Mechanochemical synthesis and structural analysis of trivalent lanthanide and uranium diphenylphosphinodiboranates

Fetrow, Taylor V.; Daly, Scott R.

doi:10.1039/d1dt01932e

Mechanochemical synthesis and structural analysis of trivalent lanthanide and uranium diphenylphosphinodiboranates

Journal Article · Thu Dec 31 23:00:00 EST 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d1dt01932e· OSTI ID:1853239

Fetrow, Taylor V. ^[1]; ^[2]

Department of Chemistry, The University of Iowa, E331 Chemistry Building, Iowa City, Iowa 52242, USA; OSTI
Department of Chemistry, The University of Iowa, E331 Chemistry Building, Iowa City, Iowa 52242, USA

Here we report how mechanochemistry was used to overcome limited solution reactivity for the synthesis of homoleptic uranium and lanthanide phosphinodiboranate complexes with weakly-coordinating (H₃BPPh₂BH₃)^1-.

Research Organization:: Univ. of Iowa, Iowa City, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0019426

OSTI ID:: 1853239

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 33 Vol. 50; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Mechanochemical synthesis and structural analysis of trivalent lanthanide and uranium diphenylphosphinodiboranates

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