Synthesis of dysprosium oxychloride (DyOCl)

Chong, Saehwa; Riley, Brian J.; Marcial, Jose; Lonergan, Charmayne E.; Cutforth, Derek A.

doi:10.1007/s10870-021-00904-2

Title: Synthesis of dysprosium oxychloride (DyOCl)

Journal Article · 01 June 2022 · Journal of Chemical Crystallography

DOI:https://doi.org/10.1007/s10870-021-00904-2· OSTI ID:1872437

Chong, Saehwa ^[1];

^[1];

^[1]; Cutforth, Derek A. ^[1]

BATTELLE (PACIFIC NW LAB)

Dysprosium oxychloride, DyOCl, was synthesized using a simple dehydration method with DyCl3·6H2O. X-ray powder diffraction data was used to determine the crystal structure. The DyOCl compound is isostructural to the matlockite (PbFCl) crystal structure and crystallizes in the tetragonal P4/nmm (#129) space group. The crystal structure contains the alternating cationic layers of (DyO)n and anionic layers of nCl– along the c-axis. The structural data including unit cell, volume, and density of DyOCl were compared to other REOCl data from Inorganic Crystal Structure Database (ICSD) and our previous study on TbOCl. Fourier-transform infrared spectroscopy (FTIR) was performed, and the vibrations of DyOCl possibly from Dy–O and Dy–Cl were observed at 543 and 744 cm-1. Scanning electron microscopy analysis (SEM) showed irregularly shaped crystals.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1872437

Report Number(s):: PNNL-SA-158753

Journal Information:: Journal of Chemical Crystallography, Vol. 52, Issue 2

Country of Publication:: United States

Language:: English

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