Re-evaluation of ortho-para-dependence of self pressure-broadening in the ν1 + ν3 band of acetylene

Gross, Eisen C.; Tsang, Kimberly A.; Sears, Trevor J.

doi:10.1063/5.0036602

Re-evaluation of ortho-para-dependence of self pressure-broadening in the ν₁ + ν₃ band of acetylene

Journal Article · Mon Feb 01 23:00:00 EST 2021 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/5.0036602· OSTI ID:1852730

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State Univ. of New York (SUNY), Albany, NY (United States); State Univ. of New York (SUNY), Albany, NY (United States)
State Univ. of New York (SUNY), Albany, NY (United States)

Optical frequency comb-referenced measurements of self pressure-broadened line profiles of the R(8) to R(13) lines in the ν₁ + ν₃ combination band of acetylene near 1.52 µm are reported. The analysis of the data found no evidence for a previously reported systematic alternation in self pressure-broadened line widths with the nuclear spin state of the molecule. This work brought out the need for the use of an accurate line profile model and careful accounting for weak background absorptions due to hot band and lower abundance isotopomer lines. The data were adequately fit using the quadratic speed-dependent Voigt profile model, neglecting the small speed-dependent shift. Parameters describing the most probable and speed-dependent pressure-broadening, most probable shift, and the line strength were determined for each line. Detailed modeling of the results of Iwakuni et al. showed that their neglect of collisional narrowing due to the speed-dependent broadening term combined with the strongly absorbing data recorded and analyzed in transmission mode were the reasons for their results.

View Accepted Manuscript (DOE)

Research Organization:: State Univ. of New York (SUNY), Albany, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0018950

OSTI ID:: 1852730

Alternate ID(s):: OSTI ID: 1970619

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 5 Vol. 154; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Re-evaluation of ortho-para-dependence of self pressure-broadening in the ν₁ + ν₃ band of acetylene