Reduction of Chlorinated Ethenes by Ag- and Cu-Amended Green Rust

O’Loughlin, Edward J.; Burris, David R.

doi:10.3390/min12020138

Reduction of Chlorinated Ethenes by Ag- and Cu-Amended Green Rust

Journal Article · Mon Jan 24 23:00:00 EST 2022 · Minerals

DOI:https://doi.org/10.3390/min12020138· OSTI ID:1868925

^[1]; Burris, David R. ^[2]

Air Force Research Lab. (AFRL), Tyndall AFB, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Air Force Research Lab. (AFRL), Tyndall AFB, IL (United States); Crooked Creek Environmental, LLC, Panama City, FL (United States)

Chlorinated ethenes have been used extensively as solvents, degreasers, and dry-cleaning agents in a range of commercial and industrial applications. This has created a legacy of contaminated soils and groundwater, particularly with respect to perchloroethylene (PCE; a.k.a. tetrachloroethene—C₂Cl₄), and trichloroethylene (TCE; a.k.a. trichloroethene—C₂HCl₃), prompting the development of a wide array of treatment technologies for remediation of chlorinated ethene-contaminated environments. Green rusts are highly redox-active layered Fe(II)-Fe(III) hydroxides that have been shown to be facile reductants for a wide range of organic and inorganic pollutants. The reduction of chlorinated ethenes [vinyl chloride (VC); 1,1-dichloroethene(11DCE), cis-1,2-dichloroethene (c12DCE), trans-1,2-dichloroethene (t12DCE), TCE, and PCE] was examined in aqueous suspensions of green rust, alone as well as with the addition of Ag(I) (AgGR) or Cu(II) (CuGR). Green rust alone was ineffective as a reductant for the reductive dechlorination for all of the chlorinated ethenes. Near-complete removal of PCE was observed in the presence of AgGR, but all other chlorinated ethenes were essentially non-reactive. Partial removal of chlorinated ethenes was observed in the presence of CuGR, particularly 11DCE (34%), t12DCE (51%), and VC (66%). Significant differences were observed in the product distributions of chlorinated ethene reduction by AgGR and CuGR. The effectiveness of Ag(I)- and Cu(II)-amended green rusts for removal of chlorinated ethenes may be improved under different conditions (e.g., pH and interlayer anion) and warrants further investigation.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); US Air Force Office of Scientific Research (AFOSR); USDOD

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1868925

Journal Information:: Minerals, Journal Name: Minerals Journal Issue: 2 Vol. 12; ISSN 2075-163X

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Journal Article · Tue Jan 19 23:00:00 EST 1999 · Biotechnology and Bioengineering · OSTI ID:318847

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis
chlorinated ethene
dichloroethane
green rust
perchloroethene
reductive dechlorination
tetrachloroethene
trichloroethene
vinyl chloride

Reduction of Chlorinated Ethenes by Ag- and Cu-Amended Green Rust

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