Quantification of Dead Lithium on Graphite Anode under Fast Charging Conditions

Vikrant, K. S. N.; McShane, Eric; Colclasure, Andrew M.; McCloskey, Bryan D.; Allu, Srikanth

doi:10.1149/1945-7111/ac61d3

Quantification of Dead Lithium on Graphite Anode under Fast Charging Conditions

Journal Article · 14 April 2022 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1945-7111/ac61d3· OSTI ID:1867590

Vikrant, K. S. N.; McShane, Eric; ; McCloskey, Bryan D.; Allu, Srikanth

A series of computational and experimental studies were conducted to understand the onset of lithium plating and subsequent quantification of dead lithium on graphite electrodes in the design of fast charging batteries. The experiments include titration and relaxation studies for detecting initiation of lithium metal plating for various SOC and C-rates, which are compared against the thermodynamically consistent phase field computational results. The collaborative study on "model graphite electrode" with 2.18 mAh cm-2 nominal capacity at 25 degrees C demonstrates: (1) the macroscopic voltage response during relaxation studies indicate the reintercalation of plated lithium into the graphite anode; (2) for SOC below 60% and low C-Rates, there is no dead lithium; (3) for SOC between 60% to 80%, and C-Rates in the range of 4C-6C show dead lithium both in experiments and simulations; (4) at 100% SOC and 4C-6C rates, large amounts of dead lithium are observed. The study presented here allows us to evaluate the effects of the physical properties of the electrochemical system on plating and stripping kinetics and the amount of dead lithium on graphite electrodes, which determines the cell capacity loss under fast charge.

Research Organization:: National Renewable Energy Lab. (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V), Extreme Fast Charge Program (XCEL)

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1867590

Report Number(s):: NREL/JA-5700-80665; MainId:77449; UUID:5fc61989-5ef9-4ebf-9c7b-e8e4710e73c4; MainAdminID:64498

Journal Information:: Journal of the Electrochemical Society, Vol. 169, Issue 4

Country of Publication:: United States

Language:: English

References (59)

