Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis

Jiang, Xiao; Sharma, Lohit; Fung, Victor; Park, Sang Jae; Jones, Christopher W.; Sumpter, Bobby G.; Baltrusaitis, Jonas; Wu, Zili

doi:10.1021/acscatal.0c03999

Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis

Journal Article · Thu Feb 04 00:00:00 EST 2021 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.0c03999· OSTI ID:1866713

^[1]; Sharma, Lohit ^[2]; ^[1]; Park, Sang Jae ^[3]; ^[3]; ^[1]; ^[2]; ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Lehigh Univ., Bethlehem, PA (United States)
Georgia Institute of Technology, Atlanta, GA (United States)

Oxidative dehydrogenation of propane to propylene can be achieved using conventional, oxygen-assisted dehydrogenation of propane (O₂–ODHP) or via the use of soft oxidants, such as CO₂, N₂O, S-containing compounds, and halogens/halides. The major roles of soft oxidants include inhibiting overoxidation and improving propylene selectivity, which are considered to be current challenges in O₂-assisted dehydrogenation. For both CO₂– and N₂O–ODHP reactions, significant efforts have been devoted to developing redox-active (e.g., chromium, vanadate, iron, etc.), nonredox-type main group metal oxide (e.g., group IIIA, gallium), and other transition metal/metal oxide catalysts (e.g., molybdenum, palladium platinum, rhodium, ruthenium, etc.), as well as zeolite-based catalysts with adjustable acid–base properties, unique pore structures, and topologies. Metal sulfides have shown promising performance in DHP, whereas the development of suitable catalysts has lagged for SO₂- or S-assisted ODHP. Recently, significant efforts have been focused on homogeneous and heterogeneous ODHP using halogens (e.g., Br₂, I₂, Cl₂, etc.) and hydrogen halides (e.g., HCl and HBr) for the development of facile processes for C₃H₆ synthesis. This work aims to provide a critical, comprehensive review of recent advances in oxidative dehydrogenation of propane with these soft oxidants, especially highlighting the current state of understanding of the following factors: (i) relationships between composition, structure, and catalytic performance, (ii) effects of the support, acidity, and promoters, (iii) reaction pathway and mechanistic insights, and (iv) the various roles of soft oxidants. Theoretical and computational insights toward understanding reaction mechanisms and catalyst design principles are also covered. Future research opportunities are discussed in terms of catalyst design and synthesis, deactivation and regeneration, reaction mechanisms, and alternative approaches.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1866713

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 4 Vol. 11; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (283)

