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Elucidating the Structure of Bimetallic NiW/SiO 2 Catalysts and Its Consequences on Selective Deoxygenation of m -Cresol to Toluene

Journal Article · · ACS Catalysis
 [1];  [2];  [3];  [4];  [4];  [3];  [5];  [4];  [2]
  1. Collaborative Innovation Center of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China, School of Chemical, Biological, and Materials Engineering, The University of Oklahoma, Norman, Oklahoma 73019, United States
  2. School of Chemical, Biological, and Materials Engineering, The University of Oklahoma, Norman, Oklahoma 73019, United States
  3. Davidson School of Chemical Engineering, Purdue University, West Lafayette, Indiana 47907, United States
  4. Collaborative Innovation Center of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  5. Department of Chemistry and Biochemistry, Southern Illinois University, Carbondale, Illinois 62901, United States
Not Available
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0018284
OSTI ID:
1859434
Alternate ID(s):
OSTI ID: 1778996
OSTI ID: 1780626
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 5 Vol. 11; ISSN 2155-5435
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (67)

Highly Selective Catalytic Conversion of Phenolic Bio-Oil to Alkanes journal May 2009
Tungsten-Based Bimetallic Catalysts for Selective Cleavage of Lignin C−O Bonds journal November 2017
Vapor-Phase Hydrodeoxygenation of Guaiacol to Aromatics over Pt/HBeta: Identification of the Role of Acid Sites and Metal Sites on the Reaction Pathway journal February 2018
Spectroscopic studies on tetragonal ZrO2-supported MoO3 and NiO−MoO3 systems journal July 1998
Catalysis on Pd/WO3 and Pd/WO2: Effect of the Modifications of the Surface States Due to Redox Treatments on the Skeletal Rearrangement of Hydrocarbons journal June 1999
The O-W (oxygen-tungsten) system journal August 1989
Structural, optical and magnetic properties of pure and rare earth-doped NiO nanoparticles journal April 2020
The Effect of Metal Type on Hydrodeoxygenation of Phenol Over Silica Supported Catalysts journal July 2016
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Raman spectroscopic study of Ni/Al2O3 catalyst journal July 1999
NaOH modified WO3/SiO2 catalysts for propylene production from 2-butene and ethylene metathesis journal February 2014
Vapor-phase hydrodeoxygenation of guaiacol on Al-MCM-41 supported Ni and Co catalysts journal February 2016
Hydrodeoxygenation of guaiacol on tungstated zirconia supported Ru catalysts journal August 2017
Synergy effect in the HDO of phenol over Ni–W catalysts supported on active carbon: Effect of tungsten precursors journal November 2010
Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity journal January 2011
The catalytic activity of Pd/WOx/γ-Al2O3 for hydrodeoxygenation of guaiacol journal May 2014
Enhanced direct deoxygenation of anisole to benzene on SiO2-supported Ni-Ga alloy and intermetallic compound journal August 2019
Enhanced production of phenolics and aromatics from raw bio-oil using HZSM-5 zeolite additives for PtPd/C and NiW/C catalysts journal December 2019
Sonochemical synthesis, size controlling and gas sensing properties of NiO nanoparticles journal February 2011
Structure–acidity correlation of supported tungsten(VI)-oxo-species: FT-IR and TPD studies of adsorbed pyridine and catalytic decomposition of 2-propanol journal July 2014
Review of fast pyrolysis of biomass and product upgrading journal March 2012
A review of catalytic hydrodeoxygenation of lignin-derived phenols from biomass pyrolysis journal November 2012
Thermodynamic modeling and first-principles calculations of the Mo–O system journal June 2014
Influence on nickel particle size on the hydrodeoxygenation of phenol over Ni/SiO 2 journal January 2016
Vapor phase hydrodeoxygenation and hydrogenation of m -cresol on silica supported Ni, Pd and Pt catalysts journal October 2015
Synthesis, characterization, optical and magnetic properties of pure and Mn, Fe and Zn doped NiO nanoparticles journal January 2019
Heterobimetallic catalysis for lignocellulose to ethylene glycol on nickel-tungsten catalysts: Influenced by hydroxy groups journal October 2018
Atmospheric hydrodeoxygenation of bio-oil oxygenated model compounds: A review journal August 2018
Oxidative dehydrogenation of ethane over Ni–W–O mixed metal oxide catalysts journal May 2011
Bifunctional transalkylation and hydrodeoxygenation of anisole over a Pt/HBeta catalyst journal July 2011
