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Title: s–p Mixing in Stereochemically Active Lone Pairs Drives the Formation of 1D Chains of Lead Bromide Square Pyramids

Journal Article · · Inorganic Chemistry
ORCiD logo [1]; ORCiD logo [1];  [1]
  1. Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States
+ Show Author Affiliations

Not provided.

Research Organization:
Johns Hopkins Univ., Baltimore, MD (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0019331
OSTI ID:
1853081
Journal Information:
Inorganic Chemistry, Vol. 60, Issue 17; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English

References (37)

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Hybrid perovskite films approaching the radiative limit with over 90% photoluminescence quantum efficiency journal April 2018
The underappreciated lone pair in halide perovskites underpins their unusual properties journal June 2020
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Stereochemistry of lead(II) complexes with oxygen donor ligands journal May 2009
Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids journal January 2013
Molecular geometry: Bonded versus nonbonded interactions journal December 1968
Dynamic Stereochemical Activity of the Sn 2+ Lone Pair in Perovskite CsSnBr 3 journal September 2016
Chemical tuning of dynamic cation off-centering in the cubic phases of hybrid tin and lead halide perovskites journal January 2017
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Understanding the Instability of the Halide Perovskite CsPbI 3 through Temperature‐Dependent Structural Analysis journal July 2020
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The origin of the stereochemically active Pb(II) lone pair: DFT calculations on PbO and PbS journal May 2005
Stereochemistry of post-transition metal oxides: revision of the classical lone pair model journal January 2011
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design journal March 2016
Schwache Sn…I-Wechselwirkungen in den Kristallstrukturen der Iodostannate [SnI4]2- und [SnI3]- journal February 2000
Iodoplumbate mit vier- und fünffach koordinierten Pb2+-Ionen journal April 1999
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Synthesis and Characterization of Bromo- and Bromochloroplumbates(II). Crystal Structures of [Ph 4 E] 2 [Pb 3 Br 8 ] (E = P, As) and [Ph 4 P][PbBrCl 2 ] • CH 3 CN journal May 2000
The Cambridge Structural Database
  • Groom, Colin R.; Bruno, Ian J.; Lightfoot, Matthew P.
  • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 2, p. 171-179 https://doi.org/10.1107/S2052520616003954
journal April 2016
Kinetically Stable Single Crystals of Perovskite-Phase CsPbI 3 journal June 2019
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Bond valence as an aid to understanding the stereochemistry of O and F complexes of Sn(II), Sb(III), Te(IV), I(V) and Xe(VI) journal November 1974
A pencil-and-paper method for elucidating halide double perovskite band structures journal January 2019
Electronic Origins of Structural Distortions in Post-Transition Metal Oxides: Experimental and Theoretical Evidence for a Revision of the Lone Pair Model journal April 2006
Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance journal May 2014
718. An X-ray diffraction determination of the crystal and molecular structure of pentaphenylantimony journal January 1964
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Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
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