. Accounts of Chemical Research, Vol. 43, Issue 8, p. 1166-1175 https://doi.org/10.1021/ar1000617	journal	August 2010
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np ₆ O ₈ } hexanuclear clusters Martin, N. P.; März, J.; Feuchter, H. Chemical Communications, Vol. 54, Issue 51 https://doi.org/10.1039/C8CC03121E	journal	January 2018
Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands Li, Zi-Jian; Guo, Shangyao; Lu, Huangjie Inorganic Chemistry Frontiers, Vol. 7, Issue 1 https://doi.org/10.1039/C9QI01263J	journal	January 2020
Experimental and Quantum Mechanical Characterization of an Oxygen‐Bridged Plutonium(IV) Dimer Ray, Debmalya; Xie, Jing; White, Jacob Chemistry – A European Journal, Vol. 26, Issue 36 https://doi.org/10.1002/chem.202000638	journal	June 2020
Probing the Electronic Structure of a Thorium Nitride Complex by Solid-State ¹⁵ N NMR Spectroscopy Sergentu, Dumitru-Claudiu; Kent, Greggory T.; Staun, Selena L. Inorganic Chemistry, Vol. 59, Issue 14 https://doi.org/10.1021/acs.inorgchem.0c01263	journal	June 2020
Molecular Simulations of Zeolites: Adsorption, Diffusion, and Shape Selectivity Smit, Berend; Maesen, Theo L. M. Chemical Reviews, Vol. 108, Issue 10 https://doi.org/10.1021/cr8002642	journal	October 2008
Accurate Characterization of the Pore Volume in Microporous Crystalline Materials Ongari, Daniele; Boyd, Peter G.; Barthel, Senja Langmuir, Vol. 33, Issue 51 https://doi.org/10.1021/acs.langmuir.7b01682	journal	July 2017
Discovery of spontaneous de-interpenetration through charged point-point repulsions Hanna, Sylvia L.; Chheda, Saumil; Anderson, Ryther Chem, Vol. 8, Issue 1 https://doi.org/10.1016/j.chempr.2021.10.027	journal	January 2022
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/PhysRevB.47.558	journal	January 1993
Structure and stability range of a hexanuclear Th(iv)–glycine complex Hennig, Christoph; Takao, Shinobu; Takao, Koichiro Dalton Transactions, Vol. 41, Issue 41 https://doi.org/10.1039/c2dt31367g	journal	January 2012
Use of ¹⁵ N NMR spectroscopy to probe covalency in a thorium nitride Staun, Selena L.; Sergentu, Dumitru-Claudiu; Wu, Guang Chemical Science, Vol. 10, Issue 26 https://doi.org/10.1039/C9SC01960J	journal	January 2019
A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture Xu, Zhenzhen; Xiong, Xiaohong; Xiong, Jianbo Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16960-9	journal	June 2020
Development of Metal–Organic Nanotubes Exhibiting Low-Temperature, Reversible Exchange of Confined “Ice Channels” Unruh, Daniel K.; Gojdas, Kyle; Libo, Anna Journal of the American Chemical Society, Vol. 135, Issue 20 https://doi.org/10.1021/ja400303f	journal	May 2013
ShelXle : a Qt graphical user interface for SHELXL Hübschle, Christian B.; Sheldrick, George M.; Dittrich, Birger Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811043202	journal	November 2011
Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF Andreo, Jacopo; Priola, Emanuele; Alberto, Gabriele Journal of the American Chemical Society, Vol. 140, Issue 43 https://doi.org/10.1021/jacs.8b07113	journal	October 2018
Plutonium(IV) Cluster with a Hexanuclear [Pu ₆ (OH) ₄ O ₄ ] ¹²⁺ Core Knope, Karah E.; Soderholm, L. Inorganic Chemistry, Vol. 52, Issue 12 https://doi.org/10.1021/ic4007185	journal	May 2013
Algorithms and tools for high-throughput geometry-based analysis of crystalline porous materials Willems, Thomas F.; Rycroft, Chris H.; Kazi, Michaeel Microporous and Mesoporous Materials, Vol. 149, Issue 1 https://doi.org/10.1016/j.micromeso.2011.08.020	journal	February 2012
Capture of iodine in highly stable metal–organic frameworks: a systematic study Falaise, Clément; Volkringer, Christophe; Facqueur, Jacques Chemical Communications, Vol. 49, Issue 87 https://doi.org/10.1039/c3cc43728k	journal	January 2013
Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems Svensson, Per H.; Kloo, Lars Chemical Reviews, Vol. 103, Issue 5 https://doi.org/10.1021/cr0204101	journal	May 2003
Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses Ziegelgruber, Kate L.; Knope, Karah E.; Frisch, Mark Journal of Solid State Chemistry, Vol. 181, Issue 2 https://doi.org/10.1016/j.jssc.2007.12.008	journal	February 2008
Periodic Trends in Hexanuclear Actinide Clusters Diwu, Juan; Wang, Shuao; Albrecht-Schmitt, Thomas E. Inorganic Chemistry, Vol. 51, Issue 7 https://doi.org/10.1021/ic2023242	journal	March 2012