High H ₂ permeable SAPO‐34 hollow fiber membrane for high temperature propane dehydrogenation application Wang, Zhigang; Xu, Jeff; Pati, Subhasis AIChE Journal, Vol. 66, Issue 9 https://doi.org/10.1002/aic.16278	journal	June 2020
The effects of bimetallic interactions for CO ₂ ‐assisted oxidative dehydrogenation and dry reforming of propane Gomez, Elaine; Xie, Zhenhua; Chen, Jingguang G. AIChE Journal, Vol. 65, Issue 8 https://doi.org/10.1002/aic.16670	journal	June 2019
Chemistry with Methane: Concepts Rather than Recipes Schwarz, Helmut Angewandte Chemie International Edition, Vol. 50, Issue 43 https://doi.org/10.1002/anie.201006424	journal	June 2011
Sites for Methane Activation on Lithium-Doped Magnesium Oxide Surfaces Kwapien, Karolina; Paier, Joachim; Sauer, Joachim Angewandte Chemie International Edition, Vol. 53, Issue 33 https://doi.org/10.1002/anie.201310632	journal	April 2014
Identifying Different Types of Catalysts for CO ₂ Reduction by Ethane through Dry Reforming and Oxidative Dehydrogenation Porosoff, Marc D.; Myint, Myat Noe Zin; Kattel, Shyam Angewandte Chemie International Edition, Vol. 54, Issue 51 https://doi.org/10.1002/anie.201508128	journal	November 2015
Europium Oxybromide Catalysts for Efficient Bromine Looping in Natural Gas Valorization Paunović, Vladimir; Lin, Ronghe; Scharfe, Matthias Angewandte Chemie International Edition, Vol. 56, Issue 33 https://doi.org/10.1002/anie.201704406	journal	August 2017
Olefins from Natural Gas by Oxychlorination Zichittella, Guido; Aellen, Nicolas; Paunović, Vladimir Angewandte Chemie International Edition, Vol. 56, Issue 44 https://doi.org/10.1002/anie.201706624	journal	August 2017
Halogen‐Dependent Surface Confinement Governs Selective Alkane Functionalization to Olefins Zichittella, Guido; Scharfe, Matthias; Puértolas, Begoña Angewandte Chemie International Edition, Vol. 58, Issue 18 https://doi.org/10.1002/anie.201811669	journal	April 2019
Engineering of Ruthenium–Iron Oxide Colloidal Heterostructures: Improved Yields in CO ₂ Hydrogenation to Hydrocarbons Aitbekova, Aisulu; Goodman, Emmett D.; Wu, Liheng Angewandte Chemie International Edition, Vol. 58, Issue 48 https://doi.org/10.1002/anie.201910579	journal	November 2019
Radical Chemistry and Reaction Mechanisms of Propane Oxidative Dehydrogenation over Hexagonal Boron Nitride Catalysts Zhang, Xuanyu; You, Rui; Wei, Zeyue Angewandte Chemie International Edition, Vol. 59, Issue 21 https://doi.org/10.1002/anie.202002440	journal	April 2020
Why Boron Nitride is such a Selective Catalyst for the Oxidative Dehydrogenation of Propane Venegas, Juan M.; Zhang, Zisheng; Agbi, Theodore O. Angewandte Chemie International Edition, Vol. 59, Issue 38 https://doi.org/10.1002/anie.202003695	journal	July 2020
Alternative Oxidants for the Catalytic Oxidative Coupling of Methane Arinaga, Allison M.; Ziegelski, Morgan C.; Marks, Tobin J. Angewandte Chemie International Edition, Vol. 60, Issue 19 https://doi.org/10.1002/anie.202012862	journal	January 2021
Promotional Effect of Ni on a CrO _x Catalyst Supported on Silica in the Oxidative Dehydrogenation of Propane with CO ₂ Yun, Danim; Baek, Jayeon; Choi, Youngbo ChemCatChem, Vol. 4, Issue 12 https://doi.org/10.1002/cctc.201200397	journal	October 2012
Interplay Between Bromine and Iodine in Oxidative Dehydrogenation Ding, Kunlun; Metiu, Horia; Stucky, Galen D. ChemCatChem, Vol. 5, Issue 7 https://doi.org/10.1002/cctc.201200913	journal	March 2013
Oxidative Dehydrogenation of Ethane: Common Principles and Mechanistic Aspects Gärtner, Christian A.; van Veen, André C.; Lercher, Johannes A. ChemCatChem, Vol. 5, Issue 11 https://doi.org/10.1002/cctc.201200966	journal	March 2013
Isobutane Dehydrogenation over Metal (Fe, Co, and Ni) Oxide and Sulfide Catalysts: Reactivity and Reaction Mechanism Wang, Guowei; Gao, Chuancheng; Zhu, Xiaolin ChemCatChem, Vol. 6, Issue 8 https://doi.org/10.1002/cctc.201402173	journal	July 2014
Three-Dimensional Mesoporous Gallosilicate withPm3n Symmetry and its Unusual Catalytic Performances Srinivasu, Pavuluri; Vinu, Ajayan Chemistry - A European Journal, Vol. 14, Issue 12 https://doi.org/10.1002/chem.200701946	journal	April 2008
Sulphur/halogen promoted oxidative dehydrogenation of hydrocarbons Pasternak, I. S.; Vadekar, M. The Canadian Journal of Chemical Engineering, Vol. 48, Issue 2 https://doi.org/10.1002/cjce.5450480221	journal	April 1970
H ₂ S Promoted Oxidative Dehydrogenation of Hydrocarbons in Molten Media Gaspar, N. J.; Pasternak, I. S.; Vadekar, M. The Canadian Journal of Chemical Engineering, Vol. 52, Issue 6 https://doi.org/10.1002/cjce.5450520615	journal	December 1974
Dehydrogenation of Propane to Propylene in the Presence of CO2 over Steaming-treated HZSM-5 Supported ZnO Zhang, Fan; Miao, Changxi; Yue, Yinghong Chinese Journal of Chemistry, Vol. 30, Issue 4 https://doi.org/10.1002/cjoc.201100379	journal	April 2012
Thermally Stable Nanocrystalline Mesoporous Gallium Oxide Phases Deshmane, Chinmay A.; Jasinski, Jacek B.; Carreon, Moises A. European Journal of Inorganic Chemistry, Vol. 2009, Issue 22, p. 3275-3281 https://doi.org/10.1002/ejic.200900359	journal	August 2009
Carbon Dioxide as Feedstock in Selective Oxidation of Propane Kang, Jungshik; Czaja, Andrew D.; Guliants, Vadim V. European Journal of Inorganic Chemistry, Vol. 2017, Issue 40 https://doi.org/10.1002/ejic.201701049	journal	October 2017
Oxidative Dehydrogenation of Ethane: A Chemical Looping Approach Neal, Luke M.; Yusuf, Seif; Sofranko, John A. Energy Technology, Vol. 4, Issue 10 https://doi.org/10.1002/ente.201600074	journal	June 2016
Alkane Functionalization via Catalytic Oxychlorination: Performance as a Function of the Carbon Number Zichittella, Guido; Lüthi, James; Paunović, Vladimir Energy Technology, Vol. 8, Issue 8 https://doi.org/10.1002/ente.201900622	journal	July 2019
Kinetic investigations of the reaction of propane with sulphur dioxide on a palladium-alumina catalyst Ashmawy, Fathy M. Journal of Chemical Technology and Biotechnology. Chemical Technology, Vol. 34, Issue 4 https://doi.org/10.1002/jctb.5040340407	journal	May 1984
Oxidative Coupling of Methane over a Li+/MgO Catalyst Using N2O as an Oxidant Yamamoto, H.; Chu, H. Y.; Xu, M. T. Journal of Catalysis, Vol. 142, Issue 1 https://doi.org/10.1006/jcat.1993.1211	journal	July 1993
Chemical and Physical Characterization of Alumina-Supported Chromia-Based Catalysts and Their Activity in Dehydrogenation of Isobutane Cavani, F.; Koutyrev, M.; Trifirò, F. Journal of Catalysis, Vol. 158, Issue 1 https://doi.org/10.1006/jcat.1996.0023	journal	January 1996
The Effect of Reaction Conditions and Time on Stream on the Coke Formed during Propane Dehydrogenation Larsson, Mikael; Hultén, Magnus; Blekkan, Edd A. Journal of Catalysis, Vol. 164, Issue 1 https://doi.org/10.1006/jcat.1996.0361	journal	November 1996
Aromatization of Methane over Supported and Unsupported Mo-Based Catalysts Solymosi, F.; Cserényi, J.; Szöke, A. Journal of Catalysis, Vol. 165, Issue 2 https://doi.org/10.1006/jcat.1997.1478	journal	January 1997
Role of Tetrachloromethane as a Gas-Phase Additive in the Oxidative Dehydrogenation of Propane over Cerium Oxide Sugiyama, Shigeru; Iizuka, Yutaka; Nitta, Etsushi Journal of Catalysis, Vol. 189, Issue 1 https://doi.org/10.1006/jcat.1999.2700	journal	January 2000
Evidence for Oxidation of Ceria by CO2 Sharma, S.; Hilaire, S.; Vohs, J. M. Journal of Catalysis, Vol. 190, Issue 1 https://doi.org/10.1006/jcat.1999.2746	journal	February 2000
Vanadium-Containing MCM-41 for Partial Oxidation of Lower Alkanes Zhang, Qinghong; Wang, Ye; Ohishi, Yoshihiko Journal of Catalysis, Vol. 202, Issue 2 https://doi.org/10.1006/jcat.2001.3276	journal	September 2001
Physicochemical Characterization of Isomorphously Substituted FeZSM-5 during Activation Pérez-Ramírez, J.; Mul, G.; Kapteijn, F. Journal of Catalysis, Vol. 207, Issue 1 https://doi.org/10.1006/jcat.2002.3511	journal	April 2002
Effect of Catalyst Structure on Oxidative Dehydrogenation of Ethane and Propane on Alumina-Supported Vanadia Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T. Journal of Catalysis, Vol. 208, Issue 1 https://doi.org/10.1006/jcat.2002.3570	journal	May 2002
Characterizations of Iron-Containing MCM-41 and Its Catalytic Properties in Epoxidation of Styrene with Hydrogen Peroxide Wang, Ye; Zhang, Qinghong; Shishido, Tetsuya Journal of Catalysis, Vol. 209, Issue 1 https://doi.org/10.1006/jcat.2002.3607	journal	July 2002
Conversion of methane to benzene over Mo2C and Mo2C/ZSM-5 catalysts Solymosi, F.; Sz�ke, A.; Cser�nyi, J. Catalysis Letters, Vol. 39, Issue 3-4 https://doi.org/10.1007/BF00805576	journal	January 1996
Propane dehydrogenation by SO2 in the presence of carbon Ushkov, S. B.; Osipova, Z. G.; Sokolovskii, V. D. Reaction Kinetics and Catalysis Letters, Vol. 36, Issue 1 https://doi.org/10.1007/BF02071147	journal	March 1988
Role of silica-alumina catalyst texture in the reaction of propane oxidative dehydrogenation in the presence of sulfur dioxide Danilova, I. G.; Ivanova, A. S. Kinetics and Catalysis, Vol. 41, Issue 4 https://doi.org/10.1007/BF02756077	journal	July 2000
Effect of supports on catalytic activity of chromium oxide-based catalysts in the dehydrogenation of propane with CO2 Kocoń, Małgorzata; Michorczyk, Piotr; Ogonowski, Jan Catalysis Letters, Vol. 101, Issue 1-2 https://doi.org/10.1007/s10562-004-3749-6	journal	May 2005
Dehydrogenation of propane over a silica-supported vanadium oxide catalyst Takahara, Isao; Saito, Masahiro; Inaba, Megumu Catalysis Letters, Vol. 102, Issue 3-4 https://doi.org/10.1007/s10562-005-5856-4	journal	August 2005
Dehydrogenation of Propane in the Presence and Absence of CO2 Over β-Ga2O3 Supported Chromium Oxide Catalysts Michorczyk, P.; Góra-Marek, K.; Ogonowski, J. Catalysis Letters, Vol. 109, Issue 3-4 https://doi.org/10.1007/s10562-006-0077-z	journal	July 2006
Enhanced Activity of Spinel-type Ga2O3–Al2O3 Mixed Oxide for the Dehydrogenation of Propane in the Presence of CO2 Chen, Miao; Xu, Jie; Liu, Yong-Mei Catalysis Letters, Vol. 124, Issue 3-4 https://doi.org/10.1007/s10562-008-9478-5	journal	March 2008
