Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO 2

Journal Article · · ACS Applied Materials and Interfaces
 [1];  [2];  [3];  [4];  [4];  [1];  [4];  [3];  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, United States
  2. Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, United States
  3. Department of Chemical and Environmental Engineering, University of California Riverside, Riverside, California 92521, United States
  4. US Army Combat Capabilities Development Command Chemical Biological Center, 8198 Blackhawk Road, Aberdeen Proving Ground, Aberdeen, Maryland 21010, United States
Not Available
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1858378
Alternate ID(s):
OSTI ID: 1981986
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 45 Vol. 13; ISSN 1944-8244
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (59)

Surface Faceting and Reconstruction of Ceria Nanoparticles journal December 2016
Semiempirical GGA-type density functional constructed with a long-range dispersion correction journal January 2006
Thermal Decomposition of Dimethyl Methylphosphonate over Manganese Oxide Catalysts journal February 2001
Raman scattering as a probe of phonon confinement and surface optical modes in semiconducting nanowires journal September 2006
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Reactive adsorption of toxic organophosphates parathion methyl and DMMP on nanostructured Ti/Ce oxides and their composites journal December 2019
Theoretical investigation of dephosphorylation of phosphate monoesters on CeO2(111) journal August 2018
A critical review on visible-light-response CeO2-based photocatalysts with enhanced photooxidation of organic pollutants journal September 2019
Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate, in presence of metal oxides journal August 2021
Model-based optimization of parameters for degradation reaction of an organophosphorus pesticide, paraoxon, using CeO2 nanoparticles in water media journal July 2017
Highly selective detection of dimethyl methylphosphonate (DMMP) using CuO nanoparticles /ZnO flowers heterojunction journal March 2017
The surface chemistry of cerium oxide journal March 2015
Dimethyl methylphosphonate decomposition on fully oxidized and partially reduced ceria thin films journal March 2010
Molecular and dissociative adsorption of DMMP, Sarin and Soman on dry and wet TiO2(110) using density functional theory journal September 2018
Theoretical analysis of the adsorption of phosphoric acid and model phosphate monoesters on CeO2(111) journal March 2021
Spectroscopic and Computational Investigation of Room-Temperature Decomposition of a Chemical Warfare Agent Simulant on Polycrystalline Cupric Oxide journal August 2017
Fundamentals and Catalytic Applications of CeO 2 -Based Materials journal April 2016
Facile Decomposition of Organophosphonates by Dual Lewis Sites on a Fe 3 O 4 (111) Film journal May 2020
Adsorption of Dimethyl Methylphosphonate on MoO 3 : The Role of Oxygen Vacancies journal December 2016
Trends in Adhesion Energies of Gold on MgO(100), Rutile TiO 2 (110), and CeO 2 (111) Surfaces: A Comparative DFT Study journal December 2017
Fixed Feed Temperature-Programmed Modulation—A Quantitative Method To Obtain Thermophysical Parameters: Application to Chemical Warfare Agent Adsorbents journal March 2019
Spectroscopically Resolved Binding Sites for the Adsorption of Sarin Gas in a Metal–Organic Framework: Insights beyond Lewis Acidity journal August 2019
Degradation of Fatal Toxic Nerve Agents on Dry TiO 2 journal December 2020
Environmental Effects on Zirconium Hydroxide Nanoparticles and Chemical Warfare Agent Decomposition: Implications of Atmospheric Water and Carbon Dioxide journal October 2017
Multimodal Characterization of Materials and Decontamination Processes for Chemical Warfare Protection journal December 2019
Kinetics of Dimethyl Methylphosphonate Adsorption and Decomposition on Zirconium Hydroxide Using Variable Temperature In Situ Attenuated Total Reflection Infrared Spectroscopy journal February 2020
