Distribution of rare earth elements in fly ash derived from the combustion of Illinois Basin coals

Hower, James C.; Groppo, John G.; Hsu-Kim, Heileen; Taggart, Ross K.

doi:10.1016/j.fuel.2020.119990

Title: Distribution of rare earth elements in fly ash derived from the combustion of Illinois Basin coals

Journal Article · Thu Dec 31 00:00:00 EST 2020 · Fuel

DOI:https://doi.org/10.1016/j.fuel.2020.119990· OSTI ID:1849205

^[1];

^[2];

^[3]; Taggart, Ross K. ^[3]

Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Univ. of Kentucky, Lexington, KY (United States). Dept. of Earth and Environmental Sciences
Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Univ. of Kentucky, Lexington, KY (United States). Dept. of Mining Engineering
Duke Univ., Durham, NC (United States). Dept. of Civil and Environmental Engineering

This study examined rare earth element (REE) trends for Illinois Basin coal-sourced fly ashes, with the goal of understanding the elemental composition and resource potential for various fly ash fractions. Illinois Basin coals have a high volatile C through A bituminous rank with a moderate ash content (slightly>12% ash (dry basis)), about 3% sulfur, and, in general, lower concentrations of hazardous and other trace elements than many Central Appalachian coals. Fly ash from the combustion of Illinois Basin coals tends to have a high Fe₂O₃ content owing to the amount of pyrite in the feed coals. The rare earth element (REE) concentrations in Illinois Basin coal-sourced fly ashes are less than that for fly ashes from the combustion of Central Appalachian coals. The Upper continental crust-corrected fly ashes show an H-type enrichment, a positive Eu_N/Eu_N^*, and, in some cases, a sharp Gd peak. For comparison, a suite of fly ashes from the combustion of a blend of eastern Kentucky coals had an H-type enrichment, a positive Eu_N/Eu_N^*, but only a minimal Gd peak. In contrast, fly ash from the combustion of the Fire Clay coal, a REE-rich coal, had a negative Eu_N/Eu_N^* and a sharp Gd peak. Finally, these results highlight the importance of feed coal composition on trace element contents of respective combustion fly ash fractions and also the unique REE enrichment patterns of the Illinois Basin fly ashes relative to the better studied fly ashes of eastern Kentucky and Central Appalachia.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Duke Univ., Durham, NC (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE); National Science Foundation (NSF)