Effect of K Addition on Catalytic Performance of PtSn/ZSM-5 Catalyst for Propane Dehydrogenation Zhang, Shaobo; Zhou, Yuming; Zhang, Yiwei Catalysis Letters, Vol. 135, Issue 1-2 https://doi.org/10.1007/s10562-010-0269-4	journal	January 2010
Oxydehydrogenation of Ethane and Propane over Alkaline Metal Modified Fe-ZSM-5 Zeolites Kowalska-Kuś, J.; Held, A.; Nowińska, K. Catalysis Letters, Vol. 136, Issue 3-4 https://doi.org/10.1007/s10562-010-0328-x	journal	March 2010
Oxidative Dehydrogenation of Propane with CO2 Over Cr/H[B]MFI Catalysts Zhu, Qingjun; Takiguchi, Makoto; Setoyama, Tohru Catalysis Letters, Vol. 141, Issue 5 https://doi.org/10.1007/s10562-011-0566-6	journal	March 2011
Halogen-Mediated Oxidative Dehydrogenation of Propane Using Iodine or Molten Lithium Iodide Upham, D. Chester; Gordon, Michael J.; Metiu, Horia Catalysis Letters, Vol. 146, Issue 4 https://doi.org/10.1007/s10562-016-1701-1	journal	February 2016
An Efficient Cr-TUD-1 Catalyst for Oxidative Dehydrogenation of Propane to Propylene with CO2 as Soft Oxidant Burri, Abhishek; Hasib, Md Abdul; Mo, Yong-Hawn Catalysis Letters, Vol. 148, Issue 2 https://doi.org/10.1007/s10562-017-2282-3	journal	December 2017
Modification of Cr/SiO2 for the dehydrogenation of propane to propylene in carbon dioxide Ge, Xin; Zou, Hu; Wang, Jun Reaction Kinetics and Catalysis Letters, Vol. 85, Issue 2 https://doi.org/10.1007/s11144-005-0268-4	journal	July 2005
Simultaneous propane dehydrogenation andco2hydrogenation overCrOx/SiO2catalyst Michorczyk, Piotr; Ogonowski, Jan Reaction Kinetics and Catalysis Letters, Vol. 87, Issue 1 https://doi.org/10.1007/s11144-006-0024-4	journal	December 2005
Role of CO2 in dehydrogenation of propane over CrOX/SiO2 catalyst with low Cr content Michorczyk, Piotr; Ogonowski, Jan Reaction Kinetics and Catalysis Letters, Vol. 92, Issue 1 https://doi.org/10.1007/s11144-007-5089-1	journal	September 2007
Dehydrogenation of propane to propene over phosphorus-modified HZSM-5 supported Ga2O3 Ren, Yingjie; Hua, Weiming; Yue, Yinghong Reaction Kinetics and Catalysis Letters, Vol. 95, Issue 1 https://doi.org/10.1007/s11144-008-5339-x	journal	October 2008
Effect of oxychlorination treatment on the regeneration of Pt–Sn/Al2O3 catalyst for propane dehydrogenation Kim, Ga Hee; Jung, Kwang-Deog; Kim, Won-Il Research on Chemical Intermediates, Vol. 42, Issue 1 https://doi.org/10.1007/s11164-015-2300-2	journal	October 2015
Oxidative Dehydrogenation of Light Alkanes on Supported Molten Alkali Metal Chloride Catalysts Kumar, Chinthala Praveen; Gaab, Stefan; Müller, Thomas E. Topics in Catalysis, Vol. 50, Issue 1-4 https://doi.org/10.1007/s11244-008-9102-3	journal	July 2008
Catalytic oxidations with sulfur dioxide I. Exploratory studies Adams, C. Journal of Catalysis, Vol. 11, Issue 2 https://doi.org/10.1016/0021-9517(68)90017-1	journal	June 1968
Catalytic oxidative dehydrogenation of propane to propylene Ashmawy, F. Journal of Catalysis, Vol. 46, Issue 3 https://doi.org/10.1016/0021-9517(77)90228-7	journal	March 1977
The role of sulfur in deactivation of Pt/MgAl2O4 for propane dehydrogenation Rennard, R. Journal of Catalysis, Vol. 98, Issue 2 https://doi.org/10.1016/0021-9517(86)90312-X	journal	April 1986
Isobutane dehydrogenation over sulfided nickel catalysts Resasco, D.; Marcus, B.; Huang, C. Journal of Catalysis, Vol. 146, Issue 1 https://doi.org/10.1016/0021-9517(94)90006-X	journal	March 1994
Oxidative dehydrogenation of propane in lithium hydroxide/lithium iodide melts Dahl, Ivar M.; Grande, Knut; Jens, Klaus-J. Applied Catalysis, Vol. 77, Issue 1 https://doi.org/10.1016/0166-9834(91)80033-S	journal	October 1991
The role of Ga2O3 and proton acidity on the dehydrogenating activity of Ga2O3-HZSM-5 catalysts: evidence of a bifunctional mechanism Meriaudeau, P.; Naccache, C. Journal of Molecular Catalysis, Vol. 59, Issue 3 https://doi.org/10.1016/0304-5102(90)85100-V	journal	April 1990
Catalytic oxidation of methane on MoO3-SiO2 : mechanism of oxidation with O2 and N2O studied by surface potential measurements Barbaux, Y.; Elamrani, A.; Bonnelle, J. P. Catalysis Today, Vol. 1, Issue 1-2 https://doi.org/10.1016/0920-5861(87)80035-4	journal	January 1987
Raman and IR studies of surface metal oxide species on oxide supports: Supported metal oxide catalysts Wachs, Israel E. Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00203-0	journal	February 1996
Aromatization of short chain alkanes on zeolite catalysts Guisnet, M.; Gnep, N. S.; Alario, F. Applied Catalysis A: General, Vol. 89, Issue 1 https://doi.org/10.1016/0926-860X(92)80075-N	journal	September 1992
Oxidative dehydrogenation of ethylbenzene with carbon dioxide Sugino, Mitsu-o; Shimada, Hiroshi; Turuda, Tadatoshi Applied Catalysis A: General, Vol. 121, Issue 1 https://doi.org/10.1016/0926-860X(95)85015-5	journal	January 1995
CO 2 reforming of propane over supported Rh Solymosi, F.; Tolmacsov, P.; Kedves, K. Journal of Catalysis, Vol. 216, Issue 1-2 https://doi.org/10.1016/S0021-9517(02)00071-4	journal	May 2003
Oxidative conversion of propane over lithium-promoted magnesia catalyst I. Kinetics and mechanism Leveles, L. Journal of Catalysis, Vol. 218, Issue 2 https://doi.org/10.1016/S0021-9517(03)00112-X	journal	September 2003
Characterizations and catalytic properties of Cr-MCM-41 prepared by direct hydrothermal synthesis and template-ion exchange Wang, Ye; Ohishi, Yoshihiko; Shishido, Tetsuya Journal of Catalysis, Vol. 220, Issue 2 https://doi.org/10.1016/S0021-9517(03)00278-1	journal	December 2003
Supported rhodium nanoparticles in catalysis: the role of stabilizers on catalytic activity and structural features Vitulli, Giovanni; Evangelisti, Claudio; Pertici, Paolo Journal of Organometallic Chemistry, Vol. 681, Issue 1-2 https://doi.org/10.1016/S0022-328X(03)00529-1	journal	September 2003
Reactions of propane over a bifunctional Pt/H-ZSM-5 catalyst Engelen, C. W. R.; Wolthuizen, J. P.; van Hooff, J. H. C. Applied Catalysis, Vol. 19, Issue 1 https://doi.org/10.1016/S0166-9834(00)82677-9	journal	January 1985
CO₂Dehydrogenation of Propane over Cr-MCM-41 Catalyst Takehira, K.; Oishi, Y.; Shishido, T. Studies in Surface Science and Catalysis, Vol. 153, p. 323-328 https://doi.org/10.1016/S0167-2991(04)80271-4	book	December 2003
Oxidative dehydrogenation of propane on rare earth vanadates influence of the presence of CO2 in the feed Zhaorigetu, Bao; Kieffer, Roger; Hindermann, Jean-Paul Studies in Surface Science and Catalysis, Vol. 101, p. 1049-1058 https://doi.org/10.1016/S0167-2991(96)80316-8	book	December 1995
An attempt to explain the role of CO2 and N2O as gas dopes in the feed in the oxidative dehydrogenation of propane Dury, F.; Centeno, M. A.; Gaigneaux, E. M. Catalysis Today, Vol. 81, Issue 2 https://doi.org/10.1016/S0920-5861(03)00120-2	journal	June 2003
Dehydrogenation of light alkanes over oxidized diamond-supported catalysts in the presence of carbon dioxide Nakagawa, Kiyoharu; Kajita, Chiaki; Ikenaga, Na-oki Catalysis Today, Vol. 84, Issue 3-4 https://doi.org/10.1016/S0920-5861(03)00268-2	journal	September 2003
Oxidative dehydrogenation of n-butane on MgO-supported vanadium oxide catalysts López Nieto, J. M.; Dejoz, A.; Vazquez, M. I. Catalysis Today, Vol. 40, Issue 2-3 https://doi.org/10.1016/S0920-5861(98)00010-8	journal	April 1998
Promoting effects of CO2 on dehydrogenation of propane over a SiO2-supported Cr2O3 catalyst Takahara, I.; Chang, W. -C; Mimura, N. Catalysis Today, Vol. 45, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00245-4	journal	October 1998
Effect of SO2 on the catalytic activity of Ga2O3–Al2O3 for the selective reduction of NO with propene in the presence of oxygen Haneda, Masaaki; Kintaichi, Yoshiaki; Hamada, Hideaki Applied Catalysis B: Environmental, Vol. 31, Issue 4 https://doi.org/10.1016/S0926-3373(00)00286-1	journal	June 2001
Activity enhancement of SnO2-doped Ga2O3–Al2O3 catalysts by coexisting H2O for the selective reduction of NO with propene Haneda, M. Applied Catalysis B: Environmental, Vol. 20, Issue 4 https://doi.org/10.1016/S0926-3373(98)00117-9	journal	April 1999
Screening of catalysts in the oxidative dehydrogenation of ethylbenzene with carbon dioxide Badstube, T.; Papp, H.; Dziembaj, R. Applied Catalysis A: General, Vol. 204, Issue 1 https://doi.org/10.1016/S0926-860X(00)00514-7	journal	November 2000
Dehydrogenation and oxydehydrogenation of paraffins to olefins Bhasin, M. M.; McCain, J. H.; Vora, B. V. Applied Catalysis A: General, Vol. 221, Issue 1-2, p. 397-419 https://doi.org/10.1016/S0926-860X(01)00816-X	journal	November 2001
Catalytic oxidative dehydrogenation of propane in the presence of O2 and N2O—the role of vanadia distribution and oxidant activation Kondratenko, E. V.; Baerns, M. Applied Catalysis A: General, Vol. 222, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00836-5	journal	December 2001
Propane oxydehydrogenation over transition metal modified zeolite ZSM-5 Nowińska, K.; Wącław, A.; Izbińska, A. Applied Catalysis A: General, Vol. 243, Issue 2 https://doi.org/10.1016/S0926-860X(02)00504-5	journal	April 2003
The active role of CO2 at low temperature in oxidation processes: the case of the oxidative dehydrogenation of propane on NiMoO4 catalysts Dury, F.; Gaigneaux, E. M.; Ruiz, P. Applied Catalysis A: General, Vol. 242, Issue 1 https://doi.org/10.1016/S0926-860X(02)00516-1	journal	March 2003
Interaction of N2O (as gas dope) with nickel molybdate catalysts during the oxidative dehydrogenation of propane to propylene Dury, F.; Centeno, M. A.; Gaigneaux, E. M. Applied Catalysis A: General, Vol. 247, Issue 2 https://doi.org/10.1016/S0926-860X(03)00103-0	journal	July 2003
Effect of H2–O2 pre-treatments on the state of gallium in Ga/H-ZSM-5 propane aromatisation catalysts Nowak, I. Applied Catalysis A: General, Vol. 251, Issue 1 https://doi.org/10.1016/S0926-860X(03)00299-0	journal	September 2003
Dehydrogenation of propane to propene over gallium oxide in the presence of CO2 Michorczyk, P. Applied Catalysis A: General, Vol. 251, Issue 2 https://doi.org/10.1016/S0926-860X(03)00368-5	journal	September 2003
Dehydrogenation of isobutane to isobutene with iron-loaded activated carbon catalyst Shimada, Hiroshi; Akazawa, Taro; Ikenaga, Na-oki Applied Catalysis A: General, Vol. 168, Issue 2 https://doi.org/10.1016/S0926-860X(97)00350-5	journal	March 1998
