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Using Chemical Reactor Models to Predict Fluidized Bed Pyrolysis Yields of Biomass Feedstocks

Technical Report ·
DOI:https://doi.org/10.2172/1871900· OSTI ID:1871900
A detailed biomass pyrolysis kinetics scheme is implemented in reduced-order reactor models to predict chemical species yields from a fluidized bed reactor. The biomass composition in terms of cellulose, hemicellulose, lignins, and extractives are determined for several biomass feedstocks. Model results are compared to yields measured from a two-inch diameter bench-scale fluidized bed reactor operating at fast pyrolysis conditions. The reduced-order chemical reactor models compare favorably with the experimental measurements and capture trends in product yields due to biomass compositional effects such as high ash content. This work offers a computationally inexpensive approach to predict the quality of biomass pyrolysis products in a timely manner. Source code for the reactor models along with a biomass composition web tool are made available online for future scientific research efforts.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1871900
Report Number(s):
ORNL/TM-2021/2335
Country of Publication:
United States
Language:
English

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