Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

SO3/H2SO4 continuous real-time sensor demonstration at a power plant

Conference ·
OSTI ID:1855982

We present results from field testing of a new, innovative sensor developed to measure SO3/H2SO4 continuously and in real time at a coal-fired power plant. The system utilizes the sensitivity, specificity, and real-time capabilities of mid-infrared (Mid-IR) laser-based sensor technology, along with a heated, close-coupled cell mounted directly to a power plant duct. Measurements were made by the laser sensor over a 2-day period and compared to results from the accepted method, EPA 8A, which requires a 30-minute collection, labor intensive processing, and off-site analysis at a lab. In contrast to the condensation method, the laser sensor continuously samples flue gas and reports measurements of the concentration of SO3/H2SO4, SO2 ever second with unattended operation. This initial demonstration proved the sensor concept and paves the way for its use for optimizing sorbent injection used to neutralize SO3/H2SO4. Optimized sorbent injection will enable significant cost savings associated with efforts to mitigate the presence and effects of SO3/H2SO4 such as “Blue Plume”, air heater fouling, and duct corrosion. In particular, the real-time, actionable information will enable better control of additive injection in flex conditions and variable fuels.

Research Organization:
Opto-Knowledge Systems, Inc.
Sponsoring Organization:
USDOE Office of Fossil Energy (FE)
DOE Contract Number:
FE0031560
OSTI ID:
1855982
Country of Publication:
United States
Language:
English

Similar Records

Infrared Absorption Spectra of H2SO4, SO3, SO2, and H2O at 300C and 350C
Dataset · Thu Apr 28 00:00:00 EDT 2022 · OSTI ID:1899775

Mid Infra-Red Laser Sensor for Continuous Sulfur Trioxide Monitoring to Improve Coal-Fired Power Plant Performance during Flexible Operations
Technical Report · Fri Jul 30 00:00:00 EDT 2021 · OSTI ID:1846723

SO2 fluorescence from vacuum ultraviolet dissociative excitation of SO3
Journal Article · Thu Jun 04 00:00:00 EDT 1987 · J. Phys. Chem.; (United States) · OSTI ID:6292944