Pretreatment of lignocellulosic feedstocks for cellulose nanofibril production

Copenhaver, Katie; Li, Kai; Wang, Lu; Lamm, Meghan; Zhao, Xianhui; Korey, Matthew; Neivandt, David; Dixon, Brandon; Sultana, Sabrina; Kelly, Peter; Gramlich, William M.; Tekinalp, Halil; Gardner, Douglas J.; Mackay, Susan; Nawaz, Kashif; Ozcan, Soydan

doi:10.1007/s10570-022-04580-z

Pretreatment of lignocellulosic feedstocks for cellulose nanofibril production

Journal Article · Wed May 11 00:00:00 EDT 2022 · Cellulose

DOI:https://doi.org/10.1007/s10570-022-04580-z· OSTI ID:1871901

^[1]; ^[1]; Wang, Lu ^[2]; ^[1]; Zhao, Xianhui ^[1]; Korey, Matthew ^[1]; Neivandt, David ^[2]; Dixon, Brandon ^[2]; Sultana, Sabrina ^[2]; Kelly, Peter ^[2]; Gramlich, William M. ^[2]; Tekinalp, Halil ^[1]; Gardner, Douglas J. ^[2]; Mackay, Susan ^[2]; ^[1]; ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Maine, Orono, ME (United States)

Cellulose nanofibrils (CNFs) have attracted a great deal of research interest in recent years attributable to the low cost and abundance of lignocellulosic biomass from which they can be extracted. These materials have potential applications in a wide array of areas because of their unique properties such as ultra-high aspect ratios and specific strengths. However, the high energy required to extract CNFs from biomass through fibrillation often makes them prohibitively expensive or negates their inherent sustainability. As such, a variety of biomass treatments prior to fibrillation have been investigated by researchers to reduce the energy requirements of CNF extraction, improve the efficacy of biomass fibrillation and subsequent processes, and/or impart functionality in resulting nanofibrils. In this work, both widely used and emerging mechanical, chemical, and enzymatic pretreatments used prior to fibrillation of lignocellulosic biomass for CNF extraction are reviewed. Attention is given to the effect of these various pretreatments on the properties of the resulting CNFs. Finally, the energy consumption in fibrillation processes with and without the use of pretreatments is compared, and future perspectives on challenges and opportunities in lignocellulosic feedstock pretreatments are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1871901

Journal Information:: Cellulose, Journal Name: Cellulose Journal Issue: 9 Vol. 29; ISSN 0969-0239

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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59 BASIC BIOLOGICAL SCIENCES
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