Hydrocarbon conversion on ZSM-5 in the presence of N2O: relative reactivity and routes of product formation studied by GC-MS and 13C NMR Vereshchagin, S. N.; Kirik, N. P.; Shishkina, N. N. Journal of Molecular Catalysis A: Chemical, Vol. 158, Issue 1 https://doi.org/10.1016/S1381-1169(00)00108-4	journal	September 2000
Manganese-containing MCM-41 for epoxidation of styrene and stilbene Zhang, Qinghong; Wang, Ye; Itsuki, Satoko Journal of Molecular Catalysis A: Chemical, Vol. 188, Issue 1-2 https://doi.org/10.1016/S1381-1169(02)00323-0	journal	September 2002
Effect of the phase transition of iron (III) oxide on the oxidative dehydrogenation of propane in the presence and absence of tetrachloromethane Sugiyama, Shigeru; Kastuma, Keishi; Fukuda, Nobuyuki Catalysis Communications, Vol. 2, Issue 9 https://doi.org/10.1016/S1566-7367(01)00047-4	journal	November 2001
Dual character of H2S as promoter and inhibitor for hydrodesulfurization of dibenzothiophene Farag, Hamdy; Sakanishi, Kinya; Kouzu, Masato Catalysis Communications, Vol. 4, Issue 7 https://doi.org/10.1016/S1566-7367(03)00055-4	journal	July 2003
Ceria in halogen chemistry Scharfe, Matthias; Zichittella, Guido; Paunović, Vladimir Chinese Journal of Catalysis, Vol. 41, Issue 6 https://doi.org/10.1016/S1872-2067(19)63528-X	journal	June 2020
Oxidation of propane with oxygen and/or nitrous oxide over Fe-ZSM-5 with low iron concentrations Bulánek, Roman; Wichterlová, Blanka; Novoveská, Kateřina Applied Catalysis A: General, Vol. 264, Issue 1 https://doi.org/10.1016/j.apcata.2003.12.020	journal	June 2004
Oxidative functionalization of propane over FeMFI zeolites Kondratenko, Evgueni V.; Pérez-Ramı́rez, Javier Applied Catalysis A: General, Vol. 267, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.03.003	journal	July 2004
Impact of the preparation method and iron impurities in Fe-ZSM-5 zeolites for propylene production via oxidative dehydrogenation of propane with N2O Pérez-Ramírez, Javier; Gallardo-Llamas, Amalia Applied Catalysis A: General, Vol. 279, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.10.020	journal	January 2005
Hydrogenation of olefins over hydrotreating catalysts Brémaud, M.; Vivier, L.; Pérot, G. Applied Catalysis A: General, Vol. 289, Issue 1 https://doi.org/10.1016/j.apcata.2005.04.014	journal	August 2005
Synthesis of ZSM-48 zeolites and their catalytic performance in C4-olefin cracking reactions Zhao, Guoliang; Teng, Jiawei; Zhang, Yahong Applied Catalysis A: General, Vol. 299 https://doi.org/10.1016/j.apcata.2005.10.022	journal	January 2006
Influence of reaction conditions on catalyst composition and selective/non-selective reaction pathways of the ODP reaction over V2O3, VO2 and V2O5 with O2 and N2O Kondratenko, Evgenii V.; Ovsitser, Olga; Radnik, Joerg Applied Catalysis A: General, Vol. 319 https://doi.org/10.1016/j.apcata.2006.11.021	journal	March 2007
Carbon dioxide reforming of methane over a metal modified Ni-Al2O3 catalyst Castro Luna, Adolfo E.; Iriarte, María E. Applied Catalysis A: General, Vol. 343, Issue 1-2 https://doi.org/10.1016/j.apcata.2007.11.041	journal	July 2008
Oxidative dehydrogenation of C3–C4 paraffins in the presence of CO2 over CrOx/SiO2 catalysts Botavina, M. A.; Martra, G.; Agafonov, Yu. A. Applied Catalysis A: General, Vol. 347, Issue 2 https://doi.org/10.1016/j.apcata.2008.05.037	journal	September 2008
Chromium oxide supported on MCM-41 as a highly active and selective catalyst for dehydrogenation of propane with CO2 Michorczyk, Piotr; Ogonowski, Jan; Kuśtrowski, Piotr Applied Catalysis A: General, Vol. 349, Issue 1-2 https://doi.org/10.1016/j.apcata.2008.07.008	journal	October 2008
Investigation of catalytic activity of CrSBA-1 materials obtained by direct method in the dehydrogenation of propane with CO2 Michorczyk, Piotr; Ogonowski, Jan; Niemczyk, Marta Applied Catalysis A: General, Vol. 374, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.11.040	journal	February 2010
Oxidative dehydrogenation of propane with N2O over Fe-ZSM-5 and Fe–SiO2: Influence of the iron species and acid sites Ates, Ayten; Hardacre, Christopher; Goguet, Alexandre Applied Catalysis A: General, Vol. 441-442 https://doi.org/10.1016/j.apcata.2012.06.038	journal	October 2012
Oxidative dehydrogenation of propane with nitrous oxide over Fe-ZSM-5 prepared by grafting: Characterization and performance Wu, Guangjun; Hei, Fei; Zhang, Nan Applied Catalysis A: General, Vol. 468 https://doi.org/10.1016/j.apcata.2013.08.051	journal	November 2013
Oxidative dehydrogenation of propane by molecular chlorine Testova, N. V.; Shalygin, A. S.; Kaichev, V. V. Applied Catalysis A: General, Vol. 505 https://doi.org/10.1016/j.apcata.2015.05.018	journal	September 2015
The effects of morphology of cerium oxide catalysts for dehydrogenation of ethylbenzene to styrene Kovacevic, Marijana; Agarwal, Shilpa; Mojet, Barbara L. Applied Catalysis A: General, Vol. 505 https://doi.org/10.1016/j.apcata.2015.07.025	journal	September 2015
Effect of CO2 in the oxidative dehydrogenation reaction of propane over Cr/ZrO2 catalysts de Oliveira, João F. S.; Volanti, Diogo P.; Bueno, José M. C. Applied Catalysis A: General, Vol. 558 https://doi.org/10.1016/j.apcata.2018.03.020	journal	May 2018
Formation of active species for propane dehydrogenation with hydrogen sulfide co-feeding over transition metal catalyst Watanabe, Ryo; Hirata, Nozomu; Miura, Kazuya Applied Catalysis A: General, Vol. 587 https://doi.org/10.1016/j.apcata.2019.117238	journal	October 2019
Evaluation of Fe-zeolite catalysts prepared by different methods for the decomposition of N2O Pieterse, J. Applied Catalysis B: Environmental, Vol. 51, Issue 4 https://doi.org/10.1016/j.apcatb.2004.02.013	journal	August 2004
Nitrous oxide as an oxidant for ethane oxydehydrogenation Held, A.; Kowalska, J.; Nowińska, K. Applied Catalysis B: Environmental, Vol. 64, Issue 3-4 https://doi.org/10.1016/j.apcatb.2005.11.017	journal	May 2006
The oxidizing role of CO2 at mild temperature on ceria-based catalysts Demoulin, O.; Navez, M.; Mugabo, J. -L. Applied Catalysis B: Environmental, Vol. 70, Issue 1-4 https://doi.org/10.1016/j.apcatb.2005.12.024	journal	January 2007
Performance of solvothermally prepared Ga2O3-Al2O3 catalysts for SCR of NO with methane Takahashi, Masaru; Nakatani, Tetsu; Iwamoto, Shinji Applied Catalysis B: Environmental, Vol. 70, Issue 1-4 https://doi.org/10.1016/j.apcatb.2006.01.018	journal	January 2007
The effect of pretreatment on the reactivity of Fe-ZSM-5 catalysts for N2O decomposition: Dehydroxylation vs. steaming Roy, P.; Prins, R.; Pirngruber, G. Applied Catalysis B: Environmental, Vol. 80, Issue 3-4 https://doi.org/10.1016/j.apcatb.2007.10.015	journal	May 2008
Oxidative dehydrogenation of propane to propylene with carbon dioxide Atanga, Marktus A.; Rezaei, Fateme; Jawad, Abbas Applied Catalysis B: Environmental, Vol. 220 https://doi.org/10.1016/j.apcatb.2017.08.052	journal	January 2018
Molecular structure and sour gas surface chemistry of supported K2O/WO3/Al2O3 catalysts Zhu, Minghui; Li, Bin; Jehng, Jih-Mirn Applied Catalysis B: Environmental, Vol. 232 https://doi.org/10.1016/j.apcatb.2018.03.044	journal	September 2018
Nanoflake-assembled Al2O3-supported CeO2-ZrO2 as an efficient catalyst for oxidative dehydrogenation of ethylbenzene with CO2 Wang, Tehua; Guan, Xiaolin; Lu, Huiyi Applied Surface Science, Vol. 398 https://doi.org/10.1016/j.apsusc.2016.11.180	journal	March 2017
Understanding the effects of metal particle size on the NO2 reduction from a DFT study Pascucci, B. M.; Otero, G. S.; Belelli, P. G. Applied Surface Science, Vol. 489 https://doi.org/10.1016/j.apsusc.2019.05.318	journal	September 2019
Mesoporous silica-supported chromium catalyst: Characterization and excellent performance in dehydrogenation of propane to propylene with carbon dioxide Liu, Licheng; Li, Huiquan; Zhang, Yi Catalysis Communications, Vol. 8, Issue 3 https://doi.org/10.1016/j.catcom.2006.08.005	journal	March 2007
Dehydrogenation of ethylbenzene and propane over Ga2O3–ZrO2 catalysts in the presence of CO2 Li, Huiyun; Yue, Yinghong; Miao, Changxi Catalysis Communications, Vol. 8, Issue 9 https://doi.org/10.1016/j.catcom.2006.11.034	journal	September 2007
Sucrose-templated mesoporous β-Ga2O3 as a novel efficient catalyst for dehydrogenation of propane in the presence of CO2 Wu, Jia-Ling; Chen, Miao; Liu, Yong-Mei Catalysis Communications, Vol. 30 https://doi.org/10.1016/j.catcom.2012.11.004	journal	January 2013
Ordered mesoporous Ga2O3 and Ga2O3–Al2O3 prepared by nanocasting as effective catalysts for propane dehydrogenation in the presence of CO2 Michorczyk, Piotr; Kuśtrowski, Piotr; Kolak, Agnieszka Catalysis Communications, Vol. 35 https://doi.org/10.1016/j.catcom.2013.01.019	journal	May 2013
Hydrothermally prepared Cr2O3–ZrO2 as a novel efficient catalyst for dehydrogenation of propane with CO2 Wu, Runxia; Xie, Pengfei; Cheng, Yanhu Catalysis Communications, Vol. 39 https://doi.org/10.1016/j.catcom.2013.05.002	journal	September 2013
Effect of sulfate addition on the performance of Co/Al2O3 catalysts in catalytic dehydrogenation of propane Sun, Ya-nan; Gao, Ya-nan; Wu, Yimin Catalysis Communications, Vol. 60 https://doi.org/10.1016/j.catcom.2014.11.024	journal	February 2015
Modification of active catalytic sites with N2O and CO2 as gas promoters during oxidation reactions Demoulin, O.; Dury, F.; Navez, M. Catalysis Today, Vol. 91-92 https://doi.org/10.1016/j.cattod.2004.03.005	journal	July 2004
Modulation of selective sites by introduction of N2O, CO2 and H2 as gaseous promoters into the feed during oxidation reactions Demoulin, O.; Seunier, I.; Dury, F. Catalysis Today, Vol. 99, Issue 1-2 https://doi.org/10.1016/j.cattod.2004.09.043	journal	January 2005
Oxidative dehydrogenation of propane over differently structured vanadia-based catalysts in the presence of O2 and N2O Kondratenko, E. V.; Cherian, M.; Baerns, M. Catalysis Today, Vol. 112, Issue 1-4 https://doi.org/10.1016/j.cattod.2005.11.028	journal	March 2006
