Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Review of thermophysical property methods applied to fueled and un-fueled molten salts

Journal Article · · Annals of Nuclear Energy
 [1];  [2];  [3]
  1. Brigham Young Univ., Provo, UT (United States). Dept. of Mechanical Engineering; Brigham Young Univ., Provo, UT (United States)
  2. Brigham Young Univ., Provo, UT (United States). Dept. of Chemical Engineering
  3. Brigham Young Univ., Provo, UT (United States). Dept. of Mechanical Engineering

Recent investigation into designs of molten salt reactors (MSR) requires accurate data of candidate salts. Review of the literature shows lacking thermophysical (TP) property data for coolants and fuel-bearing salts of Advanced High Temperature Reactors (AHTR). Measurement uncertainties of current data are even more deficient, and this affects ongoing research where MSR modeling and testing are being performed. Melting temperature, viscosity, density, specific heat capacity, and thermal and electrical conductivity measurements are often not arranged together or discussed in great detail, especially for fuel-bearing salts. Raw data from key findings spanning over 70 years for LiF, LiF-BeF2, LiF-NaF-KF, KCl-MgCl2, KF-ZrF4, and NaF-KF-MgF2 have been organized and presented here. Brief description of methods used to obtain these results, in addition to the TP data of some of these salts as fuel carriers, has also been discussed. Thermal conductivity data are particularly weak due to older, high-error measurement techniques. More recent measurement systems to evaluate salt thermal conductivity show promise for obtaining consistent absolute values. This work concludes that measurement systems such as transient hot-wire method, forced Rayleigh scattering, and laser flash analysis provide the most promise to fill these data gaps and reduce current uncertainty in thermal conductivity measurements of both fueled and un-fueled molten salts.

Research Organization:
Brigham Young Univ., Provo, UT (United States)
Sponsoring Organization:
USDOE Office of Nuclear Energy (NE); Nuclear Regulatory Commission (NRC)
Grant/Contract Number:
NE0008870
OSTI ID:
1850573
Alternate ID(s):
OSTI ID: 1894957
Journal Information:
Annals of Nuclear Energy, Journal Name: Annals of Nuclear Energy Journal Issue: C Vol. 146; ISSN 0306-4549
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (67)

