Correlation of Oxygen Anion Redox Activity to In‐Plane Honeycomb Cation Ordering in Na x Ni y Mn 1− y O 2 Cathodes

Li, Mengya; Jafta, Charl J.; Geng, Linxiao; Liu, Jue; Bai, Yaocai; Li, Jianlin; Essehli, Rachid; Belharouak, Ilias

doi:10.1002/aesr.202200027

Title: Correlation of Oxygen Anion Redox Activity to In‐Plane Honeycomb Cation Ordering in Na _x Ni _y Mn _{1− y} O ₂ Cathodes

Journal Article · Tue May 10 00:00:00 EDT 2022 · Advanced Energy and Sustainability Research

DOI:https://doi.org/10.1002/aesr.202200027· OSTI ID:1867051

Li, Mengya ^[1]; Jafta, Charl J. ^[1]; Geng, Linxiao ^[1]; Liu, Jue ^[2]; Bai, Yaocai ^[1]; Li, Jianlin ^[1]; Essehli, Rachid ^[1];

^[1]

Electrification and Energy Infrastructure Division Oak Ridge National Laboratory Oak Ridge TN 37830 USA
Neutron Scattering Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA

Sodium‐ion batteries (SIBs) are one of the most promising next‐generation energy storage systems because of their abundant and low‐cost component materials. However, the lower energy density of SIBs compared with lithium‐ion batteries diminishes their practical value proposition. Among the many sodium‐based cathodes, layered transition metal oxides with high sodium content have energy densities comparable with the lithium‐ion battery technology. When charged above 4.1 V, the sodium‐based cathodes often undergo transformations because the activation of oxygen anion redox causes irreversible oxygen release, transition metal ion migration, lattice distortion, and rapid capacity decay. Here, in situ gas analysis is performed to evaluate the lattice oxygen anion redox activity in Na _x Ni _y Mn _{1− y} O ₂ cathodes with P2 and O3 structural orderings. Operando X‐ray diffraction and neutron diffraction are performed to assess the structural changes related to lattice oxygen redox and transition metal ion migration in Na _x Ni _y Mn _{1− y} O ₂ cathodes. The results unveil that in‐plane honeycomb cationic ordering can help suppress oxygen anion redox activity, which is critical for the future design of layered transition metal oxide cathodes that are prone to achieve high‐energy for durable SIBs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1867051

Alternate ID(s):: OSTI ID: 1867055; OSTI ID: 1870237

Journal Information:: Advanced Energy and Sustainability Research, Journal Name: Advanced Energy and Sustainability Research Vol. 3 Journal Issue: 7; ISSN 2699-9412

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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25 ENERGY STORAGE
anionic redux
cation ordering
eutectic synthesis
gas analyses
sodium-ion batteries

Title: Correlation of Oxygen Anion Redox Activity to In‐Plane Honeycomb Cation Ordering in Na x Ni y Mn 1− y O 2 Cathodes

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Title: Correlation of Oxygen Anion Redox Activity to In‐Plane Honeycomb Cation Ordering in Na _x Ni _y Mn _{1− y} O ₂ Cathodes