Oxidative dehydrogenation of ethane and propane: How far from commercial implementation? Cavani, F.; Ballarini, N.; Cericola, A. Catalysis Today, Vol. 127, Issue 1-4, p. 113-131 https://doi.org/10.1016/j.cattod.2007.05.009	journal	September 2007
Similarity and differences in the oxidative dehydrogenation of C2–C4 alkanes over nano-sized VOx species using N2O and O2 Ovsitser, Olga; Kondratenko, Evgenii V. Catalysis Today, Vol. 142, Issue 3-4 https://doi.org/10.1016/j.cattod.2008.09.012	journal	April 2009
Combination of CO2 reforming and partial oxidation of methane to produce syngas over Ni/SiO2 prepared with nickel citrate precursor He, Sufang; Jing, Qiangshan; Yu, Wanjin Catalysis Today, Vol. 148, Issue 1-2 https://doi.org/10.1016/j.cattod.2009.03.009	journal	October 2009
ZnO supported on high silica HZSM-5 as new catalysts for dehydrogenation of propane to propene in the presence of CO2 Ren, Yingjie; Zhang, Fan; Hua, Weiming Catalysis Today, Vol. 148, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.05.011	journal	November 2009
Role of CO2 in dehydrogenation of propane over Cr-based catalysts Shishido, Tetsuya; Shimamura, Kenichi; Teramura, Kentaro Catalysis Today, Vol. 185, Issue 1 https://doi.org/10.1016/j.cattod.2011.10.028	journal	May 2012
Oxidative dehydrogenation of propane over alumina supported vanadia catalyst – Effect of carbon dioxide and secondary surface metal oxide additive Sandupatla, Aditya Shankar; Ray, Koustuv; Thaosen, Prokel Catalysis Today, Vol. 354 https://doi.org/10.1016/j.cattod.2019.06.047	journal	September 2020
CrO /SiO2 catalysts prepared by metal vapour synthesis: Physical–chemical characterisation and functional testing in oxidative dehydrogenation of propane Botavina, M. A.; Evangelisti, C.; Agafonov, Yu. A. Chemical Engineering Journal, Vol. 166, Issue 3 https://doi.org/10.1016/j.cej.2010.11.070	journal	February 2011
Effect of sulfation on the performance of Fe2O3/Al2O3 catalyst in catalytic dehydrogenation of propane to propylene Sun, Ya-nan; Tao, Lei; You, Tingzheng Chemical Engineering Journal, Vol. 244 https://doi.org/10.1016/j.cej.2014.01.047	journal	May 2014
Chemical looping oxidative dehydrogenation of propane: A comparative study of Ga-based, Mo-based, V-based oxygen carriers Wu, Tianwei; Yu, Qingbo; Roghair, Ivo Chemical Engineering and Processing - Process Intensification, Vol. 157 https://doi.org/10.1016/j.cep.2020.108137	journal	November 2020
N 2 O -mediated propane oxidative dehydrogenation over Fe-zeolites. TEOM studies for continuous propylene production in a cyclically-operated reactor Pérez-Ramírez, J.; Gallardo-Llamas, A.; Daniel, C. Chemical Engineering Science, Vol. 59, Issue 22-23 https://doi.org/10.1016/j.ces.2004.07.035	journal	November 2004
Ethylbenzene dehydrogenation to styrene with CO 2 over V 2 O 5 (001): A periodic density functional theory study Fan, Hongxia; Feng, Jie; Li, Xiaohong Chemical Engineering Science, Vol. 135 https://doi.org/10.1016/j.ces.2015.01.068	journal	October 2015
N2O-mediated propane oxidative dehydrogenation over steam-activated iron zeolites Perezramirez, J. Journal of Catalysis, Vol. 223, Issue 2 https://doi.org/10.1016/j.jcat.2004.02.005	journal	April 2004
Vanadium oxide supported on mesoporous SBA-15 as highly selective catalysts in the oxidative dehydrogenation of propane Liu, Yong-Mei; Cao, Yong; Yi, Nan Journal of Catalysis, Vol. 224, Issue 2 https://doi.org/10.1016/j.jcat.2004.03.010	journal	June 2004
Behavior of active sites on Cr-MCM-41 catalysts during the dehydrogenation of propane with CO2 Takehira, Katsuomi; Ohishi, Yoshihiko; Shishido, Tetsuya Journal of Catalysis, Vol. 224, Issue 2 https://doi.org/10.1016/j.jcat.2004.03.014	journal	June 2004
Active iron sites associated with the reaction mechanism of N2O conversions over steam-activated FeMFI zeolites Pérez-Ramírez, Javier Journal of Catalysis, Vol. 227, Issue 2 https://doi.org/10.1016/j.jcat.2004.08.005	journal	October 2004
Dehydrogenation of propane to propene over different polymorphs of gallium oxide Zheng, B.; Hua, W.; Yue, Y. Journal of Catalysis, Vol. 232, Issue 1 https://doi.org/10.1016/j.jcat.2005.03.001	journal	May 2005
Oxidative dehydrogenation of propane over V/MCM-41 catalysts: comparison of O2 and N2O as oxidants Kondratenko, E.; Cherian, M.; Baerns, M. Journal of Catalysis, Vol. 234, Issue 1 https://doi.org/10.1016/j.jcat.2005.05.025	journal	August 2005
Support effect in dehydrogenation of propane in the presence of CO2 over supported gallium oxide catalysts Xu, B.; Zheng, B.; Hua, W. Journal of Catalysis, Vol. 239, Issue 2 https://doi.org/10.1016/j.jcat.2006.02.017	journal	April 2006
Promotion of the propane ODH reaction over supported V2O5/Al2O3 catalyst with secondary surface metal oxide additives Mitra, Brishti; Wachs, Israel E.; Deo, Goutam Journal of Catalysis, Vol. 240, Issue 2 https://doi.org/10.1016/j.jcat.2006.03.015	journal	June 2006
Deactivation and regeneration of iron-containing MFI zeolites in propane oxidative dehydrogenation by N2O Sanchezgalofre, O.; Segura, Y.; Perezramirez, J. Journal of Catalysis, Vol. 249, Issue 2 https://doi.org/10.1016/j.jcat.2007.04.010	journal	July 2007
V2O5–SiO2 systems prepared by flame pyrolysis as catalysts for the oxidative dehydrogenation of propane Rossetti, I.; Fabbrini, L.; Ballarini, N. Journal of Catalysis, Vol. 256, Issue 1 https://doi.org/10.1016/j.jcat.2008.02.028	journal	May 2008
Oxidative dehydrogenation of propane: Differences between N2O and O2 in the reoxidation of reduced vanadia sites and consequences for selectivity Rozanska, X.; Kondratenko, E.; Sauer, J. Journal of Catalysis, Vol. 256, Issue 1 https://doi.org/10.1016/j.jcat.2008.03.002	journal	May 2008
Dehydrogenation of propane over spinel-type gallia–alumina solid solution catalysts Chen, M.; Xu, J.; Su, F. Journal of Catalysis, Vol. 256, Issue 2 https://doi.org/10.1016/j.jcat.2008.03.021	journal	June 2008
FAPO and Fe-TUD-1: Promising catalysts for N2O mediated selective oxidation of propane? Wei, Wei; Moulijn, Jacob A.; Mul, Guido Journal of Catalysis, Vol. 262, Issue 1 https://doi.org/10.1016/j.jcat.2008.11.015	journal	February 2009
Palladium nanoparticles supported on polyvinylpyridine: Catalytic activity in Heck-type reactions and XPS structural studies Evangelisti, Claudio; Panziera, Nicoletta; Pertici, Paolo Journal of Catalysis, Vol. 262, Issue 2 https://doi.org/10.1016/j.jcat.2009.01.005	journal	March 2009
Solvated gold atoms in the preparation of efficient supported catalysts: Correlation between morphological features and catalytic activity in the hydrosilylation of 1-hexyne Aronica, Laura Antonella; Schiavi, Eleonora; Evangelisti, Claudio Journal of Catalysis, Vol. 266, Issue 2 https://doi.org/10.1016/j.jcat.2009.06.012	journal	September 2009
On the nature and reactivity of active oxygen species formed from O2 and N2O on VOx/MCM-41 used for oxidative dehydrogenation of propane Kondratenko, E. V.; Brückner, A. Journal of Catalysis, Vol. 274, Issue 1 https://doi.org/10.1016/j.jcat.2010.06.010	journal	August 2010
A new view on the relations between tungsten and vanadium in V2O5WO3/TiO2 catalysts for the selective reduction of NO with NH3 Kompio, Patrick G. W. A.; Brückner, Angelika; Hipler, Frank Journal of Catalysis, Vol. 286 https://doi.org/10.1016/j.jcat.2011.11.008	journal	February 2012
Reaction path analysis of propane selective oxidation over V2O5 and V2O5/TiO2 Alexopoulos, Konstantinos; Reyniers, Marie-Françoise; Marin, Guy B. Journal of Catalysis, Vol. 289 https://doi.org/10.1016/j.jcat.2012.01.019	journal	May 2012
Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition Sazama, Petr; Sathu, Naveen K.; Tabor, Edyta Journal of Catalysis, Vol. 299 https://doi.org/10.1016/j.jcat.2012.12.010	journal	March 2013
Structure sensitivity of the oxidative activation of methane over MgO model catalysts: II. Nature of active sites and reaction mechanism Schwach, Pierre; Hamilton, Neil; Eichelbaum, Maik Journal of Catalysis, Vol. 329 https://doi.org/10.1016/j.jcat.2015.05.008	journal	September 2015
The role of CO2 in the dehydrogenation of propane over WO –VO /SiO2 Ascoop, Isabelle; Galvita, Vladimir V.; Alexopoulos, Konstantinos Journal of Catalysis, Vol. 335 https://doi.org/10.1016/j.jcat.2015.12.015	journal	March 2016
Propane-to-propene oxide oxidation on silica-supported vanadium catalysts with N2O as an oxidant Held, A.; Kowalska-Kuś, J.; Nowińska, K. Journal of Catalysis, Vol. 336 https://doi.org/10.1016/j.jcat.2015.12.028	journal	April 2016
Reactions of propane with CO2 over Au catalysts Tóth, Anita; Halasi, Gyula; Bánsági, Tamás Journal of Catalysis, Vol. 337 https://doi.org/10.1016/j.jcat.2016.01.029	journal	May 2016
Reforming and oxidative dehydrogenation of ethane with CO2 as a soft oxidant over bimetallic catalysts Myint, MyatNoeZin; Yan, Binhang; Wan, Jie Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2016.02.004	journal	November 2016
Effects of oxygen coverage on rates and selectivity of propane-CO2 reactions on molybdenum carbide Sullivan, Mark M.; Bhan, Aditya Journal of Catalysis, Vol. 357 https://doi.org/10.1016/j.jcat.2017.11.004	journal	January 2018
Dioxygen activation routes in Mars-van Krevelen redox cycles catalyzed by metal oxides Kwon, Stephanie; Deshlahra, Prashant; Iglesia, Enrique Journal of Catalysis, Vol. 364 https://doi.org/10.1016/j.jcat.2018.05.016	journal	August 2018
Facile in situ synthesis of highly dispersed chromium oxide incorporated into mesoporous ZrO2 for the dehydrogenation of propane with CO2 Xie, Zean; Ren, Yu; Li, Jianmei Journal of Catalysis, Vol. 372 https://doi.org/10.1016/j.jcat.2019.02.026	journal	April 2019
Effect of dealumination on the catalytic performance of Cr-containing Beta zeolite in carbon dioxide assisted propane dehydrogenation Michorczyk, Piotr; Zeńczak-Tomera, Kamila; Michorczyk, Barbara Journal of CO2 Utilization, Vol. 36 https://doi.org/10.1016/j.jcou.2019.09.018	journal	February 2020
Reverse water gas shift reaction and CO2 mitigation: nanocrystalline MgO as a support for nickel based catalysts Ranjbar, Atieh; Irankhah, Abdullah; Aghamiri, Seyed Foad Journal of Environmental Chemical Engineering, Vol. 6, Issue 4 https://doi.org/10.1016/j.jece.2018.07.032	journal	August 2018
