High capacity organic radical mediated phosphorous anode for redox flow batteries

Delnick, Frank M.; Nanda, Jagjit; Self, Ethan C.

High capacity organic radical mediated phosphorous anode for redox flow batteries

Patent · Tue Oct 12 04:00:00 EDT 2021

OSTI ID:1859954

Delnick, Frank M.; Nanda, Jagjit; Self, Ethan C.

A battery includes a redox flow anode chamber coupled to an anode current collector, a separator, and an external container in fluid connection with the redox flow anode chamber. The external container has therein a solid phosphorus material. A first redox-active mediator and the second redox-active mediator are circulated through the half-cell electrode chamber and the external container. During a charging cycle the first redox-active mediator is reduced at the current collector electrode and the reduced first mediator reduces the phosphorus material, and wherein during a discharging cycle the second redox-active mediator is oxidized at the anode current collector electrode, and the second redox-active mediator is then reduced by the reduced phosphorus material. A method of operating a battery and a method of making a battery are also discussed.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-00OR22725

Assignee:: UT-Battelle, LLC (Oak Ridge, TN)

Patent Number(s):: 11,145,885

Application Number:: 16/519,613

OSTI ID:: 1859954

Country of Publication:: United States

Language:: English

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