A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers

Yu, Liang; Ullah, Saif; Zhou, Kang; Xia, Qibin; Wang, Hao; Tu, Shi; Huang, Jiajin; Xia, Hai-Lun; Liu, Xiao-Yuan; Thonhauser, Timo; Li, Jing

doi:10.1021/jacs.1c12068

A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers

Journal Article · Thu Jan 27 23:00:00 EST 2022 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.1c12068· OSTI ID:1863575

Yu, Liang ^[1]; ^[2]; Zhou, Kang ^[3]; ^[4]; ^[3]; Tu, Shi ^[4]; Huang, Jiajin ^[4]; Xia, Hai-Lun ^[3]; ^[3]; ^[2]; ^[5]

South China Univ. of Technology, Guangzhou (China); Shenzhen Polytechnic, Guangdong (China); Rutgers University
Wake Forest Univ., Winston-Salem, NC (United States)
Shenzhen Polytechnic, Guangdong (China)
South China Univ. of Technology, Guangzhou (China)
Rutgers Univ., Piscataway, NJ (United States); Shenzhen Polytechnic, Guangdong (China)

We demonstrate the assembly of a mononuclear metal center, a hexanuclear cluster, and a V-shaped, trapezoidal tetracarboxylate linker into a microporous MOF featuring an unprecedented 3-nodal (4,4,8)-c lyu topology. Here, the compound, HIAM-302, represents the first example that incorporates both primary building unit (PBU) and hexanuclear secondary building unit (SBU) in one structure, which should be attributed to the desymmetrized geometry of the organic linker. HIAM-302 possesses optimal pore dimensions and can separate mono-branched and di-branched alkanes through selective molecular sieving, which is of significant value in petrochemical industry.

View Accepted Manuscript (DOE)

Research Organization:: Wake Forest Univ., Winston-Salem, NC (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019902

OSTI ID:: 1863575

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 9 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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