Synthesis of mesoporous β-Ga2O3 nanorods using PEG as template: Preparation, characterization and photocatalytic properties Zhao, Weirong; Yang, Yong; Hao, Rui Journal of Hazardous Materials, Vol. 192, Issue 3 https://doi.org/10.1016/j.jhazmat.2011.06.073	journal	September 2011
Ga2O3/HZSM-48 for dehydrogenation of propane: Effect of acidity and pore geometry of support Ren, Yingjie; Wang, Jie; Hua, Weiming Journal of Industrial and Engineering Chemistry, Vol. 18, Issue 2 https://doi.org/10.1016/j.jiec.2011.11.134	journal	March 2012
High-performance catalytic perovskite hollow fiber membrane reactor for oxidative propane dehydrogenation Wang, Zhigang; Bian, Zhoufeng; Dewangan, Nikita Journal of Membrane Science, Vol. 578 https://doi.org/10.1016/j.memsci.2019.02.012	journal	May 2019
Preparation and characterization of SBA-1–supported chromium oxide catalysts for CO2 assisted dehydrogenation of propane Michorczyk, Piotr; Pietrzyk, Piotr; Ogonowski, Jan Microporous and Mesoporous Materials, Vol. 161 https://doi.org/10.1016/j.micromeso.2012.05.011	journal	October 2012
Oxidative dehydrogenation of propane with nitrous oxide over Fe–O–Al species occluded in ZSM-5: Reaction and deactivation mechanisms Wu, Guangjun; Hao, Yao; Zhang, Nan Microporous and Mesoporous Materials, Vol. 198 https://doi.org/10.1016/j.micromeso.2014.07.032	journal	November 2014
Cr doped mesoporous silica spheres for propane dehydrogenation in the presence of CO2: Effect of Cr adding time in sol-gel process Wang, Hao-Miao; Chen, Yan; Yan, Xi Microporous and Mesoporous Materials, Vol. 284 https://doi.org/10.1016/j.micromeso.2019.04.016	journal	August 2019
Dehydrogenation of ethylbenzene with CO2 over Cr-MCM-41 catalyst Ohishi, Yoshihiko; Kawabata, Tomonori; Shishido, Tetsuya Journal of Molecular Catalysis A: Chemical, Vol. 230, Issue 1-2 https://doi.org/10.1016/j.molcata.2004.12.006	journal	April 2005
A DFT study on the behavior of NO2 in the selective catalytic reduction of nitric oxides with ammonia on a V2O5 catalyst surface Gao, Xiang; Du, Xue-sen; Jiang, Ye Journal of Molecular Catalysis A: Chemical, Vol. 317, Issue 1-2 https://doi.org/10.1016/j.molcata.2009.10.020	journal	February 2010
Activity of chromium oxide deposited on different silica supports in the dehydrogenation of propane with CO2 – A comparative study Michorczyk, Piotr; Ogonowski, Jan; Zeńczak, Kamila Journal of Molecular Catalysis A: Chemical, Vol. 349, Issue 1-2 https://doi.org/10.1016/j.molcata.2011.08.019	journal	October 2011
Effect of pre-reduction on the performance of Fe2O3/Al2O3 catalysts in dehydrogenation of propane Sun, Yanan; Wu, Yimin; Tao, Lei Journal of Molecular Catalysis A: Chemical, Vol. 397 https://doi.org/10.1016/j.molcata.2014.11.011	journal	February 2015
TG study on real role of active carbon support in propane dehydrogenation with CO2 Kuśtrowski, Piotr; Michorczyk, Piotr; Chmielarz, Lucjan Thermochimica Acta, Vol. 471, Issue 1-2 https://doi.org/10.1016/j.tca.2008.02.017	journal	May 2008
Halogen-Mediated Conversion of Hydrocarbons to Commodities Lin, Ronghe; Amrute, Amol P.; Pérez-Ramírez, Javier Chemical Reviews, Vol. 117, Issue 5 https://doi.org/10.1021/acs.chemrev.6b00551	journal	February 2017
Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes Shah, Mansi S.; Tsapatsis, Michael; Siepmann, J. Ilja Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.7b00095	journal	May 2017
Small-Pore Zeolites: Synthesis and Catalysis Dusselier, Michiel; Davis, Mark E. Chemical Reviews, Vol. 118, Issue 11 https://doi.org/10.1021/acs.chemrev.7b00738	journal	May 2018
Theoretical Investigation of Methane Hydroxylation over Isoelectronic [FeO] ²⁺ - and [MnO] ⁺ -Exchanged Zeolites Activated by N ₂ O Mahyuddin, M. Haris; Shiota, Yoshihito; Staykov, Aleksandar Inorganic Chemistry, Vol. 56, Issue 17 https://doi.org/10.1021/acs.inorgchem.7b01284	journal	August 2017
Mechanistic Study of Nitric Oxide Reduction by Hydrogen on Pt(100) (I): A DFT Analysis of the Reaction Network Bai, Yunhai; Mavrikakis, Manos The Journal of Physical Chemistry B, Vol. 122, Issue 2 https://doi.org/10.1021/acs.jpcb.7b01115	journal	May 2017
Reactions of Molten LiI with I ₂ , H ₂ O, and O ₂ Relevant to Halogen-Mediated Oxidative Dehydrogenation of Alkanes Huang, Chang; Kristoffersen, Henrik H.; Gong, Xue-Qing The Journal of Physical Chemistry C, Vol. 120, Issue 9 https://doi.org/10.1021/acs.jpcc.5b12336	journal	February 2016
Adsorption of CO ₂ and Facile Carbonate Formation on BaZrO ₃ Surfaces Polfus, Jonathan M.; Yildiz, Bilge; Tuller, Harry L. The Journal of Physical Chemistry C, Vol. 122, Issue 1 https://doi.org/10.1021/acs.jpcc.7b08223	journal	December 2017
Oxygen Activation in Oxidative Coupling of Methane on Calcium Oxide Thum, Lukas; Rudolph, Maik; Schomäcker, Reinhard The Journal of Physical Chemistry C, Vol. 123, Issue 13 https://doi.org/10.1021/acs.jpcc.8b07391	journal	October 2018
Understanding Catalytic Mechanisms of Alkane Oxychlorination from the Perspective of Energy Levels Zhang, Hua-Min; Fan, Qi-Yuan; Zhang, Qing-Hong The Journal of Physical Chemistry C, Vol. 124, Issue 11 https://doi.org/10.1021/acs.jpcc.9b10464	journal	March 2020
Operando Photoelectron Photoion Coincidence Spectroscopy Unravels Mechanistic Fingerprints of Propane Activation by Catalytic Oxyhalogenation Zichittella, Guido; Hemberger, Patrick; Holzmeier, Fabian The Journal of Physical Chemistry Letters, Vol. 11, Issue 3 https://doi.org/10.1021/acs.jpclett.9b03836	journal	January 2020
Dispersed Vanadium in Three-Dimensional Dendritic Mesoporous Silica Nanospheres: Active and Stable Catalysts for the Oxidative Dehydrogenation of Propane in the Presence of CO ₂ Xue, Xu-Liang; Lang, Wan-Zhong; Yan, Xi ACS Applied Materials & Interfaces, Vol. 9, Issue 18 https://doi.org/10.1021/acsami.7b01498	journal	April 2017
Nanoporous Zeolite-A Sheltered Pd-Hollow Fiber Catalytic Membrane Reactor for Propane Dehydrogenation Pati, Subhasis; Dewangan, Nikita; Wang, Zhigang ACS Applied Nano Materials, Vol. 3, Issue 7 https://doi.org/10.1021/acsanm.0c01131	journal	June 2020
Role Of CO ₂ As a Soft Oxidant For Dehydrogenation of Ethylbenzene to Styrene over a High-Surface-Area Ceria Catalyst Zhang, Li; Wu, Zili; Nelson, Nicholas C. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01519	journal	October 2015
Enhanced Two-Dimensional Dispersion of Group V Metal Oxides on Silica Grant, Joseph T.; Carrero, Carlos A.; Love, Alyssa M. ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b01679	journal	September 2015
Nature of the Active Sites of VO _x /Al ₂ O ₃ Catalysts for Propane Dehydrogenation Liu, Gang; Zhao, Zhi-Jian; Wu, Tengfang ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b00893	journal	July 2016
Dry Reforming of Ethane and Butane with CO ₂ over PtNi/CeO ₂ Bimetallic Catalysts Yan, Binhang; Yang, Xiaofang; Yao, Siyu ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b02176	journal	September 2016
Elucidating the Role of CO ₂ in the Soft Oxidative Dehydrogenation of Propane over Ceria-Based Catalysts Nowicka, Ewa; Reece, Christian; Althahban, Sultan M. ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03805	journal	March 2018
Oxidative Dehydrogenation of Propane to Propylene in the Presence of HCl Catalyzed by CeO ₂ and NiO-Modified CeO ₂ Nanocrystals Xie, Quanhua; Zhang, Huamin; Kang, Jincan ACS Catalysis, Vol. 8, Issue 6 https://doi.org/10.1021/acscatal.8b00650	journal	April 2018
Dry Reforming of Methane on Single-Site Ni/MgO Catalysts: Importance of Site Confinement Zuo, Zhijun; Liu, Shizhong; Wang, Zichun ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b02277	journal	September 2018
Quantum Chemical Characterization of Structural Single Fe(II) Sites in MIL-Type Metal–Organic Frameworks for the Oxidation of Methane to Methanol and Ethane to Ethanol Vitillo, Jenny G.; Bhan, Aditya; Cramer, Christopher J. ACS Catalysis, Vol. 9, Issue 4 https://doi.org/10.1021/acscatal.8b04813	journal	January 2019
Selective Propylene Production via Propane Oxychlorination on Metal Phosphate Catalysts Zichittella, Guido; Stähelin, Samuel; Goedicke, Florian M. ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b01315	journal	May 2019
Supported Boron Oxide Catalysts for Selective and Low-Temperature Oxidative Dehydrogenation of Propane Lu, Wen-Duo; Wang, Dongqi; Zhao, Zhenchao ACS Catalysis, Vol. 9, Issue 9 https://doi.org/10.1021/acscatal.9b02284	journal	July 2019
Inhibitor, Co-Catalyst, or Co-Reactant? Probing the Different Roles of H ₂ S during CO ₂ Hydrogenation on the MoS ₂ Catalyst Sharma, Lohit; Upadhyay, Ronak; Rangarajan, Srinivas ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b02986	journal	September 2019
Selective C–H Bond Activation via NO _x -Mediated Generation of Strong H-Abstractors Annamalai, Leelavathi; Liu, Yilang; Deshlahra, Prashant ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b03862	journal	September 2019
Computational Predictions and Experimental Validation of Alkane Oxidative Dehydrogenation by Fe ₂ M MOF Nodes Barona, Melissa; Ahn, Sol; Morris, William ACS Catalysis, Vol. 10, Issue 2 https://doi.org/10.1021/acscatal.9b03932	journal	December 2019
Pore Size Engineering and Mechanical Stability of the Cubic Mesoporous Molecular Sieve SBA-1 Vinu, A.; Murugesan, V.; Hartmann, Martin Chemistry of Materials, Vol. 15, Issue 6 https://doi.org/10.1021/cm0213523	journal	March 2003
Nanocasting of High Surface Area Mesoporous Ga ₂ O ₃ and GaN Semiconductor Materials West, Colin; Mokaya, Robert Chemistry of Materials, Vol. 21, Issue 17 https://doi.org/10.1021/cm902015f	journal	August 2009
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides Sattler, Jesper J. H. B.; Ruiz-Martinez, Javier; Santillan-Jimenez, Eduardo Chemical Reviews, Vol. 114, Issue 20 https://doi.org/10.1021/cr5002436	journal	August 2014
Preparation of Highly Dispersed Chromium Oxide Catalysts Supported on Mesoporous Silica for the Oxidative Dehydrogenation of Propane Using CO ₂ : Insight into the Nature of Catalytically Active Chromium Sites Baek, Jayeon; Yun, Hyeong Jin; Yun, Danim ACS Catalysis, Vol. 2, Issue 9 https://doi.org/10.1021/cs300198u	journal	August 2012
