Current status and future directions of multivalent metal-ion batteries

Liang, Yanliang; Dong, Hui; Aurbach, Doron; Yao, Yan

doi:10.1038/s41560-020-0655-0

Current status and future directions of multivalent metal-ion batteries

Journal Article · Thu Jul 16 00:00:00 EDT 2020 · Nature Energy

DOI:https://doi.org/10.1038/s41560-020-0655-0· OSTI ID:1856674

^[1]; ^[2]; ^[3]; ^[2]

Univ. of Houston, TX (United States); University of Houston
Univ. of Houston, TX (United States)
Bar-Ilan Univ., Ramat-Gan (Israel)

Batteries based on multivalent metals have the potential to meet the future needs of large-scale energy storage, due to the relatively high abundance of elements such as magnesium, calcium, aluminium and zinc in the Earth’s crust. However, the com- plexity of multivalent metal-ion chemistries has led to rampant confusions, technical challenges, and eventually doubts and uncertainties about the future of these technologies. In this Review, we clarify the key strengths as well as common misconceptions of multivalent metal-based batteries. We then examine the growth behaviour of metal anodes, which is crucial for their safety promises but hitherto unestablished. We further discuss scrutiny of anode efficiency and cathode storage mechanism pertaining to complications arising from electrolyte solutions. Lastly, we critically review existing cathode materials and discuss design strategies to enable genuine multivalent metal-ion-based energy storage materials with competitive performance.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Houston, TX (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office. Batteries for Advanced Transportation Technologies (BATT) Program

Grant/Contract Number:: EE0008234

OSTI ID:: 1856674

Alternate ID(s):: OSTI ID: 1799466

Journal Information:: Nature Energy, Journal Name: Nature Energy Journal Issue: 9 Vol. 5; ISSN 2058-7546

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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