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Title: Characterization of the SRNL-Washed Tank 51 Sludge Batch 10 Qualification Sample

Technical Report ·
DOI:https://doi.org/10.2172/1855349· OSTI ID:1855349
 [1]
  1. Savannah River Nuclear Solutions (SRNS), Aiken, SC (United States); Savannah River National Laboratory (SRNL), Aiken, SC (United States)

Savannah River National Laboratory (SRNL) personnel have been requested to qualify the next sludge batch (Sludge Batch 10 – SB10) for processing at the Defense Waste Processing Facility (DWPF). To accomplish this task, Savannah River Remediation (SRR) sent SRNL two 3-L samples of Tank 51H slurry to be characterized, washed, and then used in a lab-scale demonstration of the DWPF flowsheet. Sample HTF-51-19-114 was received on January 28, 2020, and HTF-51-20-15 was received on February 4, 2020. SRNL washed the Tank 51H sample per the Tank Farm washing strategy. During washing, material from H Canyon Tanks 16.3 and 16.4 was also added to the Tank 51 samples to simulate canyon discharges subsequent to sampling. A part of the qualification process is extensive radionuclide and chemical characterization of the SRNL-washed Tank 51H slurry. This report documents the chemical characterization of the washed slurry; radiological characterization will be documented in a separate report. The major supernatant components, elements on a weight percent calcined basis, and the weight percent solids of the SRNL-washed sample were comparable to the Tank Farm projections, with the exception of free hydroxide and carbonate. Therefore, this SRNL-washed sample is suitable for further SB10 qualification activities and SRR planning for SB10.

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
DOE Contract Number:
89303321CEM000080
OSTI ID:
1855349
Report Number(s):
SRNL-STI-2021-00449; TRN: US2302910
Country of Publication:
United States
Language:
English