Oxidative Dehydrogenation of Cyclohexane on Cobalt Oxide (Co ₃ O ₄ ) Nanoparticles: The Effect of Particle Size on Activity and Selectivity Tyo, Eric C.; Yin, Chunrong; Di Vece, Marcel ACS Catalysis, Vol. 2, Issue 11 https://doi.org/10.1021/cs300479a	journal	September 2012
Promoting Effect of Sulfur Addition on the Catalytic Performance of Ni/MgAl ₂ O ₄ Catalysts for Isobutane Dehydrogenation Wang, Guowei; Meng, Zhe; Liu, Jianwei ACS Catalysis, Vol. 3, Issue 12 https://doi.org/10.1021/cs400705p	journal	November 2013
Highly Efficient Metal Sulfide Catalysts for Selective Dehydrogenation of Isobutane to Isobutene Wang, Guowei; Li, Chunyi; Shan, Honghong ACS Catalysis, Vol. 4, Issue 4 https://doi.org/10.1021/cs5000944	journal	March 2014
Critical Literature Review of the Kinetics for the Oxidative Dehydrogenation of Propane over Well-Defined Supported Vanadium Oxide Catalysts Carrero, C. A.; Schloegl, R.; Wachs, I. E. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5003417	journal	September 2014
Catalytic Conversion of Alkanes to Olefins by Carbon Dioxide Oxidative DehydrogenationA Review Wang, Shaobin; Zhu, Z. H. Energy & Fuels, Vol. 18, Issue 4 https://doi.org/10.1021/ef0340716	journal	July 2004
Experimental Investigation of Initial Coke Formation over Stainless Steel, Chromium, and Iron in Thermal Cracking of Ethane with Hydrogen Sulfide as an Additive Jazayeri, Seyed Mahdi; Karimzadeh, Ramin Energy & Fuels, Vol. 25, Issue 10 https://doi.org/10.1021/ef2005173	journal	October 2011
Hydraulic Fracturing Additives and the Delayed Onset of Hydrogen Sulfide in Shale Gas Pirzadeh, Payman; Lesage, Kevin L.; Marriott, Robert A. Energy & Fuels, Vol. 28, Issue 8 https://doi.org/10.1021/ef501059k	journal	July 2014
Oxidation of Hydrocarbons and Alcohols by Carbon Dioxide on Oxide Catalysts Krylov, O. V.; Mamedov, A. Kh.; Mirzabekova, S. R. Industrial & Engineering Chemistry Research, Vol. 34, Issue 2 https://doi.org/10.1021/ie00041a007	journal	February 1995
Influence of Metal Surface and Sulfur Addition on Coke Deposition in the Thermal Cracking of Hydrocarbons Reyniers, Marie-Francoise S. G.; Froment, Gilbert F. Industrial & Engineering Chemistry Research, Vol. 34, Issue 3 https://doi.org/10.1021/ie00042a009	journal	March 1995
Cyclic Process for Propylene Production via Oxidative Dehydrogenation of Propane with N ₂ O over FeZSM-5 Gallardo-Llamas, Amalia; Mirodatos, Claude; Pérez-Ramírez, Javier Industrial & Engineering Chemistry Research, Vol. 44, Issue 3 https://doi.org/10.1021/ie0493863	journal	December 2004
Influence of Dimethyl Disulfide on Coke Formation during Steam Cracking of Hydrocarbons Wang, Jidong; Reyniers, Marie-Françoise; Marin, Guy B. Industrial & Engineering Chemistry Research, Vol. 46, Issue 12 https://doi.org/10.1021/ie061096u	journal	January 2007
Structural determination of supported vanadium pentoxide-tungsten trioxide-titania catalysts by in situ Raman spectroscopy and x-ray photoelectron spectroscopy Vuurman, Michael A.; Wachs, Israel E.; Hirt, Andrew M. The Journal of Physical Chemistry, Vol. 95, Issue 24 https://doi.org/10.1021/j100177a059	journal	November 1991
Metal vapor synthesis of a novel triple-decker sandwich complex: (.eta.6-mesitylene)2(.mu.-.eta.6:.eta.6-mesitylene)Cr2 Lamanna, William M. Journal of the American Chemical Society, Vol. 108, Issue 8 https://doi.org/10.1021/ja00268a063	journal	April 1986
Periodic Density Functional Theory Study of Propane Oxidative Dehydrogenation over V ₂ O ₅ (001) Surface Fu, Hui; Liu, Zhi-Pan; Li, Zhen-Hua Journal of the American Chemical Society, Vol. 128, Issue 34 https://doi.org/10.1021/ja0611745	journal	August 2006
Ordered Mesoporous Ce ₁ _- _x Zr _x O ₂ Solid Solutions with Crystalline Walls Yuan, Quan; Liu, Qiang; Song, Wei-Guo Journal of the American Chemical Society, Vol. 129, Issue 21 https://doi.org/10.1021/ja070908q	journal	May 2007
Reverse Water–Gas Shift or Sabatier Methanation on Ni(110)? Stable Surface Species at Near-Ambient Pressure Roiaz, Matteo; Monachino, Enrico; Dri, Carlo Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.5b13366	journal	March 2016
Tandem Reactions of CO ₂ Reduction and Ethane Aromatization Gomez, Elaine; Nie, Xiaowa; Lee, Ji Hoon Journal of the American Chemical Society, Vol. 141, Issue 44 https://doi.org/10.1021/jacs.9b08538	journal	October 2019
The Role of Chemisorbed Oxygen on Diamond Surfaces for the Dehydrogenation of Ethane in the Presence of Carbon Dioxide Nakagawa, Kiyoharu; Kajita, Chiaki; Ikenaga, Na-oki The Journal of Physical Chemistry B, Vol. 107, Issue 17 https://doi.org/10.1021/jp022173b	journal	April 2003
Framework Composition Effects on the Performance of Steam-Activated FeMFI Zeolites in the N ₂ O-Mediated Propane Oxidative Dehydrogenation to Propylene Pérez-Ramírez, Javier; Gallardo-Llamas, Amalia The Journal of Physical Chemistry B, Vol. 109, Issue 43 https://doi.org/10.1021/jp054447b	journal	October 2005
Mechanism and Kinetics of Direct N ₂ O Decomposition over Fe−MFI Zeolites with Different Iron Speciation from Temporal Analysis of Products Kondratenko, Evgenii V.; Pérez-Ramírez, Javier The Journal of Physical Chemistry B, Vol. 110, Issue 45 https://doi.org/10.1021/jp063492w	journal	November 2006
In-Situ UV/vis and Transient Isotopic Analysis of the Role of Oxidizing Agent in the Oxidative Dehydrogenation of Propane over Silica-Supported Vanadia Catalysts Ovsitser, Olga; Cherian, Maymol; Kondratenko, Evgenii V. The Journal of Physical Chemistry C, Vol. 111, Issue 24 https://doi.org/10.1021/jp070747c	journal	June 2007
Lewis Acido-Basic Interactions between CO ₂ and MgO Surface: DFT and DRIFT Approaches Cornu, Damien; Guesmi, Hazar; Krafft, Jean-Marc The Journal of Physical Chemistry C, Vol. 116, Issue 11 https://doi.org/10.1021/jp211171t	journal	March 2012
Experimental and ab Initio Investigations of H ₂ S-Assisted Propane Oxidative Dehydrogenation Reactions Premji, Zahra A.; Lo, John M. H.; Clark, Peter D. The Journal of Physical Chemistry A, Vol. 118, Issue 9 https://doi.org/10.1021/jp410750c	journal	February 2014
Periodic Density Functional Theory Study of Propane Dehydrogenation over Perfect Ga ₂ O ₃ (100) Surface Liu, Yan; Li, Zhen Hua; Lu, Jing The Journal of Physical Chemistry C, Vol. 112, Issue 51 https://doi.org/10.1021/jp807864z	journal	December 2008
Influence of the Content and Environment of Chromium in CrSiBEA Zeolites on the Oxidative Dehydrogenation of Propane Janas, Janusz; Gurgul, Jacek; Socha, Robert P. The Journal of Physical Chemistry C, Vol. 113, Issue 30 https://doi.org/10.1021/jp809733s	journal	July 2009
Oxygen and Nitrous Oxide as Oxidants: Implications for Ethane Oxidative Dehydrogenation over Silica−Titania-Supported Molybdenum Woods, Matthew P.; Mirkelamoglu, Burcu; Ozkan, Umit S. The Journal of Physical Chemistry C, Vol. 113, Issue 23 https://doi.org/10.1021/jp810664u	journal	May 2009
Mesoporous Gallium Oxide Structurally Stabilized by Yttrium Oxide Yada, Mitsunori; Ohya, Masahumi; Machida, Masato Langmuir, Vol. 16, Issue 10 https://doi.org/10.1021/la991628u	journal	April 2000
Nanostructured ceria-based catalysts for oxydehydrogenation of ethane with CO2 Valenzuela, R. X.; Bueno, G.; Solbes, A. Topics in Catalysis, Vol. 15, Issue 2/4, p. 181-188 https://doi.org/10.1023/A:1016697615043	journal	June 2001
The oxidative dehydrogenation of ethane with CO₂ over Mo₂C/SiO2 catalyst Solymosi, F.; Németh, R. Catalysis Letters, Vol. 62, Issue 2/4, p. 197-200 https://doi.org/10.1023/A:1019027912597	journal	October 1999
Catalytic performance of silica-supported chromium oxide catalysts in ethane dehydrogenation with carbon dioxide Ge, Xin; Zhu, Mingming; Shen, Jianyi Reaction Kinetics and Catalysis Letters, Vol. 77, Issue 1, p. 103-108 https://doi.org/10.1023/A:1020348021042	journal	September 2002
Effects of Pre-Treatment of a Silica-Supported Gallium Oxide Catalyst with H ₂ on Its Catalytic Performance for Dehydrogenation of Propane Takahara, Isao; Saito, Masahiro; Inaba, Megumu Catalysis Letters, Vol. 96, Issue 1/2 https://doi.org/10.1023/B:CATL.0000029525.33197.89	journal	July 2004
Oxidative dehydrogenation of propane by nitrous oxide and/or oxygen over Co beta zeolite Bulánek, Roman; Novoveská, Kateřina Reaction Kinetics and Catalysis Letters, Vol. 80, Issue 2 https://doi.org/10.1023/B:REAC.0000006143.48966.67	journal	January 2003
Influence of redox properties on the activity of iron oxide catalysts in dehydrogenation of propane with CO ₂ Michorczyk, Piotr; Kuśtrowski, Piotr; Chmielarz, Lucjan Reaction Kinetics and Catalysis Letters, Vol. 82, Issue 1 https://doi.org/10.1023/B:REAC.0000028813.14758.ea	journal	January 2004
CH bond activation in the presence or absence of oxygen or nitrous oxide Kaddouri, Abdelhakim Reaction Kinetics and Catalysis Letters, Vol. 82, Issue 2 https://doi.org/10.1023/B:REAC.0000034853.52513.86	journal	January 2004
Sulfur as a selective ‘soft’ oxidant for catalytic methane conversion probed by experiment and theory Zhu, Qingjun; Wegener, Staci L.; Xie, Chao Nature Chemistry, Vol. 5, Issue 2 https://doi.org/10.1038/nchem.1527	journal	December 2012
Catalyst design for natural-gas upgrading through oxybromination chemistry Paunović, Vladimir; Zichittella, Guido; Moser, Maximilian Nature Chemistry, Vol. 8, Issue 8 https://doi.org/10.1038/nchem.2522	journal	May 2016
Understanding trends in C–H bond activation in heterogeneous catalysis Latimer, Allegra A.; Kulkarni, Ambarish R.; Aljama, Hassan Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4760	journal	October 2016
Self-adjusted synthesis of ordered stable mesoporous minerals by acid–base pairs Tian, Bozhi; Liu, Xiaoying; Tu, Bo Nature Materials, Vol. 2, Issue 3, p. 159-163 https://doi.org/10.1038/nmat838	journal	February 2003
Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts Gomez, Elaine; Kattel, Shyam; Yan, Binhang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03793-w	journal	April 2018
Energy-efficient CO2 hydrogenation with fast response using photoexcitation of CO2 adsorbed on metal catalysts Kim, Chanyeon; Hyeon, Seokwon; Lee, Jonghyeok Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05542-5	journal	August 2018
Carbon dioxide reduction in tandem with light-alkane dehydrogenation Gomez, Elaine; Yan, Binhang; Kattel, Shyam Nature Reviews Chemistry, Vol. 3, Issue 11 https://doi.org/10.1038/s41570-019-0128-9	journal	September 2019
