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Title: Environmental, Economic, and Scalability Considerations of Selected Bio-Derived Blendstocks for Mixing-Controlled Compression Ignition Engines

Journal Article · · ACS Sustainable Chemistry & Engineering
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [2];  [1]; ORCiD logo [1]; ORCiD logo [1];  [1];  [2]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [3];  [3];  [3];  [3];  [3]
  1. National Bioenergy Center, National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, Colorado 80401, United States
  2. Systems Assessment Group, Energy Systems Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, Illinois 60439, United States
  3. Energy Processes and Materials Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, Washington 99354, United States

Economic and environmental favorability are vital considerations for the large-scale development and deployment of sustainable fuels. Here, we have conducted economic and sustainability analyses of pathways for producing bioblendstocks optimized for improved combustion for mixing-controlled compression ignition (MCCI) engines. We assessed 25 pathways for the production of target fuels from renewable feedstocks and conducted technoeconomic analysis (TEA) and life cycle analysis (LCA) to determine which bioblendstock candidates are likely to be viable given a slate of 19 metrics evaluating technology readiness, economic viability, and environmental impacts ranking each metric as either favorable, neutral, unfavorable, or unknown across a range of screening criteria. Among the results, we found that the economic metrics were largely favorable for most of the bioblendstocks. Of the near-term baseline cases, eight pathways offered the potential of a minimum fuel selling price (MFSP) of less than 5 dollars per gallon of gasoline equivalent (GGE). In comparison, under future target case scenarios, there is potential for seven pathways to reduce their fuel selling price to less than 4 dollars per GGE. Biochemically-based pathways struggled to achieve favorable target case MFSP under the processing approach taken here, but further economic improvements could be achieved when lignin valorization is included. Most of the conversion technologies were determined to be robust in that they would be minimally affected by the feedstock specifications and variations. However, given the early stage of development for most of the pathways, blending behavior and testing for regulatory limits are key data gaps as knowledge of how many of these bioblendstocks will perform when blended with existing fuels and how much can be added while still meeting fuel property specifications is still being assessed. Twelve pathways showed significant reductions in life cycle greenhouse gas (GHG) emissions greater than 60%, and 15 showed favorable fossil energy use reductions compared to conventional diesel fuel. Energy-intensive processes and the use of GHG-intensive chemicals such as sodium hydroxide contribute significantly to GHG emissions. Results from these analyses enable researchers and industry to assess the potential viability of MCCI bioblendstocks.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States); National Renewable Energy Laboratory (NREL), Golden, CO (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Bioenergy Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Co-Optimization of Fuels & Engines (Co-Optima) Initiative
Grant/Contract Number:
AC02-06CH11357; AC36-08GO28308; AC05-76RL01830
OSTI ID:
1867721
Alternate ID(s):
OSTI ID: 1869408; OSTI ID: 1869689; OSTI ID: 1878295; OSTI ID: 1903780
Report Number(s):
NREL/JA-5100-81843; PNNL-SA-170232
Journal Information:
ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Vol. 10 Journal Issue: 20; ISSN 2168-0485
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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