skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Techno-economic assessment of renewable methanol from biomass gasification and PEM electrolysis for decarbonization of the maritime sector in California

Journal Article · · Energy Conversion and Management

At scale, biomass-based fuels are seen as long-term alternatives to conventional shipping fuels to reduce greenhouse gas emissions in the maritime sector. While the operational benefits of renewable methanol as a marine fuel are well-known, its cost and environmental performance depend largely on production method and geographic context. In this study, a techno-economic and environmental assessment of renewable methanol produced by gasification of forestry residues is performed. Two biorefinery systems are modeled thermodynamically for the first time, integrating several design changes to extend past work: (1) methanol synthesized by gasification of torrefied biomass while removing and storing underground a fraction of the carbon initially contained in it, and (2) integration of a polymer electrolyte membrane (PEM) electrolyzer for increased carbon efficiency via hydrogen injection into the methanol synthesis process. The chosen use case is set in California, with forest residue biomass as the feedstock and the ports of Los Angeles and Long Beach as the shipping fuel demand point. Methanol produced by both systems achieves substantial lifecycle greenhouse gas emissions savings compared to traditional shipping fuels, ranging from 38 to 165%, from biomass roadside to methanol combustion. Renewable methanol can be carbon-negative if the CO2 captured during the biomass conversion process is sequestered underground with net greenhouse gas emissions along the lifecycle amounting to –57 gCO2eq/MJ. While the produced methanol in both pathways is still more expensive than conventional fossil fuels, the introduction of CO2eq abatement incentives available in the U.S. and California could bring down minimum fuel selling prices substantially. The produced methanol can be competitive with fossil shipping fuels at credit amounts ranging from $$\$$$$150 to $$\$$$$300/tCO2eq, depending on the eligible credits.

Research Organization:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1866014
Alternate ID(s):
OSTI ID: 1883342
Journal Information:
Energy Conversion and Management, Journal Name: Energy Conversion and Management Vol. 257 Journal Issue: C; ISSN 0196-8904
Publisher:
ElsevierCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (43)

Technoeconomic analysis for biofuels and bioproducts journal February 2021
A comparative techno-economic analysis of renewable methanol synthesis from biomass and CO2: Opportunities and barriers to commercialization journal December 2021
Techno-economic and environmental assessments of storing woodchips and pellets for bioenergy applications journal December 2018
Techno-economic analysis of hydrogen enhanced methanol to gasoline process from biomass-derived synthesis gas journal June 2021
Techno‐economic analysis of 1,4‐butanediol production by a single‐step bioconversion process journal April 2019
Volatile species release during torrefaction of biomass and its macromolecular constituents: Part 2 – Modeling study journal August 2014
Thermochemical production of liquid fuels from biomass: Thermo-economic modeling, process design and process integration analysis journal December 2010
Techno-Economic Analysis of Forest Residue Conversion to Sugar Using Three-Stage Milling as Pretreatment journal August 2018
Methanol synthesis reactions: calculations of equilibrium conversions using equations of state journal April 1986
Methanol production via pressurized entrained flow biomass gasification – Techno-economic comparison of integrated vs. stand-alone production journal May 2014
Techno-economic optimization of biomass-to-methanol with solid-oxide electrolyzer journal January 2020
Techno-economic analysis of polygeneration systems based on catalytic hydropyrolysis for the production of bio-oil and fuels journal March 2019
Intrinsic kinetics of isothermal xylan degradation in inert atmosphere journal May 1997
Processing and sorting forest residues: Cost, productivity and managerial impacts journal October 2016
Torrefaction modelling for lignocellulosic biomass conversion processes journal June 2014
Maximizing biofuel production in a thermochemical biorefinery by adding electrolytic hydrogen and by integrating torrefaction with entrained flow gasification journal June 2015
How to decarbonise international shipping: Options for fuels, technologies and policies journal February 2019
Bio-methanol: How energy choices in the western United States can help mitigate global climate change journal January 2009
Electrifying with High-Temperature Water Electrolysis to Produce Syngas from Wood via Oxy-Gasification, Leading to Superior Carbon Conversion Yield for Methanol Synthesis journal March 2021
Biomass torrefaction: Modeling of volatile and solid product evolution kinetics journal November 2012
Chemical Equilibria in Methanol Synthesis Including the Water–Gas Shift Reaction: A Critical Reassessment journal May 2016
Techno-economic assessment of microbial limonene production journal March 2020
Techno-economic assessment of catalytic gasification of biomass powders for methanol production journal August 2017
Drop-in biofuels offer strategies for meeting California’s 2030 climate mandate journal September 2018
Techno-economic analysis of producing solid biofuels and biochar from forest residues using portable systems journal February 2019
Environmental assessment of marine fuels: liquefied natural gas, liquefied biogas, methanol and bio-methanol journal July 2014
Flexible biomass conversion to methanol integrating solid oxide cells and TwoStage gasifier journal July 2020
Renewable methanol as a fuel for the shipping industry journal October 2018
Environmental Impact and Environmental Cost Assessment of Methanol Production from wood biomass journal October 2020
2016 Billion-Ton Report: Advancing Domestic Resources for a Thriving Bioeconomy report July 2016
Prediction of performance of a downdraft gasifier using equilibrium modeling for different biomass materials journal August 2001
Technoeconomic analysis of a low CO2 emission dimethyl ether (DME) plant based on gasification of torrefied biomass journal December 2010
Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water journal May 2010
Comprehensive analysis of environmental impacts and energy consumption of biomass-to-methanol and coal-to-methanol via life cycle assessment journal August 2020
Torrefaction of wood journal August 2006
A Holistic Review on Biomass Gasification Modified Equilibrium Models journal January 2019
Establishing the optimal sizes of different kinds of biorefineries journal January 2007
Biofuel Options for Marine Applications: Technoeconomic and Life-Cycle Analyses journal May 2021
Torrefaction of wood journal August 2006
An engineering-economic model of pipeline transport of CO2 with application to carbon capture and storage journal April 2008
Biomass torrefaction: Modeling of reaction thermochemistry journal April 2013
Techno-economic analysis of methanol production units coupling solid oxide cells and thermochemical biomass conversion via the TwoStage gasifier journal May 2021
Integrated torrefaction vs. external torrefaction – A thermodynamic analysis for the case of a thermochemical biorefinery journal December 2014

Similar Records

Alternative Liquid Fuels Simulation Model (AltSim).
Technical Report · Tue Dec 01 00:00:00 EST 2009 · OSTI ID:1866014

Western Kentucky University Research Foundation Biodiesel Project
Technical Report · Fri Mar 15 00:00:00 EDT 2013 · OSTI ID:1866014

Life cycle greenhouse gas emissions of different CO2 supply options for an algal biorefinery
Journal Article · Sat Jun 20 00:00:00 EDT 2020 · Journal of CO2 Utilization · OSTI ID:1866014