Adsorption and Destruction of the G-Series Nerve Agent Simulant Dimethyl Methylphosphonate on Zinc Oxide journal December 2018
Surface chemistry of organophosphorus compounds journal November 1988
Adsorption and decomposition of dimethyl methylphosphonate on an aluminum oxide surface journal January 1985
MCM-48-like Large Mesoporous Silicas with Tailored Pore Structure:  Facile Synthesis Domain in a Ternary Triblock Copolymer−Butanol−Water System journal May 2005
Adsorption and Decomposition of Dimethyl Methylphosphonate on TiO 2 journal December 2000
Decomposition of Dimethyl Methylphosphonate (DMMP) on Supported Cerium and Iron Co-Impregnated Oxides at Room Temperature journal December 2002
Adsorption and Decomposition of Dimethyl Methylphosphonate on Y 2 O 3 Nanoparticles journal January 2007
Quantum-Chemical Study of the Adsorption of DMMP and Sarin on γ-Al 2 O 3 journal February 2007
Ordered Mesoporous CeO 2 Synthesized by Nanocasting from Cubic Ia3d Mesoporous MCM-48 Silica: Formation, Characterization and Photocatalytic Activity journal October 2008
Computational Study of Environmental Effects in the Adsorption of DMMP, Sarin, and VX on γ-Al 2 O 3 : Photolysis and Surface Hydroxylation journal January 2009
Thermal Decomposition of a Chemical Warfare Agent Simulant (DMMP) on TiO 2 : Adsorbate Reactions with Lattice Oxygen as Studied by Infrared Spectroscopy journal August 2009
Decomposition of Dimethyl Methylphosphonate (DMMP) on Alumina-Supported Iron Oxide journal September 1998
Interaction of dimethyl methylphosphonate with metal oxides journal January 1989
Uptake of a Chemical Warfare Agent Simulant (DMMP) on TiO 2 : Reactive Adsorption and Active Site Poisoning journal March 2009
Synthesis of thermally stable mesoporous cerium oxide with nanocrystalline frameworks using mesoporous silica templates journal January 2003
Ordered mesoporous metal oxides: synthesis and applications journal January 2012
Synthesis of non-siliceous mesoporous oxides journal January 2014
IR spectroscopic investigations of chemical and photochemical reactions on metal oxides: bridging the materials gap journal January 2017
Shape-selective synthesis of nanoceria for degradation of paraoxon as a chemical warfare simulant journal January 2019
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
Quantum size effects in Raman spectra of Si nanocrystals journal April 2011
Catalytic Properties of Ceria and CeO 2 -Containing Materials journal November 1996
Dimethyl methylphosphonate adsorption and decomposition on MoO 2 as studied by ambient pressure x-ray photoelectron spectroscopy and DFT calculations journal March 2018
Use and mis-use of x-ray photoemission spectroscopy Ce3d spectra of Ce 2 O 3 and CeO 2 journal August 2018
Inhomogeneous Electron Gas journal November 1964
Self-Consistent Equations Including Exchange and Correlation Effects journal November 1965
Ab initiomolecular dynamics for liquid metals journal January 1993
Projector augmented-wave method journal December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal January 1998
Generalized Gradient Approximation Made Simple journal October 1996
A fundamental parameters approach to X-ray line-profile fitting journal April 1992
Designing Oxide Aerogels With Enhanced Sorptive and Degradative Activity for Acute Chemical Threats journal May 2021

Similar Records

Understanding Dimethyl Methylphosphonate Adsorption and Decomposition on Mesoporous CeO 2
Journal Article · Wed Nov 03 00:00:00 EDT 2021 · ACS Applied Materials and Interfaces · OSTI ID:1981986

Adsorption and decomposition of dimethyl methylphosphonate on size-selected (MoO 3 ) 3 clusters
Journal Article · Sun Dec 31 23:00:00 EST 2017 · Physical Chemistry Chemical Physics · OSTI ID:1492845

Dimethyl methylphosphonate adsorption and decomposition on MoO2 as studied by ambient pressure x-ray photoelectron spectroscopy and DFT calculations
Journal Article · Thu Mar 08 19:00:00 EST 2018 · Journal of Physics. Condensed Matter · OSTI ID:1465445

Related Subjects