Tuning the selectivity for ring-opening reactions of methylcyclopentane over Pt catalysts: A mechanistic study from first-principles calculations journal January 2012
Comparison of kinetics, activity and stability of Ni/HZSM-5 and Ni/Al2O3-HZSM-5 for phenol hydrodeoxygenation journal December 2012
Active sites of Ni2P/SiO2 catalyst for hydrodeoxygenation of guaiacol: A joint XAFS and DFT study journal March 2014
Geometric and electronic effects of bimetallic Ni–Re catalysts for selective deoxygenation of m-cresol to toluene journal May 2017
Selective conversion of m-cresol to toluene over bimetallic Ni–Fe catalysts journal July 2014
Visible light assisted photocatalysis of Methylene Blue and Rose Bengal dyes by iron doped NiO nanoparticles prepared via chemical co-precipitation journal February 2020
Competition and Cooperation of Hydrogenation and Deoxygenation Reactions during Hydrodeoxygenation of Phenol on Pt(111) journal May 2017
Experimental and Theoretical Insights into the Hydrogen-Efficient Direct Hydrodeoxygenation Mechanism of Phenol over Ru/TiO 2 journal October 2015
Role of Branching on the Rate and Mechanism of C–C Cleavage in Alkanes on Metal Surfaces journal December 2015
Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review journal July 2016
Enhanced Hydrodeoxygenation of m -Cresol over Bimetallic Pt–Mo Catalysts through an Oxophilic Metal-Induced Tautomerization Pathway journal June 2016
Size Dependence of Vapor Phase Hydrodeoxygenation of m -Cresol on Ni/SiO 2 Catalysts journal January 2018
Mechanistic Study of the Direct Hydrodeoxygenation of m -Cresol over WO x -Decorated Pt/C Catalysts journal July 2018
Enhancement of m -Cresol Hydrodeoxygenation Selectivity on Ni Catalysts by Surface Decoration of MoO x Species journal July 2019
Does a Strong Oxophilic Promoter Enhance Direct Deoxygenation? A Study of NiFe, NiMo, and NiW Catalysts in p -Cresol Conversion journal November 2017
Controlled Hydrodeoxygenation of Phenolic Components in Pyrolysis Bio-oil to Arenes journal March 2018
The Catalytic Valorization of Lignin for the Production of Renewable Chemicals journal June 2010
Screening of Catalysts for Hydrodeoxygenation of Phenol as a Model Compound for Bio-oil journal July 2013
Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m -Cresol journal August 2014
Role of Keto Intermediates in the Hydrodeoxygenation of Phenol over Pd on Oxophilic Supports journal January 2015
Synthesis, Characterization, and Epoxidation Activity of Tungsten-Incorporated SBA-16 (W-SBA-16)
  • Maheswari, Rajamanickam; Pachamuthu, Muthusamy P.; Ramanathan, Anand
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 49 https://doi.org/10.1021/ie501784c
journal March 2014
Changes in Catalytic and Adsorptive Properties of 2 nm Pt 3 Mn Nanoparticles by Subsurface Atoms journal October 2018
In Situ Spectroscopic Investigation of the Molecular and Electronic Structures of SiO 2 Supported Surface Metal Oxides journal October 2007
Structural Determination of Bulk and Surface Tungsten Oxides with UV−vis Diffuse Reflectance Spectroscopy and Raman Spectroscopy journal September 2007
Advances in C–O Bond Transformations in Lignin-Derived Compounds for Biofuels Production journal August 2011
Selective production of arenes via direct lignin upgrading over a niobium-based catalyst journal July 2017
Catalytic conversion of compounds representative of lignin-derived bio-oils: a reaction network for guaiacol, anisole, 4-methylanisole, and cyclohexanone conversion catalysed by Pt/γ-Al 2 O 3 journal January 2012
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation journal January 2014
Stability and resistance of nickel catalysts for hydrodeoxygenation: carbon deposition and effects of sulfur, potassium, and chlorine in the feed journal January 2014
Insights into the catalytic activity and surface modification of MoO 3 during the hydrodeoxygenation of lignin-derived model compounds into aromatic hydrocarbons under low hydrogen pressures journal January 2014
Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C–O cleavage over ruthenium–tungsten bifunctional catalysts journal January 2015
Hydrodeoxygenation of phenol over Ni-based bimetallic single-atom surface alloys: mechanism, kinetics and descriptor journal January 2019
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation journal September 1992
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Self-supported hydrogenolysis of aromatic ethers to arenes journal November 2019
Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils journal November 2010

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