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Austen Angell's legacy in electrolyte research

Journal Article · · Journal of Non-Crystalline Solids. X
 [1];  [2];  [1]
  1. Army Research Lab., Adelphi, MD (United States)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
In Austen Angell's long and fruitful scientific career, electrolyte research represented a brief and temporary “tangent” that deviated from his normal trajectory of interest. However, with this tangential touch, he left profound and rich legacies in the understanding of fundamental aspects of electrolyte science, the ripple effect of which can still be felt today.
Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
1861989
Report Number(s):
PNNL-SA-169405
Journal Information:
Journal of Non-Crystalline Solids. X, Journal Name: Journal of Non-Crystalline Solids. X Vol. 14; ISSN 2590-1591
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (66)

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High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes journal March 2018
Designing Advanced In Situ Electrode/Electrolyte Interphases for Wide Temperature Operation of 4.5 V Li||LiCoO 2 Batteries journal November 2020
High‐Performance Silicon Anodes Enabled By Nonflammable Localized High‐Concentration Electrolytes journal July 2019
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range journal April 2020
Functionalized Phosphonium Cations Enable Zinc Metal Reversibility in Aqueous Electrolytes journal April 2021
Advanced Low‐Flammable Electrolytes for Stable Operation of High‐Voltage Lithium‐Ion Batteries journal April 2021
Critical Factors Dictating Reversibility of the Zinc Metal Anode journal April 2020
Electrical conductivity in ionic complexes of poly(ethylene oxide) journal September 1975
Relaxation in liquids, polymers and plastic crystals — strong/fragile patterns and problems journal June 1991
Frequency-dependent conductivity, relaxation times, and the conductivity/viscosity coupling problem, in polymer-electrolyte solutions: LiClO4 and NaCF3SO3 in PPO 4000 journal July 1992
Variations on the salt-polymer electrolyte theme for flexible solid electrolytes journal July 1996
Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries journal August 2018
Sulfone-based electrolytes for high-voltage Li-ion batteries journal May 2009
Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries journal January 2021
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes journal August 2018
Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions journal July 2019
Uncharted Waters: Super-Concentrated Electrolytes journal January 2020
LiBOB: Is it an alternative salt for lithium ion chemistry? journal August 2005
Stabilizing ultrahigh-nickel layered oxide cathodes for high-voltage lithium metal batteries journal April 2021
Unravelling high-temperature stability of lithium-ion battery with lithium-rich oxide cathode in localized high-concentration electrolyte journal October 2020
Enabling Ether-Based Electrolytes for Long Cycle Life of Lithium-Ion Batteries at High Charge Voltage journal November 2020
Toward the Practical Use of Cobalt-Free Lithium-Ion Batteries by an Advanced Ether-Based Electrolyte journal September 2021
Optimized Electrolyte with High Electrochemical Stability and Oxygen Solubility for Lithium–Oxygen and Lithium–Air Batteries journal June 2020
Highly Reversible Sodium Ion Batteries Enabled by Stable Electrolyte-Electrode Interphases journal September 2020
Electrolyte Regulating toward Stabilization of Cobalt-Free Ultrahigh-Nickel Layered Oxide Cathode in Lithium-Ion Batteries journal March 2021
High-Efficiency Zinc-Metal Anode Enabled by Liquefied Gas Electrolytes journal November 2021
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes journal January 2018
A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries journal July 2018
Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases journal September 2019
Ion-pairing effects on viscosity/conductance relations in Raman-characterized polymer electrolytes: lithium perchlorate and sodium triflate in PPG(4000) journal November 1991
Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes journal August 2011
Correlating Li-Ion Solvation Structures and Electrode Potential Temperature Coefficients journal January 2021
Solvation Sheath of Li + in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry journal May 2007
Understanding Li + –Solvent Interaction in Nonaqueous Carbonate Electrolytes with 17 O NMR journal May 2013
Differentiating Contributions to “Ion Transfer” Barrier from Interphasial Resistance and Li + Desolvation at Electrolyte/Graphite Interface journal July 2010
Rubbery solid electrolytes with dominant cationic transport and high ambient conductivity journal March 1993
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries journal February 2013
Batteries: Widening voltage windows journal October 2016
Aqueous interphase formed by CO2 brings electrolytes back to salt-in-water regime journal October 2021
High-energy lithium metal pouch cells with limited anode swelling and long stable cycles journal May 2019
Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization journal September 2019
Realizing high zinc reversibility in rechargeable batteries journal August 2020
Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries journal June 2021
Highly reversible zinc metal anode for aqueous batteries journal April 2018
On the concept of ionicity in ionic liquids journal January 2009
Energy storage emerging: A perspective from the Joint Center for Energy Storage Research journal June 2020
Role of inner solvation sheath within salt–solvent complexes in tailoring electrode/electrolyte interphases for lithium metal batteries journal November 2020
Formation of Glasses from Liquids and Biopolymers journal March 1995
"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries journal November 2015
A rechargeable zinc-air battery based on zinc peroxide chemistry journal December 2020
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions journal January 2001
A Fusible Orthoborate Lithium Salt with High Conductivity in Solutions journal January 1999
Electrochemical Intercalation of  PF 6 into Graphite journal January 2000
High Li[sup +] Self-Diffusivity and Transport Number in Novel Electrolyte Solutions journal January 2001
LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation journal January 2002
Sulfone-Based Electrolytes for Lithium-Ion Batteries journal January 2002
Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate journal September 2002
Formation of the Graphite/Electrolyte Interface by Lithium Bis(oxalato)borate journal January 2003
LiMOB, an Unsymmetrical Nonaromatic Orthoborate Salt for Nonaqueous Solution Electrochemical Applications journal January 2004
Inorganic Electrolyte Solutions and Gels for Rechargeable Lithium Batteries journal September 1996
Room Temperature Inorganic “Quasi‐Molten Salts” as Alkali‐Metal Electrolytes journal November 1996
A Novel Electrolyte Solvent for Rechargeable Lithium and Lithium‐Ion Batteries journal December 1996
High Anodic Stability of a New Electrolyte Solvent: Unsymmetric Noncyclic Aliphatic Sulfone journal January 1998
“Charge-Transfer” Process at Graphite/Electrolyte Interface and the Solvation Sheath Structure of Li[sup +] in Nonaqueous Electrolytes journal January 2007
Preferential Solvation of Li+ Directs Formation of Interphase on Graphitic Anode journal January 2011

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