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Ternary borides and borohydrides for hydrogen storage and method of synthesis

Patent ·
OSTI ID:1860134

A method and a system is provided for obtaining solid-state hydrogen storage and release in materials with at least theoretical loaded hydrogen densities of 11 wt % or greater that can deliver hydrogen and be recharged at moderate temperatures enabling incorporation into hydrogen storage systems suitable for transportation applications. These materials comprise ternary boride materials comprising certain light transition metals and alkaline or alkaline earth metals, and ideally have no or very little phase separation. A process of making these materials is also provided.

Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
DOE Contract Number:
NA0003525
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Number(s):
11,192,783
Application Number:
15/812,254
OSTI ID:
1860134
Country of Publication:
United States
Language:
English

References (4)

Reversibility and Improved Hydrogen Release of Magnesium Borohydride journal February 2010
Metal borohydrides and derivatives – synthesis, structure and properties journal January 2017
First-Principles Prediction of a Ground State Crystal Structure of Magnesium Borohydride journal March 2008
Boron-Based Hydrogen Storage: Ternary Borides and Beyond report April 2016

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