Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Enantiomerically enriched, polycrystalline molecular sieves

Patent ·
OSTI ID:1860176
This disclosure describes enantiomerically enriched chiral molecular sieves and methods of making and using the same. In some embodiments, the molecular sieves are silicates or germanosilicates of STW topology.
Research Organization:
California Institute of Technology, Pasadena, CA (United States); William Marsh Rice University, Houston, TX (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-03ER15456
Assignee:
California Institute of Technology (Pasadena, CA); William Marsh Rice University (Houston, TX)
Patent Number(s):
11,203,013
Application Number:
15/875,245
OSTI ID:
1860176
Country of Publication:
United States
Language:
English

References (57)

A Pure Silica Chiral Polymorph with Helical Pores journal March 2012
Synthesis of a Specified, Silica Molecular Sieve by Using Computationally Predicted Organic Structure-Directing Agents journal June 2014
A Highly Configurationally Stable [4]Heterohelicenium Cation journal July 2003
A Pure Silica Chiral Polymorph with Helical Pores journal March 2012
Towards the Rational Design of Efficient Organic Structure-Directing Agents for Zeolite Synthesis journal October 2013
Synthesis of a Specified, Silica Molecular Sieve by Using Computationally Predicted Organic Structure-Directing Agents journal June 2014
ChemInform Abstract: Synthesis of New Zeolite Structures journal November 2015
Chiral Organic Structure-Directing Agents book January 2017
High resolution, quasi-equilibrium sorption studies of molecular sieves journal January 1990
Impact of Zeolites on the Petroleum and Petrochemical Industry journal May 2009
Computationally-Guided Synthesis of the 8-Ring Zeolite AEI journal April 2015
Toward the rational design of zeolite synthesis: The synthesis of zeolite ZSM-18 journal November 1994
Cyclopropanes—XVII journal January 1964
Stereoselective synthesis of cyclopropane-1,2-bis(glycine) derivatives journal July 1997
Chiral anion-mediated asymmetric induction onto chiral diquats journal January 2002
Guest/host relationships in zeolite synthesis: ring-substituted piperidines and the remarkable adamantane mimicry by 1-azonio spiro [5.5] undecanes journal June 1998
Separation of naproxen enantiomers by supercritical/subcritical fluid chromatography journal September 2005
Enantioselective adsorption and diffusion of S-/R-glycidol in homochiral zeolites: A molecular simulation study journal February 2011
Crystallization of zeolite beta in the presence of chiral amine or rhodium complex journal March 2008
Synthesis and characterization of pure silica zeolite beta obtained by an aging–drying method journal August 2011
Translating new materials discoveries in zeolite research to commercial manufacture journal October 2011
Synthesis of RTH-Type Zeolites Using a Diverse Library of Imidazolium Cations journal May 2015
Monomolecular Skeletal Isomerization of 1-Butene over Selective Zeolite Catalysts journal March 2015
Design of Heterogeneous Catalysts for Fuels and Chemicals Processing: An Overview book January 2013
Zeolite and molecular sieve synthesis journal July 1992
Facile Preparation of Aluminosilicate RTH across a Wide Composition Range Using a New Organic Structure-Directing Agent journal December 2014
New Stories of Zeolite Structures: Their Descriptions, Determinations, Predictions, and Evaluations journal May 2014
Predicting the Templating Ability of Organic Additives for the Synthesis of Microporous Materials journal July 1995
Cyclopropylarene chemistry. IV. Homoketenyl cations in a Friedel-Crafts acylation journal August 1973
Cyclopropanes. VIII. 1 Rates of Ring Opening of Substituted Cyclopropyl Ketones and Carbinols 2 journal May 1961
Synthesis, Structure, and Optical Activity of HPM-1, a Pure Silica Chiral Zeolite journal July 2013
Probes for Narcotic Receptor Mediated Phenomena. 41. Unusual Inverse μ-Agonists and Potent μ-Opioid Antagonists by Modification of the N-Substituent in Enantiomeric 5-(3-Hydroxyphenyl)morphans journal January 2011
Synthesis and Application of Chiral Cyclopropane-Based Ligands in Palladium-Catalyzed Allylic Alkylation journal October 2004
Performance of Chiral Zeolites for Enantiomeric Separation Revealed by Molecular Simulation journal December 2010
Predicting Structural Feasibility of Silica and Germania Zeolites journal January 2010
Synthesis and Optical Properties of Asymmetric Polyamides Derived from Optically Active Cyclic Dicarboxylic Acids journal November 1971
Synthesis and Optical Properties of Asymmetric Polyamides Derived from Optically Active Dicarboxylic Acids and Spirodiamine journal January 1975
Configurational Ordering of Cationic Chiral Dyes Using a Novel C 2 -Symmetric Hexacoordinated Phosphate Anion journal November 2000
Efficient NMR Enantiodifferentiation of Chiral Quats with BINPHAT Anion journal March 2002
De novo design of structure-directing agents for the synthesis of microporous solids journal August 1996
Ordered porous materials for emerging applications journal June 2002
The ITQ-37 mesoporous chiral zeolite journal April 2009
Induction of chiral porous solids containing only achiral building blocks journal April 2010
A zeolite family with chiral and achiral structures built from the same building layer journal April 2008
In silico screening of carbon-capture materials journal May 2012
Electron crystallography for determining the handedness of a chiral zeolite nanocrystal journal May 2017
Synthesis of chiral polymorph A-enriched zeolite Beta with an extremely concentrated fluoride route journal June 2015
CIT-7, a crystalline, molecular sieve with pores bounded by 8 and 10-membered rings journal January 2015
High-silica, heulandite-type zeolites prepared by direct synthesis and topotactic condensation journal January 2015
Chiral zeolitic materials: structural insights and synthetic challenges journal January 2008
Chiral silicate zeolites journal January 2009
A database of new zeolite-like materials journal January 2011
Computational prediction of chemically synthesizable organic structure directing agents for zeolites journal January 2013
Spontaneous nucleation and growth of pure silica zeolite-? free of connectivity defects journal January 1996
Enantiomerically enriched, polycrystalline molecular sieves journal May 2017
Structural Characterization of Zeolite Beta
  • Newsam, J. M.; Treacy, M. M. J.; Koetsier, W. T.
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 420, Issue 1859 https://doi.org/10.1098/rspa.1988.0131
journal December 1988
(±) trans-3,3'-(1,2-Cyclpropanediyl)Bis-2-(E)-Propenoic Acid, Diethyl Ester : Tandem Oxidation Procedure (TOP) Using MnO2 Oxidation-stabilized Phosphorane Trapping journal January 2008

Similar Records

Enantiomerically enriched, polycrystalline molecular sieves
Patent · Tue May 09 00:00:00 EDT 2023 · OSTI ID:1998348

Enantiomerically enriched, polycrystalline molecular sieves
Journal Article · Sun Apr 30 20:00:00 EDT 2017 · Proceedings of the National Academy of Sciences of the United States of America · OSTI ID:1429468

Further Investigations of Racemic and Chiral Molecular Sieves of the STW Topology
Journal Article · Tue Feb 23 19:00:00 EST 2021 · Chemistry of Materials · OSTI ID:1846400

Related Subjects