Energy storage emerging: A perspective from the Joint Center for Energy Storage Research Trahey, Lynn; Brushett, Fikile R.; Balsara, Nitash P. Proceedings of the National Academy of Sciences, Vol. 117, Issue 23 https://doi.org/10.1073/pnas.1821672117	journal	June 2020
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
A Review of Lithium-Ion Battery for Electric Vehicle Applications and Beyond Chen, Weidong; Liang, Jun; Yang, Zhaohua Energy Procedia, Vol. 158 https://doi.org/10.1016/j.egypro.2019.01.783	journal	February 2019
A case for the internal combustion engine powered vehicle Towoju, Olumide A.; Ishola, Felix A. Energy Reports, Vol. 6 https://doi.org/10.1016/j.egyr.2019.11.082	journal	February 2020
Enabling fast charging – A battery technology gap assessment Ahmed, Shabbir; Bloom, Ira; Jansen, Andrew N. Journal of Power Sources, Vol. 367 https://doi.org/10.1016/j.jpowsour.2017.06.055	journal	November 2017
Enabling fast charging – Battery thermal considerations Keyser, Matthew; Pesaran, Ahmad; Li, Qibo Journal of Power Sources, Vol. 367 https://doi.org/10.1016/j.jpowsour.2017.07.009	journal	November 2017
Challenges and opportunities towards fast-charging battery materials Liu, Yayuan; Zhu, Yangying; Cui, Yi Nature Energy, Vol. 4, Issue 7 https://doi.org/10.1038/s41560-019-0405-3	journal	June 2019
Environmental impacts of extreme fast charging Jenn, Alan; Clark-Sutton, Kyle; Gallaher, Michael Environmental Research Letters, Vol. 15, Issue 9 https://doi.org/10.1088/1748-9326/ab9870	journal	August 2020
Direct in situ measurements of Li transport in Li-ion battery negative electrodes Harris, Stephen J.; Timmons, Adam; Baker, Daniel R. Chemical Physics Letters, Vol. 485, Issue 4-6 https://doi.org/10.1016/j.cplett.2009.12.033	journal	January 2010
Review and Performance Comparison of Mechanical-Chemical Degradation Models for Lithium-Ion Batteries Reniers, Jorn M.; Mulder, Grietus; Howey, David A. Journal of The Electrochemical Society, Vol. 166, Issue 14 https://doi.org/10.1149/2.0281914jes	journal	January 2019
Requirements for Enabling Extreme Fast Charging of High Energy Density Li-Ion Cells while Avoiding Lithium Plating Colclasure, Andrew M.; Dunlop, Alison R.; Trask, Stephen E. Journal of The Electrochemical Society, Vol. 166, Issue 8 https://doi.org/10.1149/2.0451908jes	journal	January 2019
How Observable Is Lithium Plating? Differential Voltage Analysis to Identify and Quantify Lithium Plating Following Fast Charging of Cold Lithium-Ion Batteries Campbell, Ian D.; Marzook, Mohamed; Marinescu, Monica Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0821904jes	journal	January 2019
Electrode scale and electrolyte transport effects on extreme fast charging of lithium-ion cells Colclasure, Andrew M.; Tanim, Tanvir R.; Jansen, Andrew N. Electrochimica Acta, Vol. 337 https://doi.org/10.1016/j.electacta.2020.135854	journal	March 2020
Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging Mistry, Aashutosh; Usseglio-Viretta, Francois L. E.; Colclasure, Andrew Journal of The Electrochemical Society, Vol. 167, Issue 9 https://doi.org/10.1149/1945-7111/ab8fd7	journal	May 2020
Mesoscale Anatomy of Dead Lithium Formation Tewari, Deepti; Rangarajan, Sobana P.; Balbuena, Perla B. The Journal of Physical Chemistry C, Vol. 124, Issue 12 https://doi.org/10.1021/acs.jpcc.9b11563	journal	March 2020
Effects of Electrolyte Composition on Lithium Plating in Lithium-Ion Cells Smart, M. C.; Ratnakumar, B. V. Journal of The Electrochemical Society, Vol. 158, Issue 4 https://doi.org/10.1149/1.3544439	journal	January 2011
In situ detection of lithium metal plating on graphite in experimental cells Uhlmann, C.; Illig, J.; Ender, M. Journal of Power Sources, Vol. 279 https://doi.org/10.1016/j.jpowsour.2015.01.046	journal	April 2015
Lithium plating in a commercial lithium-ion battery – A low-temperature aging study Petzl, Mathias; Kasper, Michael; Danzer, Michael A. Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.065	journal	February 2015
Lithium plating in lithium-ion batteries investigated by voltage relaxation and in situ neutron diffraction von Lüders, Christian; Zinth, Veronika; Erhard, Simon V. Journal of Power Sources, Vol. 342 https://doi.org/10.1016/j.jpowsour.2016.12.032	journal	February 2017
Li plating as unwanted side reaction in commercial Li-ion cells – A review Waldmann, Thomas; Hogg, Björn-Ingo; Wohlfahrt-Mehrens, Margret Journal of Power Sources, Vol. 384 https://doi.org/10.1016/j.jpowsour.2018.02.063	journal	April 2018
