Molecular Characterization of Water-Soluble Brown Carbon Chromophores in Snowpack from Northern Xinjiang, China

Zhou, Yue; West, Christopher P.; Hettiyadura, Anusha P. S.; Pu, Wei; Shi, Tenglong; Niu, Xiaoying; Wen, Hui; Cui, Jiecan; Wang, Xin; Laskin, Alexander

doi:10.1021/acs.est.1c07972

Molecular Characterization of Water-Soluble Brown Carbon Chromophores in Snowpack from Northern Xinjiang, China

Journal Article · Tue Mar 15 00:00:00 EDT 2022 · Environmental Science and Technology

DOI:https://doi.org/10.1021/acs.est.1c07972· OSTI ID:1867341

^[1]; ^[2]; ^[2]; Pu, Wei ^[3]; Shi, Tenglong ^[3]; Niu, Xiaoying ^[3]; Wen, Hui ^[3]; Cui, Jiecan ^[3]; ^[4]; ^[2]

Lanzhou Univ. (China); Purdue Univ., West Lafayette, IN (United States); Purdue University
Purdue Univ., West Lafayette, IN (United States)
Lanzhou Univ. (China)
Lanzhou Univ. (China); Tianjin Univ. (China)

This study reports molecular-level characterization of brown carbon (BrC) attributed to water-soluble organic carbon in six snowpack samples collected from northern Xinjiang, China. Here, the molecular composition and light-absorbing properties of BrC chromophores were unraveled by application of high-performance liquid chromatography (HPLC) coupled to a photodiode array (PDA) detector and high-resolution mass spectrometry. The chromophores were classified into five major types, that is, (1) phenolic/lignin-derived compounds, (2) flavonoids, (3) nitroaromatics, (4) oxygenated aromatics, and (5) other chromophores. Identified chromophores account for ~23–64% of the total light absorption measured by the PDA detector in the wavelength range of 300–370 nm. In the representative samples from urban and remote areas, oxygenated aromatics and nitroaromatics dominate the absorption in the wavelengths below and above 320 nm, respectively. The highly polluted urban sample shows the most complex HPLC-PDA chromatogram, and more other chromophores contribute to the bulk absorption. Phenolic/ lignin-derived compounds are the most light-absorbing species in the soil-influenced sample. Chromophores in two remote samples exhibit ultraviolet–visible features distinct from other samples, which are attributed to flavonoids. Identification of individual chromophores and quantitative analysis of their optical properties are helpful for elucidating the roles of BrC in snow radiative balance and photochemistry.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Atmospheric Radiation Measurement (ARM) Data Center; Purdue Univ., West Lafayette, IN (United States)

Sponsoring Organization:: China Scholarship Council (CSC); National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Contributing Organization:: Argonne National Laboratory (ANL); Brookhaven National Laboratory (BNL); Lanzhou University; Pacific Northwest National Laboratory (PNNL)

Grant/Contract Number:: SC0021977

OSTI ID:: 1867341

Alternate ID(s):: OSTI ID: 1880349
OSTI ID: 1908099

Journal Information:: Environmental Science and Technology, Journal Name: Environmental Science and Technology Journal Issue: 7 Vol. 56; ISSN 0013-936X