Grant/Contract Number:: FE0026952; CBET-1510965; CBET-1510861

OSTI ID:: 1849205

Alternate ID(s):: OSTI ID: 1775786

Journal Information:: Fuel, Vol. 289, Issue C; ISSN 0016-2361

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Changes in the quality of coal combustion by-products produced by Kentucky power plants, 1978 to 1997: consequences of Clean Air Act directives Hower, James C.; Robl, Thomas L.; Thomas, Gerald A. Fuel, Vol. 78, Issue 6 https://doi.org/10.1016/S0016-2361(98)00191-4	journal	May 1999
Arsenic, cadmium, lead, and zinc in the Danville and Springfield coal members (Pennsylvanian) from Indiana Mastalerz, Maria; Drobniak, Agnieszka International Journal of Coal Geology, Vol. 71, Issue 1 https://doi.org/10.1016/j.coal.2006.05.005	journal	June 2007
Selective Recovery of Rare Earth Elements from Coal Fly Ash Leachates Using Liquid Membrane Processes Smith, Ryan C.; Taggart, Ross K.; Hower, James C. Environmental Science & Technology, Vol. 53, Issue 8 https://doi.org/10.1021/acs.est.9b00539	journal	March 2019
Mercury content of the Springfield coal, Indiana and Kentucky Hower, James C.; Mastalerz, Maria; Drobniak, Agnieszka International Journal of Coal Geology, Vol. 63, Issue 3-4 https://doi.org/10.1016/j.coal.2005.03.018	journal	August 2005
Enrichment of U-Re-V-Cr-Se and rare earth elements in the Late Permian coals of the Moxinpo Coalfield, Chongqing, China: Genetic implications from geochemical and mineralogical data Dai, Shifeng; Xie, Panpan; Jia, Shaohui Ore Geology Reviews, Vol. 80 https://doi.org/10.1016/j.oregeorev.2016.06.015	journal	January 2017
Temporal and spatial variations in fly ash quality Hower, James C.; Trimble, Alan S.; Eble, Cortland F. Fuel Processing Technology, Vol. 73, Issue 1 https://doi.org/10.1016/S0378-3820(01)00193-X	journal	October 2001
Changes in the quality of coal delivered to Kentucky power plants, 1978 to 1997: responses to Clean Air Act directives Hower, James C.; Robl, Thomas L.; Thomas, Gerald A. International Journal of Coal Geology, Vol. 41, Issue 1-2 https://doi.org/10.1016/S0166-5162(99)00014-2	journal	August 1999
Chemistry of coal and coal combustion products from Kentucky power plants: Results from the 2007 sampling, with emphasis on selenium Hower, James C.; Robl, Thomas L.; Thomas, Gerald A. Coal Combustion and Gasification Products, Vol. 1, Issue 1 https://doi.org/10.4177/CCGP-D-09-00013.1	journal	January 2009
Trends in the Rare Earth Element Content of U.S.-Based Coal Combustion Fly Ashes Taggart, Ross K.; Hower, James C.; Dwyer, Gary S. Environmental Science & Technology, Vol. 50, Issue 11 https://doi.org/10.1021/acs.est.6b00085	journal	May 2016
Ponded and Landfilled Fly Ash as a Source of Rare Earth Elements from a Kentucky Power Plant Hower, James C.; Groppo, John G.; Henke, Kevin R. Coal Combustion and Gasification Products, Vol. 9, Issue 1 https://doi.org/10.4177/CCGP-D-17-00003.1	journal	January 2017
Rare Earth Element Distribution in Fly Ash Derived from the Fire Clay Coal, Kentucky Hood, Madison M.; Taggart, Ross K.; Smith, Ryan C. Coal Combustion and Gasification Products, Vol. 9, Issue 1 https://doi.org/10.4177/CCGP-D-17-00002.1	journal	January 2017
Distribution of yttrium and rare-earth elements in the Penge and Kuruman iron-formations, Transvaal Supergroup, South Africa Bau, Michael; Dulski, Peter Precambrian Research, Vol. 79, Issue 1-2 https://doi.org/10.1016/0301-9268(95)00087-9	journal	July 1996
Aqueous acid and alkaline extraction of rare earth elements from coal combustion ash King, Jack F.; Taggart, Ross K.; Smith, Ryan C. International Journal of Coal Geology, Vol. 195 https://doi.org/10.1016/j.coal.2018.05.009	journal	July 2018
Distribution of rare earth elements in eastern Kentucky coals: Indicators of multiple modes of enrichment? Hower, James C.; Eble, Cortland F.; Dai, Shifeng International Journal of Coal Geology, Vol. 160-161 https://doi.org/10.1016/j.coal.2016.04.009	journal	April 2016
Discussion on “Characteristics of Fly Ashes from Full-Scale Coal-Fired Power Plants and Their Relationship to Mercury Adsorption” by Lu et al. Hower, James C.; Valentim, Bruno; Kostova, Irena J. Energy & Fuels, Vol. 22, Issue 2 https://doi.org/10.1021/ef700683q	journal	February 2008
A biosorption-based approach for selective extraction of rare earth elements from coal byproducts Park, Dan; Middleton, Andrew; Smith, Ryan Separation and Purification Technology, Vol. 241 https://doi.org/10.1016/j.seppur.2020.116726	journal	June 2020
A review of anomalous rare earth elements and yttrium in coal Dai, Shifeng; Graham, Ian T.; Ward, Colin R. International Journal of Coal Geology, Vol. 159 https://doi.org/10.1016/j.coal.2016.04.005	journal	April 2016
Impact of coal properties on coal combustion by-product quality: examples from a Kentucky power plant Mardon, Sarah M.; Hower, James C. International Journal of Coal Geology, Vol. 59, Issue 3-4 https://doi.org/10.1016/j.coal.2004.01.004	journal	August 2004
Notes on the Potential for the Concentration of Rare Earth Elements and Yttrium in Coal Combustion Fly Ash Hower, James; Groppo, John; Henke, Kevin Minerals, Vol. 5, Issue 2 https://doi.org/10.3390/min5020356	journal	June 2015
Permian outliers in Western Kentucky Nelson, W. John; Elrick, Scott; Williams, David A. International Journal of Coal Geology, Vol. 119 https://doi.org/10.1016/j.coal.2013.07.010	journal	November 2013