Direct Observation of the Growth of Lithium Dendrites on Graphite Anodes by Operando EC-AFM Shen, Cai; Hu, Guohong; Cheong, Ling-Zhi Small Methods, Vol. 2, Issue 2 https://doi.org/10.1002/smtd.201700298	journal	December 2017
In Situ Detection of Lithium Plating on Graphite Electrodes by Electrochemical Calorimetry Downie, L. E.; Krause, L. J.; Burns, J. C. Journal of The Electrochemical Society, Vol. 160, Issue 4 https://doi.org/10.1149/2.049304jes	journal	January 2013
Lithium plating in lithium-ion batteries at sub-ambient temperatures investigated by in situ neutron diffraction Zinth, Veronika; von Lüders, Christian; Hofmann, Michael Journal of Power Sources, Vol. 271 https://doi.org/10.1016/j.jpowsour.2014.07.168	journal	December 2014
Quantification of Inactive Lithium and Solid–Electrolyte Interphase Species on Graphite Electrodes after Fast Charging McShane, Eric J.; Colclasure, Andrew M.; Brown, David E. ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00859	journal	May 2020
A Review of Existing and Emerging Methods for Lithium Detection and Characterization in Li‐Ion and Li‐Metal Batteries Paul, Partha P.; McShane, Eric J.; Colclasure, Andrew M. Advanced Energy Materials, Vol. 11, Issue 17 https://doi.org/10.1002/aenm.202100372	journal	March 2021
Mathematical Modeling of the Lithium Deposition Overcharge Reaction in Lithium-Ion Batteries Using Carbon-Based Negative Electrodes Arora, Pankaj Journal of The Electrochemical Society, Vol. 146, Issue 10 https://doi.org/10.1149/1.1392512	journal	January 1999
Two-Dimensional Modeling of Lithium Deposition during Cell Charging Tang, Maureen; Albertus, Paul; Newman, John Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3095513	journal	January 2009
Low-temperature charging of lithium-ion cells part I: Electrochemical modeling and experimental investigation of degradation behavior Tippmann, Simon; Walper, Daniel; Balboa, Luis Journal of Power Sources, Vol. 252 https://doi.org/10.1016/j.jpowsour.2013.12.022	journal	April 2014
Modeling of lithium plating induced aging of lithium-ion batteries: Transition from linear to nonlinear aging Yang, Xiao-Guang; Leng, Yongjun; Zhang, Guangsheng Journal of Power Sources, Vol. 360 https://doi.org/10.1016/j.jpowsour.2017.05.110	journal	August 2017
Prediction of Reversible Lithium Plating with a Pseudo-3D Lithium-Ion Battery Model Carelli, Serena; Bessler, Wolfgang G. Journal of The Electrochemical Society, Vol. 167, Issue 10 https://doi.org/10.1149/1945-7111/ab95c8	journal	June 2020
An Electrochemical Model of Lithium Plating and Stripping in Lithium Ion Batteries Hein, Simon; Danner, Timo; Latz, Arnulf ACS Applied Energy Materials, Vol. 3, Issue 9 https://doi.org/10.1021/acsaem.0c01155	journal	July 2020
Fast Charging of Lithium-ion Batteries via Electrode Engineering Vishnugopi, Bairav S.; Verma, Ankit; Mukherjee, Partha P. Journal of The Electrochemical Society, Vol. 167, Issue 9 https://doi.org/10.1149/1945-7111/ab7fb9	journal	January 2020
Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries Garcı́a, R. Edwin; Chiang, Yet-Ming; Craig Carter, W. Journal of The Electrochemical Society, Vol. 152, Issue 1 https://doi.org/10.1149/1.1836132	journal	January 2005
Intercalation dynamics in rechargeable battery materials: General theory and phase-transformation waves in LiFePO4 Singh, Gogi K.; Ceder, Gerbrand; Bazant, Martin Z. Electrochimica Acta, Vol. 53, Issue 26 https://doi.org/10.1016/j.electacta.2008.03.083	journal	November 2008
Anisotropic Phase Boundary Morphology in Nanoscale Olivine Electrode Particles Tang, Ming; Belak, James F.; Dorr, Milo R. The Journal of Physical Chemistry C, Vol. 115, Issue 11 https://doi.org/10.1021/jp109628m	journal	February 2011
Coherency Strain and the Kinetics of Phase Separation in LiFePO ₄ Nanoparticles Cogswell, Daniel A.; Bazant, Martin Z. ACS Nano, Vol. 6, Issue 3 https://doi.org/10.1021/nn204177u	journal	February 2012
Nonequilibrium Thermodynamics of Porous Electrodes Ferguson, Todd R.; Bazant, Martin Z. Journal of The Electrochemical Society, Vol. 159, Issue 12 https://doi.org/10.1149/2.048212jes	journal	January 2012
Phase Transformation Dynamics in Porous Battery Electrodes Ferguson, Todd R.; Bazant, Martin Z. Electrochimica Acta, Vol. 146 https://doi.org/10.1016/j.electacta.2014.08.083	journal	November 2014
Phase field modeling of electrochemistry. I. Equilibrium Guyer, J. E.; Boettinger, W. J.; Warren, J. A. Physical Review E, Vol. 69, Issue 2 https://doi.org/10.1103/PhysRevE.69.021603	journal	February 2004
