Accelerated carbonation and structural transformation of blast furnace slag by mechanochemical alkali-activation

Marple, Maxwell A.T.; Koroglu, Batikan; Morrison, Keith; Crowhurst, Jonathan; Balachandra, Anagi; Soroushian, Parviz; Mason, Harris E.

doi:10.1016/j.cemconres.2022.106760

Title: Accelerated carbonation and structural transformation of blast furnace slag by mechanochemical alkali-activation

Journal Article · Sat Mar 05 00:00:00 EST 2022 · Cement and Concrete Research

DOI:https://doi.org/10.1016/j.cemconres.2022.106760· OSTI ID:1864118

Marple, Maxwell A.T. ^[1]; Koroglu, Batikan ^[1]; Morrison, Keith ^[1]; Crowhurst, Jonathan ^[1]; Balachandra, Anagi ^[2]; Soroushian, Parviz ^[2]; Mason, Harris E. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Metna Corporation, Lansing, MI (United States)

Alternative cements and production routes are necessary to offset the considerable global CO₂ emissions of Portland cement production. The combination of alkali-activation and mechanochemical milling in a CO₂ rich atmosphere is a promising green direction for synthesizing cementitious material as it upcycles hazardous material (slag) while capturing wt% of CO₂ during synthesis. We investigate the resulting structural transformations incurred during synthesis and hydration using a suite of characterization techniques including solid-state ²⁷Al, ²⁹Si, and ¹³C NMR. The local aluminosilicate network structure of the processed clinker is best described by a melilite-type structure. Upon hydration, the network polymerizes to form a calcium, sodium aluminosilicate hydrate gel. The synthesis route also creates various metastable carbonates and bicarbonates from captured CO₂ and alkali-additives that transform into stable carbonate phases like calcite, aragonite, and gaylussite, after hydration. These findings indicate accelerated carbonation reactions occur during clinker production and demonstrates novelty as a green cement technology.

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Research Organization:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344; SC0011960

OSTI ID:: 1864118

Report Number(s):: LLNL-JRNL-811939; 1019022

Journal Information:: Cement and Concrete Research, Vol. 156, Issue na; ISSN 0008-8846

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
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Title: Accelerated carbonation and structural transformation of blast furnace slag by mechanochemical alkali-activation

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