Viscosity Measurements on Molten Salts with an Oscillating Cup Viscometer: Viscosity of Molten KNO 3 and NaCl journal October 1998
Experimental determination of the thermal conductivity of molten pure salts and salt mixtures journal July 1985
Measurement of the thermal conductivity of KNO3-NaNO3 mixtures using a transient hot-wire method with a liquid metal in a capillary probe journal March 1982
Archimedes Revisited journal September 2009
Molar thermal conductivity of molten salts journal November 2015
Specific electrical conductivity of molten flourides journal January 1970
On the frequency- and temperature- dependence of the conductivity of molten salts journal March 1972
Thermal conductivity of molten alkali halides and their mixtures journal July 1987
Molar volumes in the LiFThF4 system journal January 1967
Equilibrium phase diagram of the lithium fluoride-beryllium fluoridezirconium fluoride system journal August 1968
Viscosity of LiF-BeF2 eutectic mixture () and LiF single salt at elevated temperatures journal September 1981
On the measurement of the thermal conductivity of liouids by a non-stationary method journal January 1953
Fluoride salt coolant properties for nuclear reactor applications: A review journal November 2017
Molten salts database for energy applications journal November 2013
Potentialities of the fast spectrum molten salt reactor concept: REBUS-3700 journal October 2006
Thermal conductivity of high temperature fluoride molten salt determined by laser flash technique journal November 2015
A theoretical model for predicting the thermal conductivity of binary molten salts journal January 2016
Materials corrosion in molten LiF–NaF–KF salt journal January 2009
Thermodynamic assessment of the LiF–BeF2–ThF4–UF4 system journal October 2006
Heat capacity and thermal conductivity of molten ternary lithium, sodium, potassium, and zirconium fluorides mixtures journal March 2011
Viscosity of LiF–NaF–KF eutectic and effect of cerium trifluoride and uranium tetrafluoride additions journal October 2014
Modeling and simulation functional needs for molten salt reactor licensing journal December 2019
The molten salt reactor (MSR) in generation IV: Overview and perspectives journal November 2014
Design and licensing strategies for the fluoride-salt-cooled, high-temperature reactor (FHR) technology journal November 2014
Survey and evaluation of equations for thermophysical properties of binary/ternary eutectic salts from NaCl, KCl, MgCl2, CaCl2, ZnCl2 for heat transfer and thermal storage fluids in CSP journal August 2017
Recommended values for the thermal conductivity of molten salts between the melting and boiling points journal July 2014
Thermal conductivities of molten alkali metal halides journal October 1992
New electrochemical measurements of the liquidus in the lithium fluoride-beryllium fluoride system. Congruency of lithium beryllium fluoride (Li2BeF4) journal April 1972
PHASE EQUILIBRIA IN THE SYSTEMS BeF 2 -ThF 4 AND LiF-BeF 2 -ThF 4 journal July 1960
Lithium Fluoride: Heat Content from 0 to 900°, the Melting Point and Heat of Fusion 1 journal October 1954
Fusion properties and heat capacities of the eutectic lithium fluoride-sodium fluoride-potassium fluoride melt journal July 1982
Thermal conductivity of molten salts, HTS and the lithium nitrate-sodium nitrate system, using a modified transient hot-wire method journal January 1984
Surface tensions of lithium fluoride-thorium fluoride binary melts and lithium fluoride-beryllium fluoride-thorium fluoride ternary melts journal April 1984
Density and Viscosity of the (LiF + NaF + KF) e ut (1) + K 2 TaF 7 (2) + Ta 2 O 5 (3) Melts journal March 2006
Radiant Transfer of Heat in Molten Inorganic Compounds at High Temperatures. journal April 1962
Densities and Molal Volumes of Molten Magnesium Chloride, Potassium Chloride, and Barium Chloride Mixtures. journal January 1965
Densities and excess molar volumes of binary and ternary melts of MgCl 2 , CaCl 2 and AlkCl journal January 1971
Viscosity and Density in Molten BeF 2 –LiF Solutions journal April 1969
Metal Dilatometer for Determining Density and Expansivity of Volatile Liquids at Elevated Temperature journal July 1969
Molten Salts: Volume 4, Part 1, Fluorides and Mixtures Electrical Conductance, Density, Viscosity, and Surface Tension Data journal January 1974
Thermal conductivity of molten salt mixtures: Theoretical model supported by equilibrium molecular dynamics simulations journal February 2016
Characteristic of molten fluoride salt system LiF-BeF2 (Flibe) and LiF-NaF-KF (Flinak) as coolant and fuel carrier in molten salt reactor (MSR)
  • Bahri, Che Nor Aniza Che Zainul; Al-Areqi, Wadee’ah Mohd; Ruf, Mohd ’Izzat Fahmi Mohd
  • MATHEMATICAL SCIENCES AND ITS APPLICATIONS, AIP Conference Proceedings https://doi.org/10.1063/1.4972932
conference January 2017
Determination of thermal physical properties of alkali fluoride/carbonate eutectic molten salt
  • An, Xue-Hui; Cheng, Jin-Hui; Su, Tao
  • SOLARPACES 2016: International Conference on Concentrating Solar Power and Chemical Energy Systems, AIP Conference Proceedings https://doi.org/10.1063/1.4984415
conference January 2017
Molten salts: Volume 4, part 2, chlorides and mixtures—electrical conductance, density, viscosity, and surface tension data journal October 1975
A Summary of the Department of Energy’s Advanced Demonstration and Test Reactor Options Study journal July 2017
Thermal-Hydraulic and Neutronic Phenomena Important in Modeling and Simulation of Liquid-Fuel Molten Salt Reactors journal April 2019
Determination of the Thermal Conductivities of Several Molten Alkali Halides by Means of a Sheathed Hot-Wire Technique journal January 1971
A Device for Measuring the Density and Liquidus Temperature of Molten Fluorides for Heat Transfer and Storage journal December 2013
Thermal Conductivity of Liquids journal January 1941
Hot Wire Needle Probe for In-Reactor Thermal Conductivity Measurement journal August 2012
Phase Equilibria in the Ternary Fused-Salt System LiF-BeF2,-UF4 journal February 1962
The Determination of Thermal Diffusivities of Thermal Energy Storage Materials: Part II—Molten Salts Beyond the Melting Point journal July 1969
Batch-Scale Hydrofluorination of Li27BeF4 to Support Molten Salt Reactor Development journal September 2015
Surface tension and density of the molten PbCl 2 –KCl–NaCl ternary system journal May 1985
Specific Conductance of Molten Potassium Nitrate journal January 1969
The Density and Surface Tension of Molten Fluorides journal January 1964
Electrical Conductivity of Molten Fluorides journal January 1957
Electrical Conductivity of Molten Fluorides journal January 1957
Molten-Salt-Cooled Advanced High-Temperature Reactor for Production of Hydrogen and Electricity journal December 2003
Evaluation of Salt Coolants for Reactor Applications journal September 2008
Fast Spectrum Molten Salt Reactor Options report July 2011
Basic Research Needs for Future Nuclear Energy: Report of the Basic Energy Sciences Workshop for Future Nuclear Energy, August 9-11, 2017 report August 2017
Physical Properties of Molten-Salt Reactor Fuel, Coolant, and Flush Salts. report October 1968
Development of the variable-gap technique for measuring the thermal conductivity of fluoride salt mixtures. report January 1973
An Overview of Liquid Fluoride Salt Heat Transport Systems report September 2010
Viscosity of Molten Alkali Fluorides [溶融アルカリ金属弗化物の粘度] journal January 1987
A high-temperature transient hot-wire thermal conductivity apparatus for fluids journal May 1991