Bimetallic uranyl/cobalt( ii ) isothiocyanates: structure, property and spectroscopic analysis of homo- and heterometallic phases

Byrne, Nicole M.; Schofield, Mark H.; Nicholas, Aaron D.; Cahill, Christopher L.

doi:10.1039/d1dt01464a

Title: Bimetallic uranyl/cobalt( ii ) isothiocyanates: structure, property and spectroscopic analysis of homo- and heterometallic phases

Journal Article · Fri Jan 01 00:00:00 EST 2021 · Dalton Transactions

DOI:https://doi.org/10.1039/d1dt01464a· OSTI ID:1849601

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Department of Chemistry; The George Washington University; Washington; USA

An unexpected blue shift in the characteristic uranyl ν1 stretching frequency is observed upon engagement of the uranyl oxo with isothiocyanate group stemming from coupling between U✔O and U-NCS modes.

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Research Organization:: George Washington Univ., Washington, DC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-05ER15736

OSTI ID:: 1849601

Journal Information:: Dalton Transactions, Vol. 50, Issue 26; ISSN 1477-9226

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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