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Energy, greenhouse gas, and water life cycle analysis of lithium carbonate and lithium hydroxide monohydrate from brine and ore resources and their use in lithium ion battery cathodes and lithium ion batteries

Journal Article · · Resources, Conservation and Recycling

Life cycle analyses (LCAs) were conducted for battery-grade lithium carbonate (Li2CO3) and lithium hydroxide monohydrate (LiOH·H2O) produced from Chilean brines (Salar de Atacama) and Australian spodumene ores. The LCA was also extended beyond the production of Li2CO3 and LiOH·H2O to include battery cathode materials as well as full automotive traction batteries to observe the effect that the lithium production pathways had on these end products. The LCA here covers material, water, and energy flows associated with lithium acquisition; lithium concentration; production of lithium chemicals, battery cathode powders, and batteries; and associated transportation activities along the supply chain. Based on battery cathode material, the difference in lithium source represents a difference of up to 20% for NMC811 cathode greenhouse gases (GHGs) and up to 45% for NMC622 cathode GHGs. For full batteries, this represents a difference of up to 9% for NMC811 batteries and 20% for NMC622 batteries. Production of Li2CO3 from brine-based resources had less life cycle GHG emissions and freshwater consumption per tonne of Li2CO3 than Li2CO3 from ore-based resources. And LiOH·H2O produced from brine-based lithium also had less life cycle GHG emissions and freshwater consumption per tonne of LiOH·H2O than LiOH·H2O from ore-based resources.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
Sociedad Química y Minera de Chile (SQM)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1868964
Journal Information:
Resources, Conservation and Recycling, Journal Name: Resources, Conservation and Recycling Vol. 174; ISSN 0921-3449
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (6)

3D mapping, hydrodynamics and modelling of the freshwater-brine mixing zone in salt flats similar to the Salar de Atacama (Chile) journal June 2018
The rise and fall of American lithium journal November 2020
Extended life cycle assessment reveals the spatially-explicit water scarcity footprint of a lithium-ion battery storage journal January 2021
Wells to wheels: water consumption for transportation fuels in the United States journal January 2016
Understanding the future of lithium: Part 2, temporally and spatially resolved life‐cycle assessment modeling journal October 2019
Understanding the future of lithium: Part 1, resource model journal October 2019

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