Photothermal Atomic Force Microscopy Coupled with Infrared Spectroscopy (AFM-IR) Analysis of High Extinction Coefficient Materials: A Case Study with Silica and Silicate Glasses

Lin, Yen-Ting; He, Hongtu; Kaya, Huseyin; Liu, Hongshen; Ngo, Dien; Smith, Nicholas J.; Banerjee, Joy; Borhan, Ali; Kim, Seong H.

doi:10.1021/acs.analchem.1c04398

Title: Photothermal Atomic Force Microscopy Coupled with Infrared Spectroscopy (AFM-IR) Analysis of High Extinction Coefficient Materials: A Case Study with Silica and Silicate Glasses

Journal Article · Mon Mar 21 00:00:00 EDT 2022 · Analytical Chemistry

DOI:https://doi.org/10.1021/acs.analchem.1c04398· OSTI ID:1865523

Lin, Yen-Ting ^[1]; He, Hongtu ^[2]; Kaya, Huseyin ^[1]; Liu, Hongshen ^[1];

^[1];

^[3]; Banerjee, Joy ^[3]; Borhan, Ali ^[1];

^[1]

Pennsylvania State Univ., University Park, PA (United States)
Pennsylvania State Univ., University Park, PA (United States); Southwest Univ. of Science and Technology, Sichuan (China)
Corning Incorporated, NY (United States)

Photothermal atomic force microscopy coupled with infrared spectroscopy (AFM-IR) brings significant value as a spatially resolved surface analysis technique for disordered oxide materials such as glasses, but additional development and fundamental understanding of governing principles is needed to interpret AFM-IR spectra, since the existing theory described for organic materials does not work for materials with high extinction coefficients for infrared (IR) absorption. This paper describes theoretical calculation of a transient temperature profile inside the IR-absorbing material considering IR refraction at the interface as well as IR adsorption and heat transfer inside the sample. Furthermore, this calculation explains the differences in peak positions and amplitudes of AFM-IR spectra from those of specular reflectance and extinction coefficient spectra. It also addresses the information depth of the AFM-IR characterization of bulk materials. AFM-IR applied to silica and silicate glass surfaces has demonstrated novel capability of characterizing subsurface structural changes and surface heterogeneity due to mechanical stresses from physical contacts, as well as chemical alterations manifested in surface layers through aqueous corrosion.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: SC0016584; DMR-2011410

OSTI ID:: 1865523

Journal Information:: Analytical Chemistry, Vol. 94, Issue 13; ISSN 0003-2700

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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