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Three-dimensional porous siloxanes using leachable porogen particles

Patent ·
OSTI ID:1860089
According to one embodiment, a silicone-based ink for additive manufacturing includes a vinyl-terminated diphenyl siloxane macromer, a treated silica hydrophobic reinforcing filler, a rheology modifying additive, and a plurality of porogen particles. According to another embodiment, a product of additive manufacturing with a silicone-based ink includes a plurality of continuous filaments comprised of a siloxane matrix, where the continuous filaments are arranged in a geometric pattern, a plurality of inter-filament pores defined by the geometric pattern of the continuous filaments, and a plurality of intra-filament pores having an average diameter in a range of greater than 1 micron to less than 50 microns.
Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-07NA27344
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA)
Patent Number(s):
11,180,670
Application Number:
16/368,725
OSTI ID:
1860089
Country of Publication:
United States
Language:
English

References (12)

Gamma radiation effects on siloxane-based additive manufactured structures journal January 2017
Production of aluminum foam by spherical carbamide space holder technique-processing parameters journal October 2010
Deformable Hollow Hybrid Silica/Siloxane Colloids by Emulsion Templating journal April 2006
Effect of diphenylsiloxane unit content on relaxation behavior of poly(dimethylsiloxane‐co‐diphenylsiloxane) journal August 2008
Custom 3D Printable Silicones with Tunable Stiffness journal December 2017
Production of Aluminum Glass Fiber Reinforced Foam Synthesized by Space-Holder Technique journal April 2016
The thermal degradation of polysiloxanes—Part 4: Poly(dimethyl/diphenyl siloxane) journal January 1980
Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness journal May 2014
Preparation of Novel Silicone Multicompartment Particles by Multiple Emulsion Templating and Their Use As Encapsulating Systems journal December 2013
Synthesis of Monodisperse Colloidal Spheres, Capsules, and Microballoons by Emulsion Templating journal April 2005
Microencapsulation of Active Ingredients Using PDMS as Shell Material journal November 2014
Urea Finishing Process: Prilling Versus Granulation journal January 2015

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