Characteristics of coal combustion products (CCP's) from Kentucky power plants, with emphasis on mercury content Hower, J.; Robl, T.; Anderson, C. Fuel, Vol. 84, Issue 11 https://doi.org/10.1016/j.fuel.2004.09.029	journal	August 2005
Coal deposits as potential alternative sources for lanthanides and yttrium Seredin, Vladimir V.; Dai, Shifeng International Journal of Coal Geology, Vol. 94 https://doi.org/10.1016/j.coal.2011.11.001	journal	May 2012
Distribution of Rare Earth Elements in the Illinois Basin Coals Valian, Alireza; Groppo, John G.; Eble, Cortland F. Mining, Metallurgy & Exploration, Vol. 38, Issue 4 https://doi.org/10.1007/s42461-020-00257-y	journal	July 2020
Effects of roasting additives and leaching parameters on the extraction of rare earth elements from coal fly ash Taggart, Ross K.; Hower, James C.; Hsu-Kim, Heileen International Journal of Coal Geology, Vol. 196 https://doi.org/10.1016/j.coal.2018.06.021	journal	August 2018
Comparison of the Eastern and Western Kentucky coal fields (Pennsylvanian), USA—why are coal distribution patterns and sulfur contents so different in these coal fields? Greb, Stephen F.; Eble, Cortland F.; Chesnut, Donald R. International Journal of Coal Geology, Vol. 50, Issue 1-4 https://doi.org/10.1016/S0166-5162(02)00115-5	journal	May 2002
Impact of coal source changes on mercury content in fly ash: Examples from a Kentucky power plant Hower, James C.; Clack, Herek L.; Hood, Madison M. International Journal of Coal Geology, Vol. 170 https://doi.org/10.1016/j.coal.2016.10.007	journal	February 2017
Distribution of rare earth elements in coal combustion fly ash, determined by SHRIMP-RG ion microprobe Kolker, Allan; Scott, Clint; Hower, James C. International Journal of Coal Geology, Vol. 184 https://doi.org/10.1016/j.coal.2017.10.002	journal	November 2017
Sequence stratigraphy of the late Desmoinesian to early Missourian (Pennsylvanian) succession of southern Illinois: Insights into controls on stratal architecture in an icehouse period of Earth history Fielding, Christopher R.; Nelson, W. John; Elrick, Scott D. Journal of Sedimentary Research, Vol. 90, Issue 2 https://doi.org/10.2110/jsr.2020.10	journal	February 2020
Geochemical partitioning from pulverized coal to fly ash and bottom ash Hower, James C.; Fu, Biao; Dai, Shifeng Fuel, Vol. 279 https://doi.org/10.1016/j.fuel.2020.118542	journal	November 2020
Mississippian (Serpukhovian; Chesterian Stage) coals from the Fluorspar District, Crittenden and Caldwell counties, Kentucky: Petrological and palynological compositions and their indications for peat-producing ecosystems Hower, James C.; O'Keefe, Jennifer M. K.; Eble, Cortland F. International Journal of Coal Geology, Vol. 174 https://doi.org/10.1016/j.coal.2017.03.009	journal	April 2017
Rare earth elements of fly ash from Wyoming's Powder River Basin coal Huang, Zaixing; Fan, Maohong; Tian, Hanjing Journal of Rare Earths, Vol. 38, Issue 2 https://doi.org/10.1016/j.jre.2019.05.004	journal	February 2020
Sedimentary Rocks and Crustal Evolution: Tectonic Setting and Secular Trends McLennan, S. M.; Taylor, S. R. The Journal of Geology, Vol. 99, Issue 1 https://doi.org/10.1086/629470	journal	January 1991
Characterization of fly ash from Kentucky power plants Hower, James C.; Robertson, J. David; Thomas, Gerald A. Fuel, Vol. 75, Issue 4 https://doi.org/10.1016/0016-2361(95)00278-2	journal	March 1996
Mercury capture by native fly ash carbons in coal-fired power plants Hower, James C.; Senior, Constance L.; Suuberg, Eric M. Progress in Energy and Combustion Science, Vol. 36, Issue 4 https://doi.org/10.1016/j.pecs.2009.12.003	journal	August 2010
Size-Dependent Variations in Fly Ash Trace Element Chemistry: Examples from a Kentucky Power Plant and with Emphasis on Rare Earth Elements Liu, Jingjing; Dai, Shifeng; He, Xin Energy & Fuels, Vol. 31, Issue 1 https://doi.org/10.1021/acs.energyfuels.6b02644	journal	December 2016
Rare earth element-bearing coals from the Russian Far East deposits Seredin, V. V. International Journal of Coal Geology, Vol. 30, Issue 1-2 https://doi.org/10.1016/0166-5162(95)00039-9	journal	June 1996
Trends in Coal Utilization and Coal Combustion Product Production in Kentucky: Results of the 2012 Survey of Power Plants [English] Hower, James; Thomas, Gerald; Hopps, Shelley Coal Combustion and Gasification Products, Vol. 6, Issue 1 https://doi.org/10.4177/CCGP-D-14-00006.1	journal	January 2014
Anomalies of rare metals in Lopingian super-high-organic-sulfur coals from the Yishan Coalfield, Guangxi, China Dai, Shifeng; Xie, Panpan; Ward, Colin R. Ore Geology Reviews, Vol. 88 https://doi.org/10.1016/j.oregeorev.2017.05.007	journal	August 2017
Discussion on origin of vanadium in coals: parts of the Western Kentucky (USA) No. 9 coal rich in vanadium: Special Publication No. 125, 1997, 273–286 Hower, James C.; Greb, Stephen F.; Cobb, James C. Journal of the Geological Society, Vol. 157, Issue 6 https://doi.org/10.1144/jgs.157.6.1257	journal	November 2000
Distribution of Lanthanides, Yttrium, and Scandium in the Pilot-Scale Beneficiation of Fly Ashes Derived from Eastern Kentucky Coals Hower, James C.; Groppo, John G.; Joshi, Prakash Minerals, Vol. 10, Issue 2 https://doi.org/10.3390/min10020105	journal	January 2020