Thorium(IV) Coordination Polymers in the Pyridine and Pyrazinedicarboxylic Acid Systems Frisch, Mark; Cahill, Christopher L. Crystal Growth & Design, Vol. 8, Issue 8 https://doi.org/10.1021/cg800029z	journal	August 2008
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands Thuéry, Pierre Inorganic Chemistry, Vol. 50, Issue 5 https://doi.org/10.1021/ic102359q	journal	March 2011
RASPA: molecular simulation software for adsorption and diffusion in flexible nanoporous materials Dubbeldam, David; Calero, Sofía; Ellis, Donald E. Molecular Simulation, Vol. 42, Issue 2 https://doi.org/10.1080/08927022.2015.1010082	journal	February 2015
Evaluating metal–organic frameworks for natural gas storage Mason, Jarad A.; Veenstra, Mike; Long, Jeffrey R. Chemical Science, Vol. 5, Issue 1, p. 32-51 https://doi.org/10.1039/C3SC52633J	journal	January 2014
Ultrastable Thorium Metal–Organic Frameworks for Efficient Iodine Adsorption Li, Zi-Jian; Yue, Zenghui; Ju, Yu Inorganic Chemistry, Vol. 59, Issue 7 https://doi.org/10.1021/acs.inorgchem.9b03602	journal	March 2020
In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal–Organic Framework Gilson, Sara E.; Li, Peng; Szymanowski, Jennifer E. S. Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b06187	journal	July 2019
Tuning the Structural Flexibility for Multi-Responsive Gas Sorption in Isonicotinate-Based Metal–Organic Frameworks Chen, Yongwei; Idrees, Karam B.; Son, Florencia A. ACS Applied Materials & Interfaces, Vol. 13, Issue 14 https://doi.org/10.1021/acsami.1c00061	journal	April 2021
Multiwfn: A multifunctional wavefunction analyzer Lu, Tian; Chen, Feiwu Journal of Computational Chemistry, Vol. 33, Issue 5 https://doi.org/10.1002/jcc.22885	journal	December 2011
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Capture of volatile iodine by newly prepared and characterized non-porous [CuI] _n -based coordination polymers Tarassoli, Abbas; Nobakht, Valiollah; Baladi, Elham CrystEngComm, Vol. 19, Issue 41 https://doi.org/10.1039/C7CE01193H	journal	January 2017
A Double-Walled Thorium-Based Metal–Organic Framework as a Promising Dual-Function Absorbent for Efficiently Capturing Iodine and Dyes Zhang, Na; Sun, Li-Xian; Xing, Yong-Heng Crystal Growth & Design, Vol. 19, Issue 10 https://doi.org/10.1021/acs.cgd.9b00671	journal	August 2019
Metal-organic nanotubes: Designs, structures and functions Jia, Jia-Ge; Zheng, Li-Min Coordination Chemistry Reviews, Vol. 403 https://doi.org/10.1016/j.ccr.2019.213083	journal	January 2020
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions Zhao, Yan; Truhlar, Donald G. The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101 https://doi.org/10.1063/1.2370993	journal	November 2006
Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H ₂ O System Falaise, Clément; Charles, Jean-Sébastien; Volkringer, Christophe Inorganic Chemistry, Vol. 54, Issue 5 https://doi.org/10.1021/ic502725y	journal	February 2015
Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates Vanagas, Nicole A.; Wacker, Jennifer N.; Rom, Christopher L. Inorganic Chemistry, Vol. 57, Issue 12 https://doi.org/10.1021/acs.inorgchem.8b00919	journal	June 2018
Thorium–Organic Framework Constructed with a Semirigid Triazine Hexacarboxylic Acid Ligand: Unique Structure with Thorium Oxide Wheel Clusters and Iodine Adsorption Behavior Zhang, Na; Sun, Li-Xian; Bai, Feng-Ying Inorganic Chemistry, Vol. 59, Issue 6 https://doi.org/10.1021/acs.inorgchem.9b03639	journal	March 2020
Applied Topological Analysis of Crystal Structures with the Program Package ToposPro Blatov, Vladislav A.; Shevchenko, Alexander P.; Proserpio, Davide M. Crystal Growth & Design, Vol. 14, Issue 7 https://doi.org/10.1021/cg500498k	journal	May 2014
A density-functional model of the dispersion interaction Becke, Axel D.; Johnson, Erin R. The Journal of Chemical Physics, Vol. 123, Issue 15 https://doi.org/10.1063/1.2065267	journal	October 2005
Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption Ju, Yu; Li, Zi-Jian; Lu, Huangjie Inorganic Chemistry, Vol. 60, Issue 8 https://doi.org/10.1021/acs.inorgchem.0c03586	journal	March 2021
Energetics of Formation and Hydration of a Porous Metal Organic Nanotube Sahu, Sulata K.; Unruh, Daniel K.; Forbes, Tori Z. Chemistry of Materials, Vol. 26, Issue 17 https://doi.org/10.1021/cm5024053	journal	August 2014
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Chemical, thermal and mechanical stabilities of metal–organic frameworks Howarth, Ashlee J.; Liu, Yangyang; Li, Peng Nature Reviews Materials, Vol. 1, Issue 3 https://doi.org/10.1038/natrevmats.2015.18	journal	February 2016