Heterogeneous Nucleation and Growth of Lithium Electrodeposits on Negative Electrodes Ely, David R.; García, R. Edwin Journal of The Electrochemical Society, Vol. 160, Issue 4 https://doi.org/10.1149/1.057304jes	journal	January 2013
Phase field kinetics of lithium electrodeposits Ely, David R.; Jana, Aniruddha; García, R. Edwin Journal of Power Sources, Vol. 272 https://doi.org/10.1016/j.jpowsour.2014.08.062	journal	December 2014
Modulation of dendritic patterns during electrodeposition: A nonlinear phase-field model Chen, Lei; Zhang, Hao Wei; Liang, Lin Yun Journal of Power Sources, Vol. 300 https://doi.org/10.1016/j.jpowsour.2015.09.055	journal	December 2015
Quantitative phase-field modeling of dendritic electrodeposition Cogswell, Daniel A. Physical Review E, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRevE.92.011301	journal	July 2015
Dendrite-separator interactions in lithium-based batteries Jana, Aniruddha; Ely, David R.; García, R. Edwin Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.11.056	journal	February 2015
Electrochemomechanics of lithium dendrite growth Jana, Aniruddha; Woo, Sang Inn; Vikrant, K. S. N. Energy & Environmental Science, Vol. 12, Issue 12 https://doi.org/10.1039/C9EE01864F	journal	January 2019
Modeling of Lithium Nucleation and Plating Kinetics Under Fast Charge Conditions Vikrant, K. S. N.; Allu, Srikanth Journal of The Electrochemical Society, Vol. 168, Issue 2 https://doi.org/10.1149/1945-7111/abe5e7	journal	February 2021
Gibbs: Phase equilibria and symbolic computation of thermodynamic properties Cool, Thomas; Bartol, Alexander; Kasenga, Matthew Calphad, Vol. 34, Issue 4 https://doi.org/10.1016/j.calphad.2010.07.005	journal	December 2010
Charged grain boundary transitions in ionic ceramics for energy applications Vikrant, K. S. N.; García, R. Edwin npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0159-2	journal	February 2019
Flash sintering incubation kinetics Vikrant, K. S. N.; Wang, Han; Jana, Aniruddha npj Computational Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41524-020-00359-7	journal	July 2020
Effect of charge separation on the stability of large wavelength fluctuations during spinodal decomposition Bishop, Catherine M.; García, R. Edwin; Carter, W. Craig Acta Materialia, Vol. 51, Issue 6 https://doi.org/10.1016/S1359-6454(02)00535-9	journal	April 2003
Thermodynamically consistent variational principles with applications to electrically and magnetically active systems Garcı́a, R. Edwin; Bishop, Catherine M.; Carter, W. Craig Acta Materialia, Vol. 52, Issue 1 https://doi.org/10.1016/j.actamat.2003.08.020	journal	January 2004
Phase field approach to heterogeneous crystal nucleation in alloys Warren, James A.; Pusztai, Tamás; Környei, László Physical Review B, Vol. 79, Issue 1 https://doi.org/10.1103/PhysRevB.79.014204	journal	January 2009
FiPy: Partial Differential Equations with Python Guyer, Jonathan E.; Wheeler, Daniel; Warren, James A. Computing in Science & Engineering, Vol. 11, Issue 3 https://doi.org/10.1109/MCSE.2009.52	journal	May 2009
Operando video microscopy of Li plating and re-intercalation on graphite anodes during fast charging Chen, Yuxin; Chen, Kuan-Hung; Sanchez, Adrian J. Journal of Materials Chemistry A, Vol. 9, Issue 41 https://doi.org/10.1039/D1TA06023F	journal	January 2021
Effect of Electrolyte Composition on Lithium Dendrite Growth Crowther, Owen; West, Alan C. Journal of The Electrochemical Society, Vol. 155, Issue 11 https://doi.org/10.1149/1.2969424	journal	January 2008
Dendrite Growth in Lithium/Polymer Systems Monroe, Charles; Newman, John Journal of The Electrochemical Society, Vol. 150, Issue 10 https://doi.org/10.1149/1.1606686	journal	January 2003
Investigating Lithium Plating in Lithium-Ion Batteries at Low Temperatures Using Electrochemical Model with NMR Assisted Parameterization Ge, Hao; Aoki, Tetsuya; Ikeda, Nobuhisa Journal of The Electrochemical Society, Vol. 164, Issue 6 https://doi.org/10.1149/2.0461706jes	journal	January 2017
Thermodynamic and kinetic properties of the Li-graphite system from first-principles calculations Persson, Kristin; Hinuma, Yoyo; Meng, Ying Shirley Physical Review B, Vol. 82, Issue 12 https://doi.org/10.1103/PhysRevB.82.125416	journal	September 2010
Phase-Field Simulation of Solidification Boettinger, W. J.; Warren, J. A.; Beckermann, C. Annual Review of Materials Research, Vol. 32, Issue 1 https://doi.org/10.1146/annurev.matsci.32.101901.155803	journal	August 2002

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