Similar Records

Signatures of rare earth element distributions in fly ash derived from the combustion of Central Appalachian, Illinois, and Powder River basin coals

Journal Article · Thu May 27 00:00:00 EDT 2021 · Fuel · OSTI ID:1849205

Hower, James C.; Groppo, John G.; Hsu-Kim, Heileen; +1 more

Effects of roasting additives and leaching parameters on the extraction of rare earth elements from coal fly ash

Journal Article · Sat Jun 30 00:00:00 EDT 2018 · International Journal of Coal Geology · OSTI ID:1849205

Taggart, Ross K.; Hower, James C.; Hsu-Kim, Heileen

A review of rare earth elements and yttrium in coal ash: Content, modes of occurrences, combustion behavior, and extraction methods

Journal Article · Thu Sep 16 00:00:00 EDT 2021 · Progress in Energy and Combustion Science · OSTI ID:1849205

Fu, Biao; Hower, James C.; Zhang, Wencai; +3 more

Related Subjects

01 COAL, LIGNITE, AND PEAT
42 ENGINEERING
Energy & fuels
Engineering
Lanthanides
Critical materials
Energy resources
Coal
Fly ash

Title: Distribution of rare earth elements in fly ash derived from the combustion of Illinois Basin coals

Citation Formats

References (40)

Similar Records

Related Subjects