Steam-activated FeMFI zeolites as highly efficient catalysts for propane and N ₂ O valorisation via oxidative conversions Pérez-Ramírez, Javier; Kondratenko, Evgueni V. Chem. Commun., Issue 17 https://doi.org/10.1039/B305568J	journal	January 2003
Impact of K and Ba promoters on CO ₂ hydrogenation over Cu/Al ₂ O ₃ catalysts at high pressure Bansode, Atul; Tidona, Bruno; von Rohr, Philipp Rudolf Catal. Sci. Technol., Vol. 3, Issue 3 https://doi.org/10.1039/C2CY20604H	journal	January 2013
Studies on the promoting effect of sulfate species in catalytic dehydrogenation of propane over Fe ₂ O ₃ /Al ₂ O ₃ catalysts Sun, Yanan; Wu, Yimin; Shan, Honghong Catalysis Science & Technology, Vol. 5, Issue 2 https://doi.org/10.1039/C4CY01163E	journal	January 2015
Recent advances in automotive catalysis for NO _x emission control by small-pore microporous materials Beale, A. M.; Gao, F.; Lezcano-Gonzalez, I. Chemical Society Reviews, Vol. 44, Issue 20 https://doi.org/10.1039/C5CS00108K	journal	January 2015
Recent advances of pore system construction in zeolite-catalyzed chemical industry processes Shi, Jing; Wang, Yangdong; Yang, Weimin Chemical Society Reviews, Vol. 44, Issue 24 https://doi.org/10.1039/C5CS00626K	journal	January 2015
Methanation of CO ₂ and reverse water gas shift reactions on Ni/SiO ₂ catalysts: the influence of particle size on selectivity and reaction pathway Wu, H. C.; Chang, Y. C.; Wu, J. H. Catalysis Science & Technology, Vol. 5, Issue 8 https://doi.org/10.1039/C5CY00667H	journal	January 2015
Towards efficient catalysts for the oxidative dehydrogenation of propane in the presence of CO ₂ : Cr/SiO ₂ systems prepared by direct hydrothermal synthesis Botavina, M. A.; Agafonov, Yu. A.; Gaidai, N. A. Catalysis Science & Technology, Vol. 6, Issue 3 https://doi.org/10.1039/C5CY00998G	journal	January 2016
Dehydrogenation of propane over a hydrothermal-synthesized Ga ₂ O ₃ –Al ₂ O ₃ catalyst in the presence of carbon dioxide Xiao, He; Zhang, Junfeng; Wang, Peng Catalysis Science & Technology, Vol. 6, Issue 13 https://doi.org/10.1039/C5CY02161H	journal	January 2016
Catalytic dehydrogenation of propane by carbon dioxide: a medium-temperature thermochemical process for carbon dioxide utilisation Du, X.; Yao, B.; Gonzalez-Cortes, S. Faraday Discussions, Vol. 183 https://doi.org/10.1039/C5FD00062A	journal	January 2015
Mechanistic insights into heterogeneous methane activation Latimer, Allegra A.; Aljama, Hassan; Kakekhani, Arvin Physical Chemistry Chemical Physics, Vol. 19, Issue 5 https://doi.org/10.1039/C6CP08003K	journal	January 2017
Partial oxidation of propane with CO ₂ on Ru doped catalysts Pradhan, Sivaram; Upham, David C.; Metiu, Horia Catalysis Science & Technology, Vol. 6, Issue 14 https://doi.org/10.1039/C6CY00011H	journal	January 2016
Understanding oxidative dehydrogenation of ethane on Co ₃ O ₄ nanorods from density functional theory Fung, Victor; Tao, Franklin (Feng); Jiang, De-en Catalysis Science & Technology, Vol. 6, Issue 18 https://doi.org/10.1039/C6CY00749J	journal	January 2016
Effect of O ₂ , CO ₂ and N ₂ O on Ni–Mo/Al ₂ O ₃ catalyst oxygen mobility in n -butane activation and conversion to 1,3-butadiene Dasireddy, Venkata D. B. C.; Huš, Matej; Likozar, Blaž Catalysis Science & Technology, Vol. 7, Issue 15 https://doi.org/10.1039/C7CY01033H	journal	January 2017
Halogen type as a selectivity switch in catalysed alkane oxyhalogenation Zichittella, Guido; Puértolas, Begoña; Paunović, Vladimir Catalysis Science & Technology, Vol. 8, Issue 8 https://doi.org/10.1039/C8CY00122G	journal	January 2018
Mechanistic study of dry reforming of ethane by CO ₂ on a bimetallic PtNi(111) model surface Kattel, Shyam; Chen, Jingguang G.; Liu, Ping Catalysis Science & Technology, Vol. 8, Issue 15 https://doi.org/10.1039/C8CY00880A	journal	January 2018
The role of H ₂ S addition on Pt/Al ₂ O ₃ catalyzed propane dehydrogenation: a mechanistic study Wang, Hai-Zhi; Zhang, Wei; Jiang, Jia-Wei Catalysis Science & Technology, Vol. 9, Issue 3 https://doi.org/10.1039/C8CY02393J	journal	January 2019
Catalytic halogenation of methane: a dream reaction with practical scope? Paunović, Vladimir; Pérez-Ramírez, Javier Catalysis Science & Technology, Vol. 9, Issue 17 https://doi.org/10.1039/C9CY00625G	journal	January 2019
Ru-Promoted CO ₂ activation for oxidative dehydrogenation of propane over chromium oxide catalyst Jin, Renxi; Easa, Justin; Tran, Dat T. Catalysis Science & Technology, Vol. 10, Issue 6 https://doi.org/10.1039/C9CY01990A	journal	January 2020
Chemical looping beyond combustion – a perspective Zhu, Xing; Imtiaz, Qasim; Donat, Felix Energy & Environmental Science, Vol. 13, Issue 3 https://doi.org/10.1039/C9EE03793D	journal	January 2020
Diamond surface functionalization: from gemstone to photoelectrochemical applications Raymakers, Jorne; Haenen, Ken; Maes, Wouter Journal of Materials Chemistry C, Vol. 7, Issue 33 https://doi.org/10.1039/C9TC03381E	journal	January 2019
Mechanism of selective and complete oxidation in La ₂ O ₃ -catalyzed oxidative coupling of methane Wang, Shibin; Li, Shenggang; Dixon, David A. Catalysis Science & Technology, Vol. 10, Issue 8 https://doi.org/10.1039/D0CY00141D	journal	January 2020
Catalytic performance and stability of Fe-doped CeO ₂ in propane oxidative dehydrogenation using carbon dioxide as an oxidant Wang, Hedun; Tsilomelekis, George Catalysis Science & Technology, Vol. 10, Issue 13 https://doi.org/10.1039/D0CY00586J	journal	January 2020
Oxidative dehydrogenation of propane over transition metal sulfides using sulfur as an alternative oxidant Arinaga, Allison M.; Liu, Shanfu; Marks, Tobin J. Catalysis Science & Technology, Vol. 10, Issue 20 https://doi.org/10.1039/D0CY01039A	journal	January 2020
Catalytic mixed conducting ceramic membrane reactors for methane conversion Wang, Zhigang; Chen, Tianjia; Dewangan, Nikita Reaction Chemistry & Engineering, Vol. 5, Issue 10 https://doi.org/10.1039/D0RE00177E	journal	January 2020
Non-ionic surfactant assembly of wormhole silica molecular sieves from water soluble silicates Kim, Seong-Su; Pauly, Thomas R.; Pinnavaia, Thomas J. Chemical Communications, Issue 10 https://doi.org/10.1039/b001012j	journal	January 2000
Carbon dioxide utilization as a soft oxidant and promoter in catalysis Ansari, Mohd Bismillah; Park, Sang-Eon Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22409g	journal	January 2012
Oxidative dehydrogenation of propane with nitrous oxide over Fe–MFI prepared by ion-exchange: effect of acid post-treatments Wu, Guangjun; Hei, Fei; Guan, Naijia Catalysis Science & Technology, Vol. 3, Issue 5 https://doi.org/10.1039/c3cy20782j	journal	January 2013
Vapour-phase oxidation of diamond surfaces in O2 studied by diffuse reflectance Fourier-transform infrared and temperture-programmed desorption spectroscopy Ando, Toshihiro; Yamamoto, Kazuo; Ishii, Motohiko Journal of the Chemical Society, Faraday Transactions, Vol. 89, Issue 19 https://doi.org/10.1039/ft9938903635	journal	January 1993
Carbon dioxide activation and dissociation on ceria (110): A density functional theory study Cheng, Zhuo; Sherman, Brent J.; Lo, Cynthia S. The Journal of Chemical Physics, Vol. 138, Issue 1, Article No. 014702 https://doi.org/10.1063/1.4773248	journal	January 2013
Active sites for tandem reactions of CO ₂ reduction and ethane dehydrogenation Yan, Binhang; Yao, Siyu; Kattel, Shyam Proceedings of the National Academy of Sciences, Vol. 115, Issue 33 https://doi.org/10.1073/pnas.1806950115	journal	July 2018
Thermodynamic Equilibrium Analysis of Propane Dehydrogenation with Carbon Dioxide and Side Reactions Zangeneh, Farnaz Tahriri; Taeb, Abbas; Gholivand, Khodayar Chemical Engineering Communications, Vol. 203, Issue 4 https://doi.org/10.1080/00986445.2015.1017638	journal	March 2015
Oxidative dehydrogenation of propane to propene in the presence of H ₂ S at short contact times Clark, Peter D.; Dowling, Norman I.; Long, Xiangyun Journal of Sulfur Chemistry, Vol. 25, Issue 6 https://doi.org/10.1080/17415990412331327909	journal	December 2004
Ethylene manufacture by partial oxidation with sulfur Clark, P. D.; Dowling, N. I.; Liu, S. Journal of Sulfur Chemistry, Vol. 31, Issue 6 https://doi.org/10.1080/17415993.2010.527981	journal	December 2010
Selective oxidative dehydrogenation of propane to propene using boron nitride catalysts Grant, J. T.; Carrero, C. A.; Goeltl, F. Science, Vol. 354, Issue 6319 https://doi.org/10.1126/science.aaf7885	journal	December 2016
Propane Dehydrogenation on Chromium Oxide and Gallium Oxide Catalysts in the Presence of CO2 Agafonov, Yu. A.; Gaidai, N. A.; Lapidus, A. L. Kinetics and Catalysis, Vol. 59, Issue 6 https://doi.org/10.1134/S0023158418060010	journal	November 2018
Hydrogen sulfide formation in oil and gas Marriott, Robert A.; Pirzadeh, Payman; Marrugo-Hernandez, Juan J. Canadian Journal of Chemistry, Vol. 94, Issue 4 https://doi.org/10.1139/cjc-2015-0425	journal	April 2016
Active Species of Sulfated Metal Oxide Catalyst for Propane Dehydrogenation Watanabe, Ryo; Hirata, Nozomu; Fukuhara, Choji Journal of the Japan Petroleum Institute, Vol. 60, Issue 5 https://doi.org/10.1627/jpi.60.223	journal	January 2017
Effect of the introduction of alkaline promoters into chromium oxide catalysts for propane dehydrogenation in the presence of CO2 Lapidus, A. L.; Agafonov, Yu. A.; Gaidai, N. A. Solid Fuel Chemistry, Vol. 46, Issue 1 https://doi.org/10.3103/S0361521912010089	journal	February 2012

Similar Records

Comparison of direct and CO₂-oxidative dehydrogenation of propane

Journal Article · Thu Sep 28 20:00:00 EDT 2023 · Trends in Chemistry · OSTI ID:2267553

Combining CO₂ reduction with propane oxidative dehydrogenation over bimetallic catalysts

Journal Article · Tue Apr 10 20:00:00 EDT 2018 · Nature Communications · OSTI ID:1439297

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbon dioxide
nitrous oxide
oxidative dehydrogenation of propane
propane
propylene
soft oxidants
sulfur/halogen-containing compounds

Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis

Citation Formats

References (283)

Similar Records

Related Subjects