Metal–Organic Nanotube with Helical and Propeller-Chiral Motifs Composed of a C ₁₀ -Symmetric Double-Decker Nanoring Yamagishi, Hiroshi; Fukino, Takahiro; Hashizume, Daisuke Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b04386	journal	June 2015
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Ionization Reaction in Iodine/Pyridine Solutions: What Can We Learn from Conductivity Measurements, Far-Infrared Spectroscopy, and Raman Scattering? Tassaing, T.; Besnard, M. The Journal of Physical Chemistry A, Vol. 101, Issue 15 https://doi.org/10.1021/jp963767f	journal	April 1997
Characterization and comparison of pore landscapes in crystalline porous materials Pinheiro, Marielle; Martin, Richard L.; Rycroft, Chris H. Journal of Molecular Graphics and Modelling, Vol. 44 https://doi.org/10.1016/j.jmgm.2013.05.007	journal	July 2013
Vapor–liquid equilibria of mixtures containing alkanes, carbon dioxide, and nitrogen Potoff, Jeffrey J.; Siepmann, J. Ilja AIChE Journal, Vol. 47, Issue 7, p. 1676-1682 https://doi.org/10.1002/aic.690470719	journal	July 2001
An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements Ridenour, J. August; Surbella, Robert G.; Gelis, Artem V. Angewandte Chemie International Edition, Vol. 58, Issue 46 https://doi.org/10.1002/anie.201909988	journal	November 2019
High Uptake of ReO ₄ ⁻ and CO ₂ Conversion by a Radiation-Resistant Thorium-Nickle [Th ₄₈ Ni ₆ ] Nanocage-Based Metal-Organic Framework Xu, Hang; Cao, Chun-Shuai; Hu, Han-Shi Angewandte Chemie International Edition, Vol. 58, Issue 18 https://doi.org/10.1002/anie.201901786	journal	March 2019
Complexes of a hexadentate podand ligand with actinides; The syntheses and crystal structures of [Th(TpPy)(NO3)3] · (dmf) · (Et2O)0.5 and trans-[UO2(TpPy)(OEt)] TpPy = tris[3-(2′-pyridyl)pyrazol-1-yl]hydroborate Amoroso, Angelo J.; Jeffery, John C.; Jones, Peter L. Polyhedron, Vol. 15, Issue 12 https://doi.org/10.1016/0277-5387(95)00451-3	journal	June 1996
Interaction of neptunium(V) with picolinic, nicotinic and isonicotinic acids Budantseva, Nina A.; Andreev, Grigory B.; Fedoseev, Alexander M. Radiochimica Acta, Vol. 94, Issue 2 https://doi.org/10.1524/ract.2006.94.2.69	journal	February 2006
Capture of Volatile Iodine, a Gaseous Fission Product, by Zeolitic Imidazolate Framework-8 Sava, Dorina F.; Rodriguez, Mark A.; Chapman, Karena W. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja204757x	journal	August 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites Stock, Norbert; Biswas, Shyam Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200304e	journal	September 2011
Valence basis sets for relativistic energy-consistent small-core actinide pseudopotentials Cao, Xiaoyan; Dolg, Michael; Stoll, Hermann The Journal of Chemical Physics, Vol. 118, Issue 2 https://doi.org/10.1063/1.1521431	journal	January 2003
PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors Spek, Anthony L. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 9-18 https://doi.org/10.1107/S2053229614024929	journal	January 2015
Iodine Confinement into Metal–Organic Frameworks (MOFs): Low-Temperature Sintering Glasses To Form Novel Glass Composite Material (GCM) Alternative Waste Forms Sava, Dorina F.; Garino, Terry J.; Nenoff, Tina M. Industrial & Engineering Chemistry Research, Vol. 51, Issue 2 https://doi.org/10.1021/ie200248g	journal	May 2011

Similar Records

Homochiral Cu(II) and Ni(II) malates with tunable structural features

Journal Article · Sat Feb 15 00:00:00 EST 2014 · Journal of Solid State Chemistry · OSTI ID:1873156

Zavakhina, Marina S.; Samsonenko, Denis G.; Virovets, Alexander V.; +1 more

Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks

Journal Article · Thu Jun 30 00:00:00 EDT 2022 · CrystEngComm · OSTI ID:1873156

Wasson, Megan C.; Xie, Haomiao; Wang, Xingjie; +2 more

Synthesis, structure and properties of zinc(II) coordination polymers with 9H-carbazole-2,7-dicarboxylic acid

Journal Article · Tue Oct 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:1873156

Yi, Xiu-Chun; Xi, Fu-Gui; Wang, Kun; +2 more

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Adsorption
Iodine
Ligands
Pyridines
Thorium
microporous materials
nanotube
thorium
actinides
metal–organic frameworks

Title: Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture

Citation Formats

References (75)

Linked Research (1)

Similar Records

Related Subjects