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Organics in environmental ices: sources, chemistry, and impacts McNeill, V. F.; Grannas, A. M.; Abbatt, J. P. D. Atmospheric Chemistry and Physics, Vol. 12, Issue 20 https://doi.org/10.5194/acp-12-9653-2012	journal	January 2012
The role of the global cryosphere in the fate of organic contaminants Grannas, A. M.; Bogdal, C.; Hageman, K. J. Atmospheric Chemistry and Physics, Vol. 13, Issue 6 https://doi.org/10.5194/acp-13-3271-2013	journal	January 2013
Brown carbon: a significant atmospheric absorber of solar radiation? Feng, Y.; Ramanathan, V.; Kotamarthi, V. R. Atmospheric Chemistry and Physics, Vol. 13, Issue 17 https://doi.org/10.5194/acp-13-8607-2013	journal	January 2013
Sources and light absorption of water-soluble organic carbon aerosols in the outflow from northern China Kirillova, E. N.; Andersson, A.; Han, J. Atmospheric Chemistry and Physics, Vol. 14, Issue 3 https://doi.org/10.5194/acp-14-1413-2014	journal	January 2014
Biomass burning emissions and potential air quality impacts of volatile organic compounds and other trace gases from fuels common in the US Gilman, J. B.; Lerner, B. M.; Kuster, W. C. Atmospheric Chemistry and Physics, Vol. 15, Issue 24 https://doi.org/10.5194/acp-15-13915-2015	journal	January 2015
Characterization of primary and secondary wood combustion products generated under different burner loads Bruns, E. A.; Krapf, M.; Orasche, J. Atmospheric Chemistry and Physics, Vol. 15, Issue 5 https://doi.org/10.5194/acp-15-2825-2015	journal	January 2015
Dicarboxylic acids, ketocarboxylic acids, α-dicarbonyls, fatty acids and benzoic acid in PM_2.5 aerosol collected during CAREBeijing-2007: an effect of traffic restriction on air quality Ho, K. F.; Huang, R. -J.; Kawamura, K. Atmospheric Chemistry and Physics, Vol. 15, Issue 6 https://doi.org/10.5194/acp-15-3111-2015	journal	January 2015
Secondary organic aerosol from atmospheric photooxidation of indole Montoya-Aguilera, Julia; Horne, Jeremy R.; Hinks, Mallory L. Atmospheric Chemistry and Physics, Vol. 17, Issue 18 https://doi.org/10.5194/acp-17-11605-2017	journal	January 2017
Snow scavenging and phase partitioning of nitrated and oxygenated aromatic hydrocarbons in polluted and remote environments in central Europe and the European Arctic Shahpoury, Pourya; Kitanovski, Zoran; Lammel, Gerhard Atmospheric Chemistry and Physics, Vol. 18, Issue 18 https://doi.org/10.5194/acp-18-13495-2018	journal	January 2018
Large contribution of fossil fuel derived secondary organic carbon to water soluble organic aerosols in winter haze in China Zhang, Yan-Lin; El-Haddad, Imad; Huang, Ru-Jin Atmospheric Chemistry and Physics, Vol. 18, Issue 6 https://doi.org/10.5194/acp-18-4005-2018	journal	January 2018
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Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol Fleming, Lauren T.; Lin, Peng; Roberts, James M. Atmospheric Chemistry and Physics, Vol. 20, Issue 2 https://doi.org/10.5194/acp-20-1105-2020	journal	January 2020
Secondary organic aerosol yields from the oxidation of benzyl alcohol Charan, Sophia M.; Buenconsejo, Reina S.; Seinfeld, John H. Atmospheric Chemistry and Physics, Vol. 20, Issue 21 https://doi.org/10.5194/acp-20-13167-2020	journal	January 2020
Relationship between the molecular composition, visible light absorption, and health-related properties of smoldering woodsmoke aerosols Chan, Lam Kam; Nguyen, Khanh Q.; Karim, Noreen Atmospheric Chemistry and Physics, Vol. 20, Issue 1 https://doi.org/10.5194/acp-20-539-2020	journal	January 2020
Molecular composition and photochemical evolution of water-soluble organic carbon (WSOC) extracted from field biomass burning aerosols using high-resolution mass spectrometry Cai, Jing; Zeng, Xiangying; Zhi, Guorui Atmospheric Chemistry and Physics, Vol. 20, Issue 10 https://doi.org/10.5194/acp-20-6115-2020	journal	January 2020
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Measurement report: Molecular composition, optical properties, and radiative effects of water-soluble organic carbon in snowpack samples from northern Xinjiang, China Zhou, Yue; West, Christopher P.; Hettiyadura, Anusha P. S. Atmospheric Chemistry and Physics, Vol. 21, Issue 11 https://doi.org/10.5194/acp-21-8531-2021	journal	January 2021
Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols Andreae, M. O.; Gelencsér, A. Atmospheric Chemistry and Physics, Vol. 6, Issue 10 https://doi.org/10.5194/acp-6-3131-2006	journal	January 2006
An overview of snow photochemistry: evidence, mechanisms and impacts Grannas, A. M.; Jones, A. E.; Dibb, J. Atmospheric Chemistry and Physics, Vol. 7, Issue 16 https://doi.org/10.5194/acp-7-4329-2007	journal	January 2007
Emission of sunscreen salicylic esters from desert vegetation and their contribution to aerosol formation Matsunaga, S. N.; Guenther, A. B.; Potosnak, M. J. Atmospheric Chemistry and Physics, Vol. 8, Issue 24 https://doi.org/10.5194/acp-8-7367-2008	journal	January 2008
Aromatic acids in an Arctic ice core from Svalbard: a proxy record of biomass burning Grieman, Mackenzie M.; Aydin, Murat; Isaksson, Elisabeth Climate of the Past, Vol. 14, Issue 5 https://doi.org/10.5194/cp-14-637-2018	journal	January 2018
Confirming anthropogenic influences on the major organic and inorganic constituents of rainwater in an urban area Chon, K.; Kim, Y.; Bae, D. H. Drinking Water Engineering and Science, Vol. 8, Issue 2 https://doi.org/10.5194/dwes-8-35-2015	journal	January 2015
Concentration, sources and light absorption characteristics of dissolved organic carbon on a medium-sized valley glacier, northern Tibetan Plateau Yan, Fangping; Kang, Shichang; Li, Chaoliu The Cryosphere, Vol. 10, Issue 6 https://doi.org/10.5194/tc-10-2611-2016	journal	January 2016
Properties of black carbon and other insoluble light-absorbing particles in seasonal snow of northwestern China Pu, Wei; Wang, Xin; Wei, Hailun The Cryosphere, Vol. 11, Issue 3 https://doi.org/10.5194/tc-11-1213-2017	journal	January 2017
Quantifying bioalbedo: a new physically based model and discussion of empirical methods for characterising biological influence on ice and snow albedo Cook, Joseph M.; Hodson, Andrew J.; Gardner, Alex S. The Cryosphere, Vol. 11, Issue 6 https://doi.org/10.5194/tc-11-2611